Chiral approach to investigate mechanism of highly efficient thermally activated delayed fluorescence

2021 ◽  
Vol 57 (14) ◽  
pp. 1738-1741
Author(s):  
Kikuya Hayashi ◽  
Arimasa Matsumoto ◽  
Shuzo Hirata
Keyword(s):  
Cotton Effect ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Donor Acceptor

Cancellation of the Cotton effect depending on vibrations of a chiral orthogonal donor–acceptor structure identifies a mechanism of highly efficient delayed fluorescence.

scholarly journals Highly Efficient Thermally Activated Delayed Fluorescence via an Unconjugated Donor–Acceptor System Realizing EQE of Over 30%

2020 ◽  
Vol 32 (48) ◽  
pp. 2003885 ◽  
Author(s):  
Chen‐Chen Peng ◽  
Sheng‐Yi Yang ◽  
Hong‐Cheng Li ◽  
Guo‐Hua Xie ◽  
Lin‐Song Cui ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Donor Acceptor

scholarly journals High-efficiency blue thermally activated delayed fluorescence from donor–acceptor–donor systems via the through-space conjugation effect

2019 ◽  
Vol 10 (21) ◽  
pp. 5556-5567 ◽  
Author(s):  
Feifei Gao ◽  
Ruiming Du ◽  
Chunmiao Han ◽  
Jing Zhang ◽  
Ying Wei ◽  
...  
Keyword(s):  
High Efficiency ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Conjugation Effect ◽  
Highly Efficient ◽  
Donor Acceptor

Highly efficient sky-blue TADF donor–acceptor–donor molecules were demonstrated, in which 5,10-diphenyl-5,10-dihydrophosphanthrene oxide (DPDPO2A) with the feature of homoconjugation was used as the acceptor to bridge four carbazolyl or 3,6-di-t-butyl-carbazolyl groups.

Extended π-backbone for highly efficient near-infrared thermally activated delayed fluorescence with enhanced horizontal molecular orientation

2022 ◽  
Author(s):  
Jian-Li He ◽  
Yukun Tang ◽  
Kai Zhang ◽  
Yue Zhao ◽  
Yu-Ching Lin ◽  
...  
Keyword(s):  
Molecular Orientation ◽  
Near Infrared ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Donor Acceptor ◽  
Limited Choice

The near-infrared thermally activated delayed fluorescence (NIR-TADF) materials with emission over 700 nm were insufficiently investigated mainly due to the limited choice of strong donor/acceptor units for the molecular construction...

scholarly journals Pyrimidine-based twisted donor–acceptor delayed fluorescence molecules: a new universal platform for highly efficient blue electroluminescence

2017 ◽  
Vol 8 (2) ◽  
pp. 953-960 ◽  
Author(s):  
In Seob Park ◽  
Hideaki Komiyama ◽  
Takuma Yasuda
Keyword(s):  
High Efficiency ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Deep Blue ◽  
Donor Acceptor

High-efficiency deep blue thermally activated delayed fluorescence (TADF) emitters consisting of acridan–pyrimidine donor–acceptor motifs are developed.

Novel thermally activated delayed fluorescence materials by high-throughput virtual screening: going beyond donor–acceptor design

2021 ◽  
Vol 9 (9) ◽  
pp. 3324-3333 ◽  
Author(s):  
Ke Zhao ◽  
Ömer H. Omar ◽  
Tahereh Nematiaram ◽  
Daniele Padula ◽  
Alessandro Troisi
Keyword(s):  
Virtual Screening ◽  
Quantum Chemistry ◽  
High Throughput ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Quantum Chemistry Calculations ◽  
Donor Acceptor ◽  
Molecular Semiconductors ◽  
High Throughput Virtual Screening

125 potential TADF candidates are identified through quantum chemistry calculations of 700 molecules derived from a database of 40 000 molecular semiconductors. Most of them are new and some do not belong to the class of donor–acceptor molecules.

Highly Efficient Near‐Infrared Electrofluorescence from a Thermally‐Activated Delayed Fluorescence Molecule

2021 ◽  
Author(s):  
Umamahesh Balijapalli ◽  
Ryo Nagata ◽  
Nishiki Yamada ◽  
Hajime Nakanotani ◽  
Masaki Tanaka ◽  
...  
Keyword(s):  
Near Infrared ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient

scholarly journals Regioisomeric Effect on the Excited-State Fate Leading to Room-Temperature Phosphorescence or Thermally Activated Delayed Fluorescence in a Dibenzophenazine-Cored Donor–Acceptor–Donor System

2021 ◽  
Author(s):  
Takumi Hosono ◽  
Nicolas Oliveira Decarli ◽  
Paola Zimmermann Crocomo ◽  
Tsuyoshi Goya ◽  
Leonardo Evaristo de Sousa ◽  
...  
Keyword(s):  
Excited State ◽  
Room Temperature ◽  
Delayed Fluorescence ◽  
Quantum Yields ◽  
Room Temperature Phosphorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Emission Behavior

Exploring design principle for switching thermally activated dealyed fluorescecne (TADF) and room temperature phosphorescence (RTP) is a fundamentally imporant research in developing triplet-mediated photofunctional organic materials. Herein systematic studies on the regioisomeric and substituents effects in a twisted donor–acceptor–donor (D–A–D) scaffold (A = dibenzo[a,j]phenazine; D = dihydrophenazasiline) on the fate of the excited state have been performed. The study revealed that the regiosiomerism clearly affects the emission behavior of the D–A–D compounds. Distinct difference in TADF, dual TADF & RTP, and dual RTP were observed, depending on the host used. Furthermore, OLED organic light-emitting diodes (OLEDs) fabricated with the developed emitters achieved high external quantum yields for RTP-based OLEDS up to 7.4%.

Sign in / Sign up

Export Citation Format

Share Document