Photo-oligomerization by shifting the coordination site in a luminescent coordination polymer

2021 ◽  
Author(s):  
Wei-Chao Song ◽  
Chen-Chen Geng ◽  
Sheng-Yang Li ◽  
Ling Liang ◽  
Xiu-Guang Wang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Site

The photo-oligomerization of a diolefinic ligand by shifting the coordination site in a ZnII-based CP has been designed.

A cadmium(II) coordination polymer formed from a third generation tetratopic tris(pyrazolyl)methane ligand

2016 ◽  
Vol 72 (11) ◽  
pp. 832-837 ◽  
Author(s):  
Radu F. Semeniuc ◽  
Daniel L. Reger ◽  
Mark D. Smith
Keyword(s):  
Coordination Polymer ◽  
Diethyl Ether ◽  
Dimensional Structure ◽  
Third Generation ◽  
Acetonitrile Molecule ◽  
One Dimensional ◽  
Coordination Site ◽  
Methyl Benzene ◽  
Bonding Mode

The reaction of a third generation tetratopic tris(pyrazolyl)methane ligand, namely 1,2,4,5-{[2,2,2-tris(1H-pyrazol-1-yl)ethoxy]methyl}benzene {1,2,4,5-C6H2[CH2OCH2C(pz)3]4,L4}, and [Cd2(thf)5](BF4)4(thf is tetrahydrofuran) produces the coordination polymercatena-poly[[[bis[acetonitrilecadmium(II)]-μ4-1,2,4,5-{[2,2,2-tris(1H-pyrazol-1-yl)ethoxy]methyl}benzene] tetrakis(tetrafluoroborate)]–diethyl ether–acetonitrile (1/2/2)], {[Cd2(CH3CN)2(C54H54N24O4)](BF4)4·2C4H10O·2CH3CN}n. The CdIIcenter is coordinated in a κ3-fashion by one tris(pyrazolyl)methane group and in a κ2–κ0fashion by another, while the sixth coordination site on the CdIIcation is occupied by an acetonitrile molecule. This bonding mode of the ligand generates an infinite one-dimensional structure built upon 32-atom metallomacrocycles connected by the C6H2spacer. This compound is isostructural with the silver(I) analogue of this ligand,i.e.{[Ag2(L4)](BF4)2·4CH3CN}n, thus showing the tendency of this system to form metal-based macrocyclic architectures.

Substituted imidazole copper(II) complexes: The coordination polymer complex tetrakis N -methylimidazole copper(II) sulfate

2003 ◽  
Vol 56 (8) ◽  
pp. 647-653 ◽  
Author(s):  
Lan Liu ◽  
Stan Duraj ◽  
Phillip E. Fanwick ◽  
Maria T. Andras ◽  
Aloysius F. Hepp
Keyword(s):  
Coordination Polymer ◽  
Polymer Complex

Crystal Structure of the 2D Dimensional Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Based on 4,4/ -Dipyridyl Sulfide

2018 ◽  
Vol 483 (6) ◽  
pp. 631-635
Author(s):  
Yu. Tupolova ◽  
◽  
I. Shcherbakov ◽  
L. Popov ◽  
V. Tkachev ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer

Slow Magnetization Relaxation in a 1-D Double-Chain Coordination Polymer Composed of {DyIII 4} Repeating Units

2013 ◽  
Vol 3 (2) ◽  
pp. 161-171 ◽  
Author(s):  
Dimitris Alexandropoulos ◽  
Chaoran Li ◽  
Catherine Raptopoulou ◽  
Vassilis Psycharis ◽  
Wolfgang Wernsdorfer ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Double Chain ◽  
Magnetization Relaxation

Lanthanide coordination polymer-based biosensor for citrate detection in urine

2019 ◽  
Vol 11 (10) ◽  
pp. 1405-1409 ◽  
Author(s):  
Haoshuang Shen ◽  
Baoxia Liu ◽  
Daosheng Liu ◽  
Xu Zhu ◽  
Xiuhua Wei ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
High Sensitivity ◽  
Lanthanide Coordination Polymer ◽  
Sensitivity And Selectivity

GMP ligand based LCP sensor for Cit with high sensitivity and selectivity was constructed.

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