Nitrogen doped carbon spheres with wrinkled cages for the selective oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid

2021 ◽  
Vol 57 (16) ◽  
pp. 2005-2008
Author(s):  
Jiaping Zhu ◽  
Chaojian Yao ◽  
Ayan Maity ◽  
Jielai Xu ◽  
Tong Zhan ◽  
...  

Nitrogen doped carbon spheres with wrinkled cages exhibited high catalytic activity and selectivity in the oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid using TBHP as the oxidant.

RSC Advances ◽  
2015 ◽  
Vol 5 (69) ◽  
pp. 56121-56129 ◽  
Author(s):  
Haoran Yuan ◽  
Lifang Deng ◽  
Xixi Cai ◽  
Shungui Zhou ◽  
Yong Chen ◽  
...  

Nitrogen-doped activated carbon sheets were derived from chitin, which exhibited remarkable activity for ORR and high catalytic activity towards OER.


2016 ◽  
Vol 52 (86) ◽  
pp. 12753-12756 ◽  
Author(s):  
Zonghua Pu ◽  
Min Wang ◽  
Zongkui Kou ◽  
Ibrahim Saana Amiinu ◽  
Shichun Mu

Mo2C QDs/NGCLs exhibit high catalytic activity and durability for the hydrogen evolution reaction in a broad pH range.


2019 ◽  
Vol 7 (8) ◽  
pp. 3664-3672 ◽  
Author(s):  
Hele Guo ◽  
Qichun Feng ◽  
Jixin Zhu ◽  
Jingsan Xu ◽  
Qianqian Li ◽  
...  

A Co@N-CNTF electrocatalyst derived from a metal–organic framework exhibits high catalytic activity in the ORR, OER and HER.


2016 ◽  
Vol 6 (14) ◽  
pp. 5746-5753 ◽  
Author(s):  
Sensen Shang ◽  
Lianyue Wang ◽  
Wen Dai ◽  
Bo Chen ◽  
Ying Lv ◽  
...  

We report the synthesis and assessment of novel mesoporous cobalt-coordinated nitrogen-doped carbon catalysts (meso-Co–N/C) for highly efficient synthesis of nitriles.


ChemCatChem ◽  
2010 ◽  
Vol 2 (1) ◽  
pp. 51-54 ◽  
Author(s):  
Amit A. Deshmukh ◽  
Rafique Ul Islam ◽  
Michael J. Witcomb ◽  
Willem A. L. van Otterlo ◽  
Neil J. Coville

RSC Advances ◽  
2018 ◽  
Vol 8 (26) ◽  
pp. 14462-14472 ◽  
Author(s):  
Zihao Zhen ◽  
Zhongqing Jiang ◽  
Xiaoning Tian ◽  
Lingshan Zhou ◽  
Binglu Deng ◽  
...  

A simple method has been developed for the synthesis of Co–CoO@NC/NC, which exhibits high and stable performance for the ORR.


MRS Advances ◽  
2020 ◽  
Vol 5 (57-58) ◽  
pp. 2961-2972
Author(s):  
P.C. Meléndez-González ◽  
E. Garza-Duran ◽  
J.C. Martínez-Loyola ◽  
P. Quintana-Owen ◽  
I.L. Alonso-Lemus ◽  
...  

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).


2022 ◽  
Author(s):  
Huixin Ma ◽  
Daijie Deng ◽  
Honghui Zhang ◽  
Feng Chen ◽  
Junchao Qian ◽  
...  

Nitrogen-coordinated single-atom manganese in multi-dimensional nitrogen-doped carbon electrocatalysts (Mn-NC) was successful constructed by combing two-dimensional nanosheets and one-dimensional nanofibers. The Mn-NC exhibited excellent oxygen reduction reaction catalytic activity with half-wave...


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