Visible-light promoted α-alkylation of glycine derivatives with alkyl boronic acids

2021 ◽  
Vol 57 (15) ◽  
pp. 1959-1962
Author(s):  
Jiayuan Wang ◽  
Yingpeng Su ◽  
Zhengjun Quan ◽  
Jun Li ◽  
Jie Yang ◽  
...  
Keyword(s):  
Visible Light ◽  
Catalyst System ◽  
Boronic Acids ◽  
Alkylation Reaction ◽  
Radical Coupling ◽  
Cu Catalyst ◽  
Glycine Derivatives

A visible-light-mediated aerobic α-alkylation reaction of glycine derivatives with alkyl boronic acids has been established in the presence of a Ru/Cu catalyst system, giving the desired radical coupling products efficiently.

Visible light-induced aerobic oxidative cross-coupling of glycine derivatives with indoles: a facile access to 3,3′ bisindolylmethanes

2018 ◽  
Vol 5 (13) ◽  
pp. 2120-2125 ◽  
Author(s):  
Yuan Zhang ◽  
Xiaorong Yang ◽  
Huang Zhou ◽  
Shilin Li ◽  
Yin Zhu ◽  
...  
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Alkylation Reaction ◽  
Rapid Synthesis ◽  
Glycine Derivatives

A rapid synthesis of 3,3′-bisindolylmethanes is achieved via a photocatalyzed double Friedel–Crafts alkylation reaction between glycine derivatives and indoles.

The Merger of CF3SO2Na and Palladium Catalysis to Enable Decarboxylative Cross-Coupling for the Synthesis of Aromatic Ketones under Room Temperature

2021 ◽  
Author(s):  
Pan Xie ◽  
Cheng Xue ◽  
Cancan Wang ◽  
Dongdong Du ◽  
Sanshan Shi
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Palladium Catalysis ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Aromatic Ketones ◽  
Aryl Ketones ◽  
Oxocarboxylic Acids

A CF3SO2Na/Pd(OAc)2 co-catalyzed strategy is developed to produce aryl ketones via visible-light-induced decarboxylative cross-coupling of α-oxocarboxylic acids and aryl boronic acids. This process was perfomed under air at room temperature,...

Enantioselective Radical Functionalization of Imines and Iminium Intermediates via Visible Light Photoredox Catalysis

Synthesis ◽  
2020 ◽  
Author(s):  
Jia-Jia Zhao ◽  
Hong-Hao Zhang ◽  
Shouyun Yu
Keyword(s):  
Visible Light ◽  
Asymmetric Synthesis ◽  
Carbonyl Compounds ◽  
Asymmetric Reduction ◽  
Chemical Transformations ◽  
Photoredox Catalysis ◽  
Radical Coupling ◽  
Mild Conditions ◽  
Iminium Ions ◽  
Radical Functionalization

Visible light photoredox catalysis has recently emerged as a powerful tool for the development of new and valuable chemical transformations under mild conditions. Visible-light promoted enantioselective radical transformations of imines and iminium intermediates provide new opportunities for the asymmetric synthesis of amines and asymmetric β-functionalization of unsaturated carbonyl compounds. In this review, the advance in the catalytic asymmetric radical functionalization of imines, as well as iminium intermediates, are summarized. 1 Introduction 2 The enantioselective radical functionalization of imines 2.1 Asymmetric reduction 2.2 Asymmetric cyclization 2.3 Asymmetric addition 2.4 Asymmetric radical coupling 3 The enantioselective radical functionalization of iminium ions 3.1 Asymmetric radical alkylation 3.2 Asymmetric radical acylation 4 Conclusion

ChemInform Abstract: A Highly Efficient Cu-Catalyst System for N-Arylation of Azoles in Water.

ChemInform ◽  
2012 ◽  
Vol 43 (40) ◽  
pp. no-no
Author(s):  
Deping Wang ◽  
Fuxing Zhang ◽  
Daizhi Kuang ◽  
Jiangxi Yu ◽  
Junhua Li
Keyword(s):  
Catalyst System ◽  
Highly Efficient ◽  
Cu Catalyst

scholarly journals A convenient catalyst system for microwave accelerated cross-coupling of a range of aryl boronic acids with aryl chlorides

2007 ◽  
Vol 3 ◽  
Author(s):  
Matthew L Clarke ◽  
Marcia B France ◽  
Jose A Fuentes ◽  
Edward J Milton ◽  
Geoffrey J Roff
Keyword(s):  
Cross Coupling ◽  
Catalyst System ◽  
Boronic Acids ◽  
Aryl Chlorides

scholarly journals A Modular, Self-Assembling Metallaphotocatalyst for Cross Couplings Using the Full Visible-Light Spectrum

2020 ◽  
Author(s):  
Susanne Reischauer ◽  
Volker Strauss ◽  
Bartholomäus Pieber
Keyword(s):  
Titanium Dioxide ◽  
Visible Light ◽  
Excited States ◽  
Catalyst System ◽  
Chemical Energy ◽  
Modular Approach ◽  
Nickel Catalysis ◽  
Light Spectrum ◽  
Dye Sensitized ◽  
Self Assembling

The combination of nickel- and photocatalysis has unlocked a variety of cross couplings. These protocols rely on a few photocatalysts that can only convert a small portion of visible light (<500 nm) into chemical energy. Many dyes that absorb a much broader spectrum of light are not applicable due to their short-lived excited states. Here we describe a self-assembling catalyst system that overcomes this limitation. The modular approach combines nickel catalysis with dye-sensitized titanium dioxide and can be used to catalyze various bond formations. <br>

Visible Light-Induced Aerobic Oxidative Csp3 −H Arylation of Glycine Derivatives

2018 ◽  
Vol 360 (22) ◽  
pp. 4452-4456 ◽  
Author(s):  
Shilin Li ◽  
Xiaorong Yang ◽  
Yunwei Wang ◽  
Huang Zhou ◽  
Boyang Zhang ◽  
...  
Keyword(s):  
Visible Light ◽  
Glycine Derivatives
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