Synthesis, Crystallographic and Spectroscopic Characterizations, and Theoretical Elucidation of an Elusive Aminyl Radical Containing CuII-Aminyl-Iminosemiquinone Complex‡

2021 ◽  
Author(s):  
Chandan Mukherjee ◽  
PRASENJIT SARKAR ◽  
Amrit Sarmah
Keyword(s):  
Aminyl Radical

An elusive aminyl and an iminosemiquinone radicals-coordinated square pyramidal Cu(II) complex (1) has been isolated by the reaction between noninnocent ligand H4LPy(AP) and Cu(ClO4)2•6H2O in the presence of Et3N and...

scholarly journals Three-Coordinate Copper(I) Amido and Aminyl Radical Complexes

2009 ◽  
Vol 131 (11) ◽  
pp. 3878-3880 ◽  
Author(s):  
Neal P. Mankad ◽  
William E. Antholine ◽  
Robert K. Szilagyi ◽  
Jonas C. Peters
Keyword(s):  
Aminyl Radical

Copper-Catalyzed Aminoarylation of Alkenes via Aminyl Radical Addition and Aryl Migration

2021 ◽  
Author(s):  
Jin-Lin Wang ◽  
Mei-Ling Liu ◽  
Jian-Yu Zou ◽  
Wen-Hui Sun ◽  
Xue-Yuan Liu
Keyword(s):  
Radical Addition ◽  
Aminyl Radical

Application of hypoiodite-mediated aminyl radical cyclization to synthesis of solasodine acetate

Steroids ◽  
2012 ◽  
Vol 77 (11) ◽  
pp. 1069-1074 ◽  
Author(s):  
Yi Kou ◽  
Myong Chul Koag ◽  
Young Cheun ◽  
Aram Shin ◽  
Seongmin Lee
Keyword(s):  
Radical Cyclization ◽  
Aminyl Radical

A Perturbation Molecular Orbital Study of the Recombination Reactions of Diarylaminyl Radicals

1973 ◽  
Vol 28 (12) ◽  
pp. 1892-1896 ◽  
Author(s):  
Muthana Shanshal
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Molecular Orbital ◽  
Dissociation Energy ◽  
Mo Calculations ◽  
Aminyl Radicals ◽  
Molecular Orbital Study ◽  
Aminyl Radical ◽  
High Temperature Reactions ◽  
Recombination Reactions

The recombination reactions of arylaminyl radicals are studied on the basis of its order P\10 treatment, assuming dimeric intermediates with C-N or C-C bonding modes. In the case of diphenyl aminyl radical the N -N recombination causes an increase in the T-bonding energy and should be most favourable for the low temperature reactions. Due to the low dissociation energy of the N-N bond, the C-N bonding is preferred in the high temperature reactions. It is found that the ortho- and para-additions are energetically more favourable than the meta addition, in agreement with π-SCF MO calculations and experimental results. The recombination of 2,2′-dinaphthyl aminyl radicals proceeds through C-C and C -N bonding, the 1,1′-bonding is most favourable. The PMO-results are parallel to those of the π-SCF MO calculations, providing another demonstration for the utility of this method.

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