Photo-Fries rearrangement in flow under aqueous micellar conditions

2020 ◽  
Vol 56 (98) ◽  
pp. 15470-15472
Author(s):  
Chia-Chen Chien ◽  
Shih-Chieh Kao ◽  
Chun-Jen Chen ◽  
Yen-Ku Wu
Keyword(s):  
Flow Reactor ◽  
Micellar Medium ◽  
Fries Rearrangement ◽  
Green Approach ◽  
Aqueous Micellar Medium

A combination of an aqueous micellar medium and a flow reactor provides a green approach for refining the classic photo-Fries rearrangement.

scholarly journals Synthesis of 2-Substitued Indoles via Pd-Catalysed Cyclization in an Aqueous Micellar Medium

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3917
Author(s):  
Sofia Siciliano ◽  
Elena Cini ◽  
Maurizio Taddei ◽  
Giorgia Vinciarelli
Keyword(s):  
Water Environment ◽  
Delivery Mode ◽  
Micellar Medium ◽  
Dielectric Heating ◽  
Microwave Dielectric ◽  
Microwave Dielectric Heating ◽  
Heating Mode ◽  
Aqueous Micellar Medium ◽  
By Products ◽  
Better Than

The synthesis of 2-substituted indoles starting from the corresponding unprotected 2-alkynylanilines was made possible in 3% TPGS-750-M water using Pd(OAc)2 alone as the catalyst. The reaction was sensitive to the heating mode respect to the nature of the starting material as, in many cases, convectional heating was better than microwave dielectric heating. The MW (microwave) delivery mode had also an influence in the formation of by-products and, consequently, product yields. A tandem Sonogashira-cyclisation reaction was also accomplished using Pd(OAc)2/Xphos in the nanomicellar water environment.

Captopril as a nucleophile for ester cleavage. Formation of the thiolester S-benzoylcaptopril

RSC Advances ◽  
2015 ◽  
Vol 5 (57) ◽  
pp. 45740-45748 ◽  
Author(s):  
Emilia Iglesias ◽  
Isabel Brandariz
Keyword(s):  
Micellar Medium ◽  
Carbonate Buffer ◽  
Aqueous Micellar Medium

The reaction between captopril and phenylbenzoate yields S-benzoylcaptopril that is very stable in a carbonate buffer or in an aqueous micellar medium.

Ring-Closing Metathesis in Aqueous Micellar Medium

2011 ◽  
Vol 18 (3) ◽  
pp. 760-764 ◽  
Author(s):  
Lionel Laville ◽  
Clarence Charnay ◽  
Frédéric Lamaty ◽  
Jean Martinez ◽  
Evelina Colacino
Keyword(s):  
Micellar Medium ◽  
Ring Closing Metathesis ◽  
Aqueous Micellar Medium

scholarly journals Lipase-catalyzed esterification in water enabled by nanomicelles. Applications to 1-pot multi-step sequences

2022 ◽  
Author(s):  
Bruce Howard Lipshutz ◽  
Vani Singhania ◽  
Margery Cortes-Clerget ◽  
Jade Dussart-Gautheret ◽  
Bhornrawin Akkachairin ◽  
...  
Keyword(s):  
Micellar Medium ◽  
Aqueous Micellar Medium

Esterification in an aqueous micellar medium is catalyzed by a commercially available lipase in the absence of any co-factors. The presence of only 2 wt % designer surfactant, TPGS-750-M, assists...

Sign in / Sign up

Export Citation Format

Share Document