Reversible hydrogen-bonded polymerization regulated by allosteric metal templation

2020 ◽  
Vol 56 (92) ◽  
pp. 14385-14388
Author(s):  
Tangxin Xiao ◽  
Weiwei Zhong ◽  
Weiwei Yang ◽  
Lijie Qi ◽  
Yan Gao ◽  
...  
Keyword(s):  
Cyclic Dimer ◽  
Supramolecular Polymer ◽  
Reversible Transformation ◽  
Self Assembled ◽  
Hydrogen Bonded

A stable quadruple hydrogen bonded cyclic dimer assisted by metal templation was successfully self-assembled and its reversible transformation to supramolecular polymer was investigated.

Supramolecular polymer micelles self-assembled from α -cyclodextrin and PLLA–PCL based copolymers

2011 ◽  
Vol 152 ◽  
pp. e52-e54 ◽  
Author(s):  
Haiqing Dong ◽  
Yongyong Li ◽  
Huiyun Wen ◽  
Donglu Shi ◽  
Lijian Liu
Keyword(s):  
Supramolecular Polymer ◽  
Polymer Micelles ◽  
Self Assembled

Selectivity of guest–host interactions in self-assembled hydrogen-bonded nanostructures observed by NMR

2007 ◽  
Vol 9 (32) ◽  
pp. 4545 ◽  
Author(s):  
Gunther Brunklaus ◽  
Achim Koch ◽  
Daniel Sebastiani ◽  
Hans Wolfgang Spiess
Keyword(s):  
Host Interactions ◽  
Self Assembled ◽  
Hydrogen Bonded

Hydrogen-Bonded Cyclic Dimer Formation in Temperature-Induced Reversal of Tautomerism of Salicylideneanilines

2009 ◽  
Vol 113 (9) ◽  
pp. 1822-1826 ◽  
Author(s):  
Toshikatsu Fujiwara ◽  
Jun Harada ◽  
Keiichiro Ogawa
Keyword(s):  
Cyclic Dimer ◽  
Dimer Formation ◽  
Hydrogen Bonded

scholarly journals Three-Dimensional Self-assembled Hairball-Like VS4 as High-Capacity Anodes for Sodium-Ion Batteries

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Shuangshuang Ding ◽  
Bingxin Zhou ◽  
Changmiao Chen ◽  
Zhao Huang ◽  
Pengchao Li ◽  
...  
Keyword(s):  
Large Scale ◽  
Three Dimensional ◽  
High Capacity ◽  
Sodium Ion ◽  
Ex Situ ◽  
Sodium Ion Batteries ◽  
High Discharge Capacity ◽  
Reversible Transformation ◽  
Self Assembled ◽  
Consistent Performance

AbstractSodium-ion batteries (SIBs) are considered to be attractive candidates for large-scale energy storage systems because of their rich earth abundance and consistent performance. However, there are still challenges in developing desirable anode materials that can accommodate rapid and stable insertion/extraction of Na+ and can exhibit excellent electrochemical performance. Herein, the self-assembled hairball-like VS4 as anodes of SIBs exhibits high discharge capacity (660 and 589 mAh g−1 at 1 and 3 A g−1, respectively) and excellent rate property (about 100% retention at 10 and 20 A g−1 after 1000 cycles) at room temperature. Moreover, the VS4 can also exhibit 591 mAh g−1 at 1 A g−1 after 600 cycles at 0 °C. An unlike traditional mechanism of VS4 for Na+ storage was proposed according to the dates of ex situ characterization, cyclic voltammetry, and electrochemical kinetic analysis. The capacities of the final stabilization stage are provided by the reactions of reversible transformation between Na2S and S, which were considered the reaction mechanisms of Na–S batteries. This work can provide a basis for the synthesis and application of sulfur-rich compounds in fields of batteries, semiconductor devices, and catalysts.

Selective fluorescence sensing of H2PO4− by the anion induced formation of self-assembled supramolecular polymers

2020 ◽  
Vol 18 (20) ◽  
pp. 3858-3866 ◽  
Author(s):  
Paula Sabater ◽  
Fabiola Zapata ◽  
Adolfo Bastida ◽  
Antonio Caballero
Keyword(s):  
Halogen Bonding ◽  
Supramolecular Polymers ◽  
Supramolecular Polymer ◽  
Fluorescence Sensing ◽  
Tripodal Receptor ◽  
Self Assembled

H2PO4− anions induced the formation of a fluorescent supramolecular polymer by halogen bonding interactions in a bromoimidazolium based tripodal receptor.

Synthesis and Crystal Structure of [(CH2)6N4CH3]2[CoCl4]

2002 ◽  
Vol 55 (9) ◽  
pp. 561 ◽  
Author(s):  
W. Li ◽  
S.-L. Zheng ◽  
C.-R. Zhu ◽  
Y.-X. Tong ◽  
X.-M. Chen
Keyword(s):  
Crystal Structure ◽  
Nitrogen Atom ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Chlorine Atoms ◽  
Synthesis And Crystal Structure ◽  
Methylene Groups ◽  
Self Assembled ◽  
Hydrogen Bonded

The interesting three-dimensional hydrogen-bonded self-assembled network of [(CH2)6N4CH3]+ cations and [CoCl4]2– anions has been prepared and structurally characterized. In the title complex, the quaternization of one hexamethylenetetramine nitrogen atom has been trapped, and further stabilized by the large [CoCl4]2– anions, featuring C–H���Cl hydrogen bonds (3.497–3.709 �) between the methylene groups of [(CH2)6N4CH3]+ cations and the chlorine atoms of the [CoCl4]2– anions.

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