Axial Cl/Br atom-mediated CO2 electroreduction performance in a stable porphyrin-based metal–organic framework

2020 ◽  
Vol 56 (94) ◽  
pp. 14817-14820
Author(s):  
Qing Huang ◽  
Qian Niu ◽  
Na-Na Ma ◽  
Long-Zhang Dong ◽  
Shun-Li Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Co2 Electroreduction ◽  
Metal Organic ◽  
Organic Framework

Two isostructural MOFs were utilized to reveal the influence of different halogen anions on ECR performance. The different performance mainly originates from the different abilities of adsorption and activation of CO2 by halogen anions.

Cu(111)@metal-organic framework as a tandem catalyst for highly selective CO2 electroreduction to C2H4

2021 ◽  
Author(s):  
Zhen-Hua Zhao ◽  
Kai Zheng ◽  
Ning-Yu Huang ◽  
Hao-Lin Zhu ◽  
Jiarun Huang ◽  
...  
Keyword(s):  
Catalytic Mechanism ◽  
Metal Organic Framework ◽  
Co2 Electroreduction ◽  
Metal Organic ◽  
Average Size ◽  
Organic Framework

Here, we report an improved tandem catalytic mechanism for electroreduction CO2 to C2H4. Cu(111) nanoparticles with an average size of 5.5 ± 0.9 nm were anchored on a conductive Cu-based...

scholarly journals Cathodized copper porphyrin metal–organic framework nanosheets for selective formate and acetate production from CO2 electroreduction

2019 ◽  
Vol 10 (7) ◽  
pp. 2199-2205 ◽  
Author(s):  
Jian-Xiang Wu ◽  
Shu-Zhen Hou ◽  
Xiang-Da Zhang ◽  
Ming Xu ◽  
Hua-Fei Yang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Acetate Production ◽  
Copper Porphyrin ◽  
Co2 Electroreduction ◽  
Metal Organic ◽  
Organic Framework

Highly selective and effective formate and acetate production from CO2 electroreduction on cathodized metal–organic framework nanosheets.

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

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