Introducing borane clusters into polymeric frameworks: architecture, synthesis, and applications

2020 ◽  
Vol 56 (79) ◽  
pp. 11720-11734
Author(s):  
Jing Yan ◽  
Weihong Yang ◽  
Qiuyu Zhang ◽  
Yi Yan

This feature article summarizes the preparation and applications of borane cluster-containing polymers and covers research progress and future trends of borane cluster-containing linear, dendritic, macrocyclic polymers and metal–organic frameworks.

2020 ◽  
Vol 56 (66) ◽  
pp. 9416-9432 ◽  
Author(s):  
Zhanning Liu ◽  
Lu Zhang ◽  
Daofeng Sun

This feature article mainly summarizes how the structure of MOFs changes under external stimuli.


2019 ◽  
Vol 55 (60) ◽  
pp. 8705-8715 ◽  
Author(s):  
Joshua M. Tuffnell ◽  
Christopher W. Ashling ◽  
Jingwei Hou ◽  
Shichun Li ◽  
Louis Longley ◽  
...  

This Feature Article reviews a range of amorphisation mechanisms of Metal–Organic Frameworks (MOFs) and presents recent advances to produce novel MOF materials including porous MOF glasses, MOF crystal–glass composites, flux melted MOF glasses and blended zeolitic imidazolate framework glasses.


Sensors ◽  
2020 ◽  
Vol 20 (23) ◽  
pp. 6963
Author(s):  
Gennady Evtugyn ◽  
Svetlana Belyakova ◽  
Anna Porfireva ◽  
Tibor Hianik

Metal-organic frameworks (MOFs) offer a unique variety of properties and morphology of the structure that make it possible to extend the performance of existing and design new electrochemical biosensors. High porosity, variable size and morphology, compatibility with common components of electrochemical sensors, and easy combination with bioreceptors make MOFs very attractive for application in the assembly of electrochemical aptasensors. In this review, the progress in the synthesis and application of the MOFs in electrochemical aptasensors are considered with an emphasis on the role of the MOF materials in aptamer immobilization and signal generation. The literature information of the use of MOFs in electrochemical aptasensors is classified in accordance with the nature and role of MOFs and a signal mode. In conclusion, future trends in the application of MOFs in electrochemical aptasensors are briefly discussed.


2019 ◽  
Vol 19 (6) ◽  
pp. 3059-3078 ◽  
Author(s):  
Xinbo Lian ◽  
Leilei Xu ◽  
Mindong Chen ◽  
Cai-e Wu ◽  
Wenjing Li ◽  
...  

The carbon dioxide (CO2) is notorious as the greenhouse gas, which could cause the global warming and climate change. Therefore, the reduction of the atmospheric CO2 emissions from power plants and other industrial facilities has become as an increasingly urgent concern. In the recent years, CO2 capture and storage technologies have received a worldwide attention. Adsorption is considered as one of the efficient options for CO2 capture because of its cost advantage, low energy requirement and extensive applicability over a relatively wide range of temperature and pressure. The metal organic frameworks (MOFs) show widely potential application prospects in CO2 capture and storage owing to their outstanding textural properties, such as the extraordinarily high specific surface area, tunable pore size, ultrahigh porosity (up to 90%), high crystallinity, adjustable internal surface properties, and controllable structure. Herein, the most important research progress of MOFs materials on the CO2 capture and storage in recent years has been comprehensively reviewed. The extraordinary characteristics and CO2 capture performance of Zeolitic Imidazolate Frameworks (ZIFs), Bio-metal organic frameworks (bio-MOFs), IL@MOFs and MOF-composite materials were highlighted. The promising strategies for improving the CO2 adsorption properties of MOFs materials, especially the low-pressure adsorption performance under actual flue gas conditions, are also carefully summarized. Besides, CO2 is considered as an abundant, nontoxic, nonflammable, and renewable C1 resource for the synthesis of useful chemicals and fuels. The potential routes for resource utilization of the captured CO2 are briefly proposed.


2020 ◽  
Vol 78 (7) ◽  
pp. 613 ◽  
Author(s):  
Ye Qi ◽  
Shuangsong Ren ◽  
Ying Che ◽  
Junwei Ye ◽  
Guiling Ning

2020 ◽  
Vol 56 (82) ◽  
pp. 12290-12306 ◽  
Author(s):  
Shanghua Xing ◽  
Christoph Janiak

This feature article reviews the design strategies by which multiple different emission sources could be combined for creating multi-emitter luminescent metal–organic frameworks (LMOFs).


2017 ◽  
Vol 53 (79) ◽  
pp. 10851-10869 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Abdullah M. Asiri ◽  
Hermenegildo Garcia

This Feature article describes on the recent developments in the use of metal organic frameworks as heterogeneous solid catalysts for the selective alcohol oxidation by either tuning the actives sites around the metal centre, or anchoring them on the ligands or using the pores to embed metal nanoparticles inside.


Carbon ◽  
2021 ◽  
Vol 179 ◽  
pp. 702
Author(s):  
Qian Zhang ◽  
Chun-feng Xue ◽  
Jin-xin Wang ◽  
Rui-chao Huang ◽  
H.A.O. Xiao-gang ◽  
...  

2020 ◽  
Vol 51 (2) ◽  
pp. 165-174
Author(s):  
Zhen Zhao ◽  
Hang Zhang ◽  
Sisi Zhao ◽  
Baiming Zhang ◽  
Chenyang Yue

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