Novel method for preparing stable near-infrared absorbers: a new phthalocyanine family based on rhenium(i) complexes

2020 ◽  
Vol 56 (89) ◽  
pp. 13760-13763
Author(s):  
Kei Murata ◽  
Yosuke Koike ◽  
Kazuyuki Ishii

Unsymmetric coordination of the electron-deficient Re(i) unit(s) to the phthalocyanine ring concomitantly realized intense absorption in the near-infrared region and the improvement of tolerance to oxidation.

2011 ◽  
Vol 15 (11n12) ◽  
pp. 1195-1201 ◽  
Author(s):  
Stanislav A. Trashin ◽  
Tatiana V. Dubinina ◽  
Aleksander V. Fionov ◽  
Larisa G. Tomilova

The electrochemical and spectroelectrochemical behavior of two planar binuclear naphthalocyanines containing benzene and naphthalene π-conjugated bridges was investigated for the first time. Their intense absorption in the near infrared region was observed even in a low polar solvent such as o-dichlorobenzene after electrochemical reduction at a potential of -0.4 V vs. SCE, which was not enough to reduce the complexes into their first reduction state. These data and EPR studies allow us to conclude that the electrochemically generated form is the true neutral form of the synthesized compounds whereas the suppression of the near-infrared bands is a result of the presence of their cation radicals as one-electron oxidized forms.


2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...


Author(s):  
Cong Shen ◽  
Yan Qing Zhu ◽  
Zixiao Li ◽  
Jingling Li ◽  
Hong Tao ◽  
...  

InP quantum dots (QDs) are considered as the most promising alternative to Cd-based QDs with the lower toxicity and emission spectrum tunability ranging from visible to near-infrared region. Although high-quality...


LWT ◽  
2021 ◽  
Vol 143 ◽  
pp. 111092
Author(s):  
Jose Marcelino S. Netto ◽  
Fernanda A. Honorato ◽  
Patrícia M. Azoubel ◽  
Louise E. Kurozawa ◽  
Douglas F. Barbin

Nanoscale ◽  
2020 ◽  
Vol 12 (41) ◽  
pp. 21459-21459
Author(s):  
Charlotte Marshall

Retraction of ‘Water-soluble multidentate polymers compactly coating Ag2S quantum dots with minimized hydrodynamic size and bright emission tunable from red to second near-infrared region’ by Rijun Gui et al., Nanoscale, 2014, 6, 5467–5473, DOI: 10.1039/C4NR00282B.


2019 ◽  
Vol 10 (25) ◽  
pp. 6330-6335 ◽  
Author(s):  
Jinhu Wang ◽  
Yinhua Yang ◽  
Hua Li ◽  
Jun Gao ◽  
Ping He ◽  
...  

Preparation of color-tunable and stable plasmonic MoO3 nanomaterials remains challenging, due to the lack of an effective preparation strategy and surface protection in heavily doped MoO3.


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