scholarly journals Role of electrolyte composition on the acid stability of mixed-metal oxygen evolution catalysts

2020 ◽  
Vol 56 (72) ◽  
pp. 10477-10480
Author(s):  
Nancy Li ◽  
Thomas P. Keane ◽  
Samuel S. Veroneau ◽  
Daniel G. Nocera

Acid stability in catalysts that promote the oxygen evolution reaction (OER) involves an interplay between electrolyte and catalyst composition, both of which must be judiciously selected in order to promote activity and durability.

2018 ◽  
Vol 6 (12) ◽  
pp. 16255-16266 ◽  
Author(s):  
Gaurav M. Thorat ◽  
Harsharaj S. Jadhav ◽  
Animesh Roy ◽  
Wook-Jin Chung ◽  
Jeong Gil Seo

2021 ◽  
Vol 514 ◽  
pp. 230596
Author(s):  
Abdelhadi El Jaouhari ◽  
Amine Slassi ◽  
Bowen Zhang ◽  
Anton Pershin ◽  
Wei Liu ◽  
...  

2021 ◽  
Vol 280 ◽  
pp. 119433 ◽  
Author(s):  
Eom-Ji Kim ◽  
Jaewook Shin ◽  
Junu Bak ◽  
Sang Jae Lee ◽  
Ki hyun Kim ◽  
...  

2014 ◽  
Vol 126 (49) ◽  
pp. 13622-13626 ◽  
Author(s):  
Beniamino Iandolo ◽  
Anders Hellman

Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 263 ◽  
Author(s):  
Bae-Jung Kim ◽  
Emiliana Fabbri ◽  
Ivano Castelli ◽  
Mario Borlaf ◽  
Thomas Graule ◽  
...  

Perovskite oxides have been gaining attention for its capability to be designed as an ideal electrocatalyst for oxygen evolution reaction (OER). Among promising candidates, the layered double perovskite—PrBaCo2O6-δ (PBC)—has been identified as the most active perovskite electrocatalyst for OER in alkaline media. For a single transition metal oxide catalyst, the addition of Fe enhances its electrocatalytic performance towards OER. To understand the role of Fe, herein, Fe is incorporated in PBC in different ratios, which yielded PrBaCo2(1-x)Fe2xCo6-δ (x = 0, 0.2 and 0.5). Fe-doped PBCF’s demonstrate enhanced OER activities and stabilities. Operando X-ray absorption spectroscopy (XAS) revealed that Co is more stable in a lower oxidation state upon Fe incorporation by establishing charge stability. Hence, the degradation of Co is inhibited such that the perovskite structure is prolonged under the OER conditions, which allows it to serve as a platform for the oxy(hydroxide) layer formation. Overall, our findings underline synergetic effects of incorporating Fe into Co-based layered double perovskite in achieving a higher activity and stability during oxygen evolution reaction.


2018 ◽  
Vol 10 (32) ◽  
pp. 26825-26829 ◽  
Author(s):  
Marija R. Zoric ◽  
Usha Pandey Kadel ◽  
Ksenija D. Glusac

2019 ◽  
Vol 2 (5) ◽  
pp. 3488-3499 ◽  
Author(s):  
Jon G. Baker ◽  
Joel R. Schneider ◽  
Jose A. Garrido Torres ◽  
Joseph A. Singh ◽  
Adriaan J. M. Mackus ◽  
...  

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