Synergetic effect of H+ adsorption and ethylene functional groups of covalent organic frameworks on the CO2 photoreduction in aqueous solution

2020 ◽  
Vol 56 (53) ◽  
pp. 7261-7264 ◽  
Author(s):  
Jie Zhou ◽  
Jin-Xian Cui ◽  
Man Dong ◽  
Chun-Yi Sun ◽  
Si-Qi You ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Functional Groups ◽  
Synergetic Effect ◽  
Covalent Organic Frameworks ◽  
Co2 Photoreduction

A new COF synthesized for reduction of CO2 in aqueous solution and recognition of the new role of H+ in the reduction of CO2.

Visible-light-driven photocatalytic CO2 reduction over ketoenamine-based covalent organic frameworks: role of the host functional groups

2021 ◽  
Author(s):  
Lianlian Peng ◽  
Shuqing Chang ◽  
Ziling Liu ◽  
Yanghe Fu ◽  
Rui Ma ◽  
...  
Keyword(s):  
Visible Light ◽  
Functional Groups ◽  
Charge Separation ◽  
Photocatalytic Performance ◽  
Co2 Reduction ◽  
Covalent Organic Frameworks ◽  
Visible Light Driven ◽  
Photogenerated Charge Separation ◽  
Electron Donating Groups

Compared to the electron-withdrawing groups, the electron-donating groups in TpBD can accelerate the photogenerated charge separation and transfer, thereby improving the photocatalytic performance for photocatalytic CO2 reduction.

The Role of Nanoporous Biochars Functional Groups for Immobilization of Heavy Metals in Aqueous Solution

2016 ◽  
Vol 860 ◽  
pp. 43-46 ◽  
Author(s):  
Ahmad Khodadadi Darban ◽  
Hoda Arabyarmohammadi ◽  
Mahmoud Abdollahy ◽  
Bita Ayati
Keyword(s):  
Heavy Metals ◽  
Aqueous Solution ◽  
Functional Groups ◽  
Residual Fraction ◽  
Nanoporous Structure ◽  
Ftir Analysis ◽  
Batch Experiments ◽  
Metal System ◽  
Sorption Mechanism

The affinity of nanoporous biochars functional groups for immobilization Cu, Zn, and Pb in aqueous solution has been studied. BET results revealed the nanoporous structure of the chars. Batch experiments have been designed and performed.The results indicated remarkable sorption capacity in case of each char: in a multi-metal system, B1, B2, and B3 adorbed 24.39, 23.61, 35.69 mg/g copper, 63.36, 90.96, 95.36 mg/g lead, and 20.16, 21.26, and 25.44 mg/g zinc, respectively. To find out the sorption mechanism with a post-sorption FTIR analysis over the biochars has been made. The results suggest the possible competitive immobilization mechanism as Cu being mainly organically bounded to amino, hydroxyl and carboxyl functional groups, Pb forming insoluble hydroxide, phosphate or carbonate, and Zn being mostly sorbed in the residual fraction.

Role of functional groups on protonated de-oiled soybean involved in triclosan biosorption from aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 67319-67330 ◽  
Author(s):  
Jing-Feng Gao ◽  
Chun-Ying Si ◽  
Hong-Yu Li
Keyword(s):  
Aqueous Solution ◽  
Chemical Modification ◽  
Functional Groups

The contribution of functional groups such as amine, carboxyl, sulfhydryl, phosphate and lipids on protonated de-oiled soybean (PDOS) to triclosan (TCS) biosorption was evaluated by means of chemical modification.

Environmental DNA for functional diversity

2018 ◽  
Author(s):  
Pierre Taberlet ◽  
Aurélie Bonin ◽  
Lucie Zinger ◽  
Eric Coissac
Keyword(s):  
Functional Groups ◽  
Functional Diversity ◽  
Environmental Dna ◽  
Soil Organisms ◽  
Meaningful Information ◽  
Dna Metabarcoding ◽  
Pros And Cons ◽  
Target Community

Chapter 10 “Environmental DNA for functional diversity” discusses the potential of environmental DNA to assess functional diversity. It first focuses on DNA metabarcoding and discusses the extent to which this approach can be used and/or optimized to retrieve meaningful information on the functions of the target community. This knowledge usually involves coarsely defined functional groups (e.g., woody, leguminous, graminoid plants; shredders or decomposer soil organisms; pathogenicity or decomposition role of certain microorganisms). Chapter 10 then introduces metagenomics and metatranscriptomics approaches, their advantages, but also the challenges and solutions to appropriately sampling, sequencing these complex DNA/RNA populations. Chapter 10 finally presents several strategies and software to analyze metagenomes/metatranscriptomes, and discusses their pros and cons.

scholarly journals The Role of Peptides in the Design of Electrochemical Biosensors for Clinical Diagnostics

Biosensors ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 246
Author(s):  
Patrick Severin Sfragano ◽  
Giulia Moro ◽  
Federico Polo ◽  
Ilaria Palchetti
Keyword(s):  
Functional Groups ◽  
Synthetic Peptides ◽  
Clinical Diagnostics ◽  
Electrochemical Biosensors ◽  
Practical Application ◽  
Design And Development ◽  
Electrode Surfaces ◽  
Electrochemical Transducers ◽  
Target Analyte

Peptides represent a promising class of biorecognition elements that can be coupled to electrochemical transducers. The benefits lie mainly in their stability and selectivity toward a target analyte. Furthermore, they can be synthesized rather easily and modified with specific functional groups, thus making them suitable for the development of novel architectures for biosensing platforms, as well as alternative labelling tools. Peptides have also been proposed as antibiofouling agents. Indeed, biofouling caused by the accumulation of biomolecules on electrode surfaces is one of the major issues and challenges to be addressed in the practical application of electrochemical biosensors. In this review, we summarise trends from the last three years in the design and development of electrochemical biosensors using synthetic peptides. The different roles of peptides in the design of electrochemical biosensors are described. The main procedures of selection and synthesis are discussed. Selected applications in clinical diagnostics are also described.

Microscopic Insights into Water Adsorption in Carbon Nanopore – The Role of Acidic and Basic Functional Groups and their Configurations

2021 ◽  
Author(s):  
Lumeng Liu ◽  
Wenmao Zeng ◽  
Shiliang Johnathan Tan ◽  
Meng Liu ◽  
Duong Do
Keyword(s):  
Functional Groups ◽  
Porous Carbon ◽  
Water Adsorption ◽  
Water Clusters ◽  
Pivotal Role

Functional groups (FGs) in porous carbon play a pivotal role in water adsorption by nucleating water clusters followed by their coalescence, the process for which is the precursor for the...

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