scholarly journals Concerted proton–electron transfer reactions of manganese–hydroxo and manganese–oxo complexes

2020 ◽  
Vol 56 (65) ◽  
pp. 9238-9255
Author(s):  
Jaycee R. Mayfield ◽  
Elizabeth N. Grotemeyer ◽  
Timothy A. Jackson
Keyword(s):  
Electron Transfer ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Structure Activity Relationships ◽  
Oxo Complexes ◽  
Structure Activity

Studies of MnIII–hydroxo and MnIV–oxo complexes that feature systematically perturbed ligand environments permit elucidation of structure–activity relationships that enhance our understanding of CPET processes in biological and synthetic systems.

Electron transfer and catalysis with high-valent metal-oxo complexes

2015 ◽  
Vol 44 (15) ◽  
pp. 6696-6705 ◽  
Author(s):  
Shunichi Fukuzumi
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Oxo Complexes ◽  
High Valent

High-valent metal-oxo complexes are produced by thermal and photoinduced electron-transfer reactions, acting as catalysts for oxygenation of substrates using water or dioxygen as an oxygen source.

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