Solvent triggering structural changes for two terbium-based metal–organic frameworks and their photoluminescence sensing

2020 ◽  
Vol 56 (31) ◽  
pp. 4320-4323 ◽  
Author(s):  
Dan Yue ◽  
Yanyan Wang ◽  
Dong Chen ◽  
Zhenling Wang
Keyword(s):  
Structural Changes ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Metal Organic

TbPDBA-8 and TbPDBA-9 have been obtained based on the same ligand, and have different structures and luminescence properties.

A series of europium-based metal organic frameworks with tuned intrinsic luminescence properties and detection capacities

RSC Advances ◽  
2016 ◽  
Vol 6 (113) ◽  
pp. 111934-111941 ◽  
Author(s):  
Pengda Yi ◽  
Hongliang Huang ◽  
Yaguang Peng ◽  
Dahuan Liu ◽  
Chongli Zhong
Keyword(s):  
Functional Groups ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Intrinsic Luminescence ◽  
Metal Organic

A series of europium-based metal organic frameworks with different functional groups showed tuned intrinsic luminescence properties and detection capacities.

Flexible luminescent non-lanthanide metal–organic frameworks as small molecules sensors

2021 ◽  
Author(s):  
Sajal Khatua ◽  
Chidharth Krishnaraj ◽  
Debendra Chandra Baruah ◽  
Pascal Van Der Voort ◽  
Himanshu Sekhar Jena
Keyword(s):  
Small Molecules ◽  
Small Molecule ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Flexible Structure ◽  
Metal Organic ◽  
Lanthanide Metal

Non-lanthanide metal–organic frameworks with flexible structure and luminescence properties are systematically discussed as potential small molecule sensors.

Long and local range structural changes in M[(bdc)(ted)0.5] (M = Zn, Ni or Cu) metal organic frameworks upon spontaneous thermal dispersion of LiCl and adsorption of carbon dioxide

2015 ◽  
Vol 212 ◽  
pp. 8-17 ◽  
Author(s):  
Jennifer Guerrero-Medina ◽  
Génesis Mass-González ◽  
Leonardo Pacheco-Londoño ◽  
Samuel P. Hernández-Rivera ◽  
Riqiang Fu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Structural Changes ◽  
Metal Organic Frameworks ◽  
Thermal Dispersion ◽  
Metal Organic ◽  
Local Range

Tuning Packing, Structural Flexibility, and Porosity in 2D Metal–Organic Frameworks by Metal Node Choice

2019 ◽  
Vol 72 (10) ◽  
pp. 797 ◽  
Author(s):  
Witold M. Bloch ◽  
Christian J. Doonan ◽  
Christopher J. Sumby
Keyword(s):  
Structural Changes ◽  
Metal Organic Frameworks ◽  
Chemical Properties ◽  
Complete Removal ◽  
Structural Flexibility ◽  
X Ray Diffraction ◽  
Metal Centre ◽  
Metal Organic ◽  
Physical And Chemical ◽  
And Chemical Properties

Understanding the key features that determine structural flexibility in metal–organic frameworks (MOFs) is key to exploiting their dynamic physical and chemical properties. We have previously reported a 2D MOF material, CuL1, comprising five-coordinate metal nodes that displays exceptional CO2/N2 selectively (L1=bis(4-(4-carboxyphenyl)-1H-pyrazolyl)methane). Here we examine the effect of utilising six-coordinate metal centres (CoII and NiII) in the synthesis of isostructural MOFs from L1, namely CoL1 and NiL1. The octahedral geometry of the metal centre within the MOF analogues precludes an ideal eclipse of the 2D layers, resulting in an offset stacking, and in certain cases, the formation of 2-fold interpenetrated analogues β-CoL1 and β-NiL1. We used a combination of thermogravimetric analysis (TGA), and powder and single crystal X-ray diffraction (PXRD and SCXRD) to show that desolvation is accompanied by a structural change for NiL1, and complete removal of the coordinated H2O ligands results in a reduction in long-range order. The offset nature of the 2D layers in combination with the structural changes impedes the adsorption of meaningful quantities of gases (N2, CO2), highlighting the importance of a five-coordinate metal centre in achieving optimal pore accessibility for this family of flexible materials.

Stimuli-responsive structural changes in metal–organic frameworks

2020 ◽  
Vol 56 (66) ◽  
pp. 9416-9432 ◽  
Author(s):  
Zhanning Liu ◽  
Lu Zhang ◽  
Daofeng Sun
Keyword(s):  
Structural Changes ◽  
Metal Organic Frameworks ◽  
Stimuli Responsive ◽  
Feature Article ◽  
Metal Organic ◽  
External Stimuli

This feature article mainly summarizes how the structure of MOFs changes under external stimuli.

scholarly journals New insights into solvent-induced structural changes of 13C labelled metal–organic frameworks by solid state NMR

2019 ◽  
Vol 55 (62) ◽  
pp. 9140-9143 ◽  
Author(s):  
Marcus Rauche ◽  
Sebastian Ehrling ◽  
Simon Krause ◽  
Irena Senkovska ◽  
Stefan Kaskel ◽  
...  
Keyword(s):  
Solid State Nmr ◽  
Structural Changes ◽  
Metal Organic Frameworks ◽  
Site Specific ◽  
Isotope Labelling ◽  
Specific Host ◽  
Depth Analysis ◽  
Adsorption Complexes ◽  
Metal Organic ◽  
Labelling Scheme

The proposed 13C isotope-labelling scheme enables the in-depth analysis of site-specific host–guest interactions and adsorption complexes formed in MOFs.

A series of 3D metal organic frameworks based on [24-MC-6] metallacrown clusters: structure, magnetic and luminescence properties

2014 ◽  
Vol 43 (34) ◽  
pp. 12989 ◽  
Author(s):  
Kai Wang ◽  
Hua-Hong Zou ◽  
Zi-Lu Chen ◽  
Zhong Zhang ◽  
Wei-Yin Sun ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Metal Organic

Structure, Hydrogen Storage, and Luminescence Properties of Three 3D Metal−Organic Frameworks with NbO and PtS Topologies

2008 ◽  
Vol 8 (7) ◽  
pp. 2478-2483 ◽  
Author(s):  
Ming Xue ◽  
Guangshan Zhu ◽  
Yangxue Li ◽  
Xiaojun Zhao ◽  
Zhao Jin ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Metal Organic
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