CL.—Studies of the carbonates. Part I. The equilibrium between calcium carbonate and carbonic acid

1909 ◽  
Vol 95 (0) ◽  
pp. 1347-1352 ◽  
Author(s):  
Clarence Arthur Seyler ◽  
Percy Vivian Lloyd
1985 ◽  
Vol 22 (3) ◽  
pp. 335-346 ◽  
Author(s):  
Ghislain Lessard ◽  
James K. Mitchell

The physicochemical properties of a clay from La Baie, Quebec were found to be typical of Champlain quick clays: very low plasticity, liquidity index greater than 3, sensitivity greater than 500, and pH of about 9.5. The mineralogy is characterized by the abundance of primary or "rock flour" minerals such as feldspar, quartz, amphibole, and calcite, with illite as the principal clay mineral. The pore water chemistry consists predominantly of sodium bicarbonate. Low concentrations of sulfate, calcium, and magnesium and high alkalinity and pH are attributed, in part, to anaerobic sulfate-reduction processes taking place in situ.Quick clay samples stored in the laboratory showed signs of aging regardless of the storage procedure. The remoulded strength and the liquid limit increased with time, whereas the sensitivity, the liquidity index, and the pH decreased. The water content, plastic limit, and undisturbed strength remained practically unchanged. The pore water concentrations of calcium, magnesium, and sulfate increased by severalfold.The aging phenomenon is attributed, for the most part, to the oxidation of iron sulfide, which results in the formation of iron hydroxide and sulfuric acid. The production of acid causes the dissolution of calcium carbonate, which increases the concentration of divalent cation in the clay, thereby reducing interparticle repulsion and increasing the remoulded strength. The oxidation of organic matter, resulting in the formation of carbonic acid, also contributes to the aging by its effect on the solubility of calcium carbonate. Key words: aging, chemical reactions, physicochemical phenomena, sensitivity, time effects.


2013 ◽  
Vol 357-360 ◽  
pp. 635-640 ◽  
Author(s):  
Zun Qun Xiao ◽  
Cai Yun Xu ◽  
Guo Dong Wu

The change law of gel time of calcium carbonate-acid water glass grouting material with the content of calcium carbonate is researched in this paper. But the gel time does not increase evenly with reduction calcium carbonic reducing. It increases suddenly because there is sudden exceeding range with the solution pH value increasing. Meanwhile, the change relation of strength of pure gelation with suitable gel time and time is measured. Firming sand strength experiment is conducted by the better mixture ratio. The strength of pure gelation body increases with the time and the content of calcium carbonate increasing. It is closely related with the reaction mechanism of calcium carbonate-acid water glass. The active Ca2+in this system can react with a series of silicate ion to form silicate precipitate which is filled with colloid and forming skeletonation. And the correlation between firming sand strength and the calcium carbonic acid content is non-significant. Finally, the contrast test of the water glass-glyoxal is done, which is the preparation for the subsequent engineering application.


Author(s):  
S. Q. Xiao ◽  
S. Baden ◽  
A. H. Heuer

The avian eggshell is one of the most rapidly mineralizing biological systems known. In situ, 5g of calcium carbonate are crystallized in less than 20 hrs to fabricate the shell. Although there have been much work about the formation of eggshells, controversy about the nucleation and growth mechanisms of the calcite crystals, and their texture in the eggshell, still remain unclear. In this report the microstructure and microchemistry of avian eggshells have been analyzed using transmission electron microscope (TEM) and energy dispersive spectroscopy (EDS).Fresh white and dry brown eggshells were broken and fixed in Karnosky's fixative (kaltitanden) for 2 hrs, then rinsed in distilled H2O. Small speckles of the eggshells were embedded in Spurr medium and thin sections were made ultramicrotome.The crystalline part of eggshells are composed of many small plate-like calcite grains, whose plate normals are approximately parallel to the shell surface. The sizes of the grains are about 0.3×0.3×1 μm3 (Fig.l). These grains are not as closely packed as man-made polycrystalline metals and ceramics, and small gaps between adjacent grains are visible indicating the absence of conventional grain boundaries.


1887 ◽  
Vol 24 (613supp) ◽  
pp. 9785-9785
Author(s):  
Thomas C. Van Nuys ◽  
Benjamin F. Adams
Keyword(s):  

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