scholarly journals XXXIII.—The influence of temperature on the heat of dissolution of salts

1887 ◽  
Vol 51 (0) ◽  
pp. 290-356 ◽  
Author(s):  
Spencer Umfreville Pickering
1885 ◽  
Vol 38 (235-238) ◽  
pp. 401-414

The experiments described in this paper were undertaken in the hope of obtaining some light upon the vexed question of the condition in which a solid exists when dissolved in a liquid, and were directed more especially towards the investigation of the well-known remarkable phenomena exhibited by sodium sulphate. Crystallised sodium sulphate melts at about 34°, and at this temperature the salt begins to show signs of dissociation by depositing the anhydrous compound. According to Wiedemann, indeed, indications of change are observable at a few degrees lower. He finds by observation of the volume of the crystallised salt at different temperatures, that whereas slight expansion occurs from 17° to about 30°, contraction then sets in, at first slowly, then, at 33° to 34°, very rapidly, till the salt melts. The melted salt expands regularly in proportion as the temperature is raised to near 100°. Nicol has made experiments upon the expansion of solutions of the same salt, and with similar results.


Author(s):  
T. Geipel ◽  
W. Mader ◽  
P. Pirouz

Temperature affects both elastic and inelastic scattering of electrons in a crystal. The Debye-Waller factor, B, describes the influence of temperature on the elastic scattering of electrons, whereas the imaginary part of the (complex) atomic form factor, fc = fr + ifi, describes the influence of temperature on the inelastic scattering of electrons (i.e. absorption). In HRTEM simulations, two possible ways to include absorption are: (i) an approximate method in which absorption is described by a phenomenological constant, μ, i.e. fi; - μfr, with the real part of the atomic form factor, fr, obtained from Hartree-Fock calculations, (ii) a more accurate method in which the absorptive components, fi of the atomic form factor are explicitly calculated. In this contribution, the inclusion of both the Debye-Waller factor and absorption on HRTEM images of a (Oll)-oriented GaAs crystal are presented (using the EMS software.Fig. 1 shows the the amplitudes and phases of the dominant 111 beams as a function of the specimen thickness, t, for the cases when μ = 0 (i.e. no absorption, solid line) and μ = 0.1 (with absorption, dashed line).


2010 ◽  
Vol 25 (1) ◽  
pp. 93-105 ◽  
Author(s):  
Daniel Żarski ◽  
Dariusz Kucharczyk ◽  
Wojciech Sasinowski ◽  
Katarzyna Targońska ◽  
Andrzej Mamcarz

1930 ◽  
Vol 64 (695) ◽  
pp. 570-574 ◽  
Author(s):  
Leo Ferry ◽  
N. I. Shapiro ◽  
B. N. Sidoroff

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