Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions

1996 ◽  
pp. 2431-2432 ◽  
Author(s):  
Gareth A. Cairns ◽  
Nicholas Carr ◽  
Michael Green ◽  
Mary F. Mahon
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Insertion Reactions ◽  
Alkyne Insertion

scholarly journals C—C Triple Bond Cleavage/Rearrangement Reaction for Accessing 2,4,4-Trichloronaphthalen-1(4H)-ones

2019 ◽  
Vol 39 (4) ◽  
pp. 1095 ◽  
Author(s):  
Wenjie Jiang ◽  
Yating Song ◽  
Xiaojing Wei ◽  
Yi Xu ◽  
Juan Lu ◽  
...  
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Rearrangement Reaction

scholarly journals Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides

2020 ◽  
Vol 11 (44) ◽  
pp. 12095-12102
Author(s):  
Dionisio Poveda ◽  
Ángela Vivancos ◽  
Delia Bautista ◽  
Pablo González-Herrero
Keyword(s):  
Visible Light ◽  
Addition Reactions ◽  
Insertion Reactions ◽  
Photochemical Generation ◽  
Visible Light Driven ◽  
Alkyne Insertion

The photochemical generation of isolable bis-cyclometalated Pt(iv) hydrides via photooxidative C–H addition reactions is demonstrated from easily accessible Pt(ii) precursors using visible light.

scholarly journals Ruthenium-catalyzed cascade C–H activation/annulation of N-alkoxybenzamides: reaction development and mechanistic insight

2020 ◽  
Vol 11 (42) ◽  
pp. 11562-11569
Author(s):  
Liangliang Song ◽  
Xiaoyong Zhang ◽  
Xiao Tang ◽  
Luc Van Meervelt ◽  
Johan Van der Eycken ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Mechanistic Insight ◽  
Alkyne Insertion

A highly selective ruthenium-catalyzed C–H activation/annulation through a pathway involving N–O bond cleavage prior to alkyne insertion is developed.

Palladium/copper tandem catalysis for carbon–carbon triple bond cleavage of diaryl acetylenes

2015 ◽  
Vol 56 (40) ◽  
pp. 5449-5452 ◽  
Author(s):  
Zhiwei Wang ◽  
Wenyou Fan ◽  
Guo-Jun Deng ◽  
Wang Zhou
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Tandem Catalysis ◽  
Diaryl Acetylenes

Cu-mediated nitrogen atom transfer via CN bond cleavage

2015 ◽  
Vol 13 (39) ◽  
pp. 9948-9952 ◽  
Author(s):  
Lixin Liu ◽  
Jianyu Dong ◽  
Yaxing Zhang ◽  
Yongbo Zhou ◽  
Shuang-Feng Yin
Keyword(s):  
Nitrogen Atom ◽  
Triple Bond ◽  
Organic Molecules ◽  
Bond Cleavage ◽  
Atom Transfer ◽  
Aryl Nitriles

A nitrogen atom transfer to organic molecules affording aryl nitriles via Cu-mediated C–N triple bond cleavage is firstly developed.

Palladium-Catalyzed C–C Triple Bond Cleavage: Efficient Synthesis of 4H-Benzo[d][1,3]oxazin-4-ones

ACS Catalysis ◽  
2013 ◽  
Vol 3 (2) ◽  
pp. 178-181 ◽  
Author(s):  
Qilun Liu ◽  
Pinhong Chen ◽  
Guosheng Liu
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Efficient Synthesis ◽  
Palladium Catalyzed

Alkene and Alkyne Insertion Reactions with Tantalum Metallacarborane Complexes:  the Et2C2B4H42-Carborane Ligand as a Spectator and Participant1

1998 ◽  
Vol 17 (18) ◽  
pp. 3865-3874 ◽  
Author(s):  
Eric Boring ◽  
Michal Sabat ◽  
M. G. Finn ◽  
Russell N. Grimes
Keyword(s):  
Insertion Reactions ◽  
Carborane Ligand ◽  
Alkyne Insertion
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