Preparation of some new anomeric carbohydrate difluoromethylenephosphonates via phosphonyl radical addition to gem-difluoroenol ethers

1996 ◽  
pp. 613 ◽  
Author(s):  
Timoth�e F. Herpin ◽  
J. Sarah Houlton ◽  
William B. Motherwell ◽  
Brian P. Roberts ◽  
Jean-Marc Weibel
Keyword(s):  
Radical Addition ◽  
Phosphonyl Radical

Phosphonyl Radical Addition to Enol Ethers. The Stereoselective Synthesis of Cyclic Ethers.

ChemInform ◽  
2004 ◽  
Vol 35 (40) ◽  
Author(s):  
Christopher M. Jessop ◽  
Andrew F. Parsons ◽  
Anne Routledge ◽  
Derek J. Irvine
Keyword(s):  
Stereoselective Synthesis ◽  
Radical Addition ◽  
Cyclic Ethers ◽  
Enol Ethers ◽  
Phosphonyl Radical

Manganese(iii)-mediated alkenyl Csp2–P bond formation from the reaction of β-nitrostyrenes with dialkyl phosphites

2015 ◽  
Vol 13 (17) ◽  
pp. 4896-4902 ◽  
Author(s):  
Jian-Fei Xue ◽  
Shao-Fang Zhou ◽  
Ye-Ye Liu ◽  
Xiangqiang Pan ◽  
Jian-Ping Zou ◽  
...  
Keyword(s):  
Bond Formation ◽  
Radical Addition ◽  
Dialkyl Phosphites ◽  
Phosphonyl Radical

Mn(OAc)3-mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form (E)-2-alkenyl phosphonates is described.

Phosphonyl radical addition to enol ethers. The stereoselective synthesis of cyclic ethers

2004 ◽  
Vol 45 (26) ◽  
pp. 5095-5098 ◽  
Author(s):  
Christopher M. Jessop ◽  
Andrew F. Parsons ◽  
Anne Routledge ◽  
Derek J. Irvine
Keyword(s):  
Stereoselective Synthesis ◽  
Radical Addition ◽  
Cyclic Ethers ◽  
Enol Ethers ◽  
Phosphonyl Radical

Novel regio- and stereoselective phosphonyl radical addition to glycals promoted by Mn(ii)–air: syntheses of 1,2-dideoxy 2-C-diphenylphosphinylglycopyranosides

2014 ◽  
Vol 50 (16) ◽  
pp. 2046-2048 ◽  
Author(s):  
Fuyi Zhang ◽  
Liming Wang ◽  
Cui Zhang ◽  
Yufen Zhao
Keyword(s):  
Radical Reaction ◽  
Radical Addition ◽  
The Novel ◽  
Diphenylphosphine Oxide ◽  
Phosphonyl Radical

The novel Mn(ii)–air promoted radical reaction of diphenylphosphine oxide with various glycals in excellent regio- and stereoselectivities generated 1,2-dideoxy-2-C-diphenylphosphinylglycopyranosides.

ChemInform Abstract: Preparation of Some New Anomeric Carbohydrate Difluoromethylenephoshonates via Phosphonyl Radical Addition to gem- Difluoroenol Ethers.

ChemInform ◽  
2010 ◽  
Vol 27 (29) ◽  
pp. no-no
Author(s):  
T. F. HERPIN ◽  
J. S. HOULTON ◽  
W. B. MOTHERWELL ◽  
B. P. ROBERTS ◽  
J.-M. WEIBEL
Keyword(s):  
Radical Addition ◽  
Phosphonyl Radical
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