Accurate estimation of the photoelectric conversion efficiency of a series of anthracene-based organic dyes for dye-sensitized solar cells

2020 ◽  
Vol 8 (7) ◽  
pp. 2388-2399 ◽  
Author(s):  
Panpan Heng ◽  
Lemin Mao ◽  
Xugeng Guo ◽  
Li Wang ◽  
Jinglai Zhang
Keyword(s):  
Solar Cells ◽  
Optical Absorption ◽  
Organic Dyes ◽  
Dye Sensitized Solar Cells ◽  
Accurate Estimation ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Studies demonstrate that our designed dyes 3 and 4 exhibit broad optical absorption in the 550–650 nm region and high photoelectric conversion efficiencies of over 32%.

scholarly journals Computational Prediction of Electronic and Photovoltaic Properties of Anthracene-Based Organic Dyes for Dye-Sensitized Solar Cells

2018 ◽  
Vol 2018 ◽  
pp. 1-17 ◽  
Author(s):  
Hongbo Wang ◽  
Qian Liu ◽  
Dejiang Liu ◽  
Runzhou Su ◽  
Jinglin Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Density Functional ◽  
Organic Dyes ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Photoelectric Properties ◽  
Sensitized Solar Cells

Three kinds of anthracene-based organic dyes for dye-sensitized solar cells (DSSCs) were studied, and their structures are based on a push–pull framework with anthracenyl diphenylamine as the donor connected to a carboxyphenyl or carboxyphenyl-bromothiazole (BTZ) as the acceptor via an acetylene bridge. The photoelectric properties of the three dyes were investigated using density functional theory (DFT). The simulations indicate that the improvement of anthracene-based dyes (the addition of BTZ and the change of alkyl groups to alkoxy chains) can reduce the energy gap and produce a red shift. This structural modification also improves the light capturing and the electron injection capability, making it excellent in photoelectric conversion efficiency (PCE). In addition, twelve molecules have been designed to regulate photovoltaic performance.

POTENTIAL EVALUATION OF YELLOW COTTON (COCHLOSPERMUM REGIUM) PIGMENTS FOR DYE SENSITIZED SOLAR CELLS APPLICATION

2020 ◽  
pp. 16-21
Author(s):  
PHITCHAPHORN KHAMMEE ◽  
YUWALEE UNPAPROM ◽  
UBONWAN SUBHASAEN ◽  
RAMESHPRABU RAMARAJ
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Plant Materials ◽  
Natural Pigments ◽  
Dye Sensitized ◽  
Study Results ◽  
Sensitized Solar Cells

Recently, dye-sensitized solar cells (DSSC) have concerned significant attention attributable to their material preparation process, architectural and environmental compatibility, also low cost and effective photoelectric conversion efficiency. Therefore, this study aimed to use potential plant materials for DSSC. This research presents the extraction of natural pigments from yellow cotton flowers (Cochlospermum regium). In addition, the natural pigments were revealed that outstanding advantages, including a wide absorption range (visible light), easy extraction method, safe, innocuous pigments, inexpensive, complete biodegradation and ecofriendly. Methanol was used as a solvent extraction for the yellow cotton flower. The chlorophylls and carotenoid pigments extractions were estimated by a UV-visible spectrometer. The chlorophyll-a, chlorophyll-b, and carotenoid yield were 0.719±0.061 µg/ml, 1.484±0.107 µg/ml and 7.743±0.141 µg/ml, respectively. Thus, this study results suggested that yellow cotton flowers containing reasonable amounts appealable in the DSSC production.

The Effects of Sputtering Pressure on the Properties of Carbon Counter Electrodes for Dye-Sensitized Solar Cells

2012 ◽  
Vol 430-432 ◽  
pp. 631-635
Author(s):  
Shu Hong Liu ◽  
Gui Shan Liu ◽  
Xiao Yue Shen ◽  
Zhi Qiang Hu
Keyword(s):  
Solar Cells ◽  
Sheet Resistance ◽  
Carbon Film ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Counter Electrodes ◽  
Dye Sensitized ◽  
Sputtering Pressure ◽  
Sensitized Solar Cells

The carbon counter electrodes for Dye-sensitized solar cells (DSSCs) were deposited on FTO glass using graphite target by bipolar pulse magnetron sputtering. The effects of sputtering pressure on the structures and properties for carbon films were investigated. The carbon bond structure was analyzed by Raman spectra. The sheet resistance of carbon film was detected by four-probe tester. The transmittance was tested by UV-visible spectrum. The performance of DSSCs was tested by solar simulator after the cells assembled. The results indicated that the ratio of ID/IG reduced, the degree of graphitization decreased, sheet resistance raised, transmittance increased and photoelectric conversion efficiency reduced with the increasing of sputtering pressure.

Photoelectrode with Multilayer of Gradual Scattering Structure Used in Dye-Sensitized Solar Cells

2013 ◽  
Vol 699 ◽  
pp. 22-27
Author(s):  
Xiao Peng ◽  
Bao Zhang ◽  
Shu Xian Meng ◽  
Xiang Mei Yu ◽  
Zhe Zeng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion ◽  
Emulsion Method ◽  
Dye Sensitized ◽  
Scattering Centers ◽  
Micro Emulsion ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

A multilayer TiO2 film featured with gradual scattering structure was developed and used as photoelectrode for dye-sensitized solar cells. This structure of film consists of P25 nanoparticles and TiO2 aggregate which was synthesized by micro-emulsion method as scattering centers The scattering centers were deposited by gradually increasing the amount from the film’s bottom to its top. The special films were used for the studies on the photovoltaic performance of N719 and Zn-3, and their photoelectric conversion efficiencies were 7.34% and 4.04%, respectively. Furthermore, more improvement of the conversion efficiency is realized for Zn-3 than for N719 by using our newly developed multilayer films as photoelectrode compared with ordinary photoelectrode.

Dye-Sensitized Solar Cells Based on Three-Dimensional Web-Like Structure Anodes

2012 ◽  
Vol 629 ◽  
pp. 332-338 ◽  
Author(s):  
Zhi Hua Tian ◽  
Jian Xi Yao ◽  
Mi Na Guli
Keyword(s):  
Solar Cells ◽  
Conversion Efficiency ◽  
Dye Sensitized Solar Cells ◽  
Three Dimensional ◽  
Precursor Solution ◽  
Photoelectric Conversion Efficiency ◽  
Tio2 Films ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

TiO2 films with three-dimensional web-like structure have been prepared by the photo polymerization-induced phase separation method (PIPS). Scanning electron microscopy and X-ray diffraction were used to characterize the as-prepared TiO2 films. The results showed that the film texture could be tuned by changing the composition of the precursor solution. The TiO2 film with web-like structure exhibited high photocatalytic activity for the degradation of methylene blue (MB) dye. The as-prepared films were used as the photo-anodes in dye-sensitized solar cells (DSCs). The photoelectric conversion efficiency of the DSCs was significantly enhanced by changing the POGTA/TTB in the precursor solution. Because of the increased dye adsorption active sites and efficient electron transport in the TiO2 anode film, a photoelectric conversion efficiency of 3.015% was obtained.

scholarly journals A down-shifting Eu 3+ -doped Y 2 WO 6 /TiO 2 photoelectrode for improved light harvesting in dye-sensitized solar cells

2018 ◽  
Vol 5 (2) ◽  
pp. 171054 ◽  
Author(s):  
J. Llanos ◽  
I. Brito ◽  
D. Espinoza ◽  
Ramkumar Sekar ◽  
P. Manidurai
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Light Harvesting ◽  
Electrochemical Impedance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Visible Radiation ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Y 1.86 Eu 0.14 WO 6 phosphors were prepared using a solid-state reaction method. Their optical properties were analysed, and they was mixed with TiO 2 , sintered, and used as a photoelectrode (PE) in dye-sensitized solar cells (DSSCs). The as-prepared photoelectrode was characterized by photoluminescence spectroscopy, diffuse reflectance, electrochemical impedance spectroscopy (EIS) and X-ray diffraction. The photoelectric conversion efficiency of the DSSC with TiO 2 :Y 1.86 Eu 0.14 WO 6 (100:2.5) was 25.8% higher than that of a DSCC using pure TiO 2 as PE. This high efficiency is due to the ability of the luminescent material to convert ultraviolet radiation from the sun to visible radiation, thus improving the solar light harvesting of the DSSC.

Significantly improved performance of dye-sensitized solar cells by optimizing organic dyes with pyrrole as the isolation spacer and utilizing alkyl chain engineering

2018 ◽  
Vol 6 (44) ◽  
pp. 22256-22265 ◽  
Author(s):  
Jinfeng Wang ◽  
Siwei Liu ◽  
Zhaofei Chai ◽  
Kai Chang ◽  
Manman Fang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Alkyl Chain ◽  
Organic Dyes ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Improved Performance ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells ◽  
Interfacial Charge

The conversion efficiencies of dye sensitized solar cells were largely enhanced by the optimization of intramolecular and interfacial charge transfer.

scholarly journals Sustainable Organic Dyes from Winemaking Lees for Photoelectrochemical Dye-Sensitized Solar Cells

2020 ◽  
Vol 10 (6) ◽  
pp. 2149
Author(s):  
Manuel Meneghetti ◽  
Aldo Talon ◽  
Elti Cattaruzza ◽  
Emilio Celotti ◽  
Elisabetta Bellantuono ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Dyes ◽  
Low Cost ◽  
Dye Sensitized Solar Cells ◽  
Cost Effective ◽  
Simulated Solar Light ◽  
Dye Sensitized ◽  
Different Temperatures ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

During the last two decades, Dye Sensitized Solar Cells (DSSCs) have received a great deal of attention as a promising, low-cost alternative to conventional silicon photovoltaic devices. Natural dye molecules can be used as a sensitizer for their low cost, good light absorbance, easy preparation process, and biodegradability. In this study, dyes were obtained from wine lees, the last by-product of winemaking process, supplied by a venetian winery (Italy). Polyphenols, like tannins and anthocyanins, which were extracted from winemaking lees, were adsorbed on a nanostructured ordered mesoporous titanium dioxide, previously treated at different temperatures (400–600 °C). Both dyes and titania semiconductor samples were studied with different techniques. The tests were carried out on prototypes to evaluate the cell power and the photocurrent generated under simulated solar light irradiation. The obtained solar energy conversion efficiencies are comparable to those that were reported in literature by using organic dyes extracted from vegetables, fruits, and plants. It is significant that these dyes are largely available and cost effective, since recovered from a waste otherwise to be disposed of, opening up a perspective of feasibility for inexpensive and environmentally friendly dye solar cells to generate green electricity and transforming agri-food waste into a resource.

Investigation of photovoltaic properties of dye-sensitized solar cells based on azo dyes contain various anchoring groups

2019 ◽  
Vol 48 (6) ◽  
pp. 481-486 ◽  
Author(s):  
Mozhgan Hosseinnezhad ◽  
Hanieh Shaki
Keyword(s):  
Solar Cells ◽  
Substituent Effect ◽  
Organic Dyes ◽  
Dye Sensitized Solar Cells ◽  
Photovoltaic Properties ◽  
Content Type ◽  
Dye Sensitized ◽  
Anchoring Groups ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Purpose The purpose of this paper is to study the substituent effect in dye-sensitized solar cells’ (DSSCs) performance. For this end, three new metal organic dyes with DPA structure were synthesized. For investigation of the substituent effect, two different anchoring groups, namely, 1,3-dioxo-1Hbenz[de]isoquinolin-2(3H)-yl)benzenesulfonamides and 1,8-naphthalimide, were used. Design/methodology/approach Three organic dyes based on azo were selected, which contain various electron donor groups. Absorption properties of purified dyes were studied in solution and on photoelectrode (TiO2 and ZnO) substrate. DSSCs were prepared to determine the photovoltaic performance of each photosensitizer. Findings The results showed that all organic dyes form J-aggregation on the photoanode substrate. Cyclic voltammetry results for all organic dyes ensured an energetically permissible and thermodynamically favorable charge transfer throughout the continuous cycle of photo-electric conversion. The results illustrate conversion efficiencies of cells based on solution Dyes 1, 2 and 3 and TiO2 as 3.44, 4.71 and 4.82 per cent, respectively. The conversion efficiencies of cells based on solution Dye 1, 2 and 3 and ZnO are 3.21, 4.09 and 4.14 per cent, respectively. Practical implications In this study, the development of effect of assembling materials, offering improved photovoltaic properties. Social implications Organic dye attracts more and more attention because of its low-cost, facile route synthesis and less-hazardous properties. Originality/value To the best of the authors’ knowledge, the effect of anchoring agent and nanostructure on DSSCs performance was investigated for the first time.

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