Aqueous alkaline electrolytes for dynamic windows based on reversible metal electrodeposition with improved durability

2020 ◽  
Vol 8 (5) ◽  
pp. 1826-1834 ◽  
Author(s):  
Darren D. Miller ◽  
Judy Y. Li ◽  
Shakirul M. Islam ◽  
Joseph F. Jeanetta ◽  
Christopher J. Barile
Keyword(s):  
Aqueous Electrolytes ◽  
Copper Electrodeposition ◽  
Metal Electrodeposition ◽  
Chelating Ligand ◽  
Alkaline Electrolytes

Dynamic windows based on reversible bismuth and copper electrodeposition switch between clear and opaque states using alkaline aqueous electrolytes enabled by a chelating ligand.

Electrolytes for Reversible Zinc Electrodeposition for Dynamic Windows

2021 ◽  
Author(s):  
Desmond C Madu ◽  
Shakirul M Islam ◽  
Hanqing Pan ◽  
Christopher Barile
Keyword(s):  
Aqueous Electrolytes ◽  
Zinc Electrodeposition ◽  
Metal Electrodeposition ◽  
Electronically Tunable

Reversible metal electrodeposition is a promising approach for the construction of dynamic windows with electronically tunable transmission. In this manuscript, we study a series of aqueous electrolytes that support reversible...

Thermally-stable dynamic windows based on reversible metal electrodeposition from aqueous electrolytes

2018 ◽  
Vol 6 (8) ◽  
pp. 2132-2138 ◽  
Author(s):  
Geoffrey Kirk A. Alcaraz ◽  
Jose S. Juarez-Rolon ◽  
Nicholas A. Burpee ◽  
Christopher J. Barile
Keyword(s):  
Wide Temperature Range ◽  
Aqueous Electrolytes ◽  
Thermally Stable ◽  
Temperature Range ◽  
Switching Times ◽  
Metal Electrodeposition

Appropriate additives to dynamic windows based on reversible metal electrodeposition allow aqueous-based electrolytes to be used that support minute-long switching times across a wide temperature range.

Bulk Metal Electrodeposition in the Sub-monolayer Regime: Ru on Pt(111)*

1997 ◽  
Vol 1 (1) ◽  
pp. 137-150
Author(s):  
K. A. Friedrich ◽  
K.-P. Geyzers ◽  
A. Marmann ◽  
U. Stimming ◽  
R. Vogel
Keyword(s):  
Bulk Metal ◽  
Metal Electrodeposition

Synthesis, Characterization and Biological Activity of Nitrogen­ Oxygen-Sulfur (NOS) Transition Metal Complexes Derived from Novel S-2,4-dichlorobenzyldithiocarbazate with 5-fluoroisatin

2010 ◽  
Vol 7 (2) ◽  
pp. 67
Author(s):  
Mohd Abdul Fatah Abdul Manan ◽  
Hadariah Bahron ◽  
Karimah Kassim ◽  
Mohd Asrul Hafaz Mohamad ◽  
Syed Nazmi Sayed Mohamad
Keyword(s):  
Bacillus Subtilis ◽  
Schiff Base ◽  
Metal Complexes ◽  
Condensation Reaction ◽  
Schiff Base Complex ◽  
Inhibition Zone ◽  
Azomethine Nitrogen ◽  
Strong Activity ◽  
Chelating Ligand ◽  
Physico Chemical

A novel Schiff base containing nitrogen-oxygen-sulfur (NOS) donor atoms formed from the condensation reaction of S-2,4-dichlorobenzyldithiocarbazate (S-2,4BDTC) with 5-fluroisatin has been synthesized. Complexes of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) with this Schiff base have been prepared and characterized using elemental analysis and various physico-chemical techniques. In the cobalt(II) and nickel(II) complexes the Schiff base behaves as a uninegatively charged tridentate nitrogen-oxygen-sulfur (NOS) chelating ligand, bonding through the azomethine nitrogen, thiolate sulfur and carbonylic oxygen of the isatin moiety. However, in the copper(II), zinc(II) and cadmium(II) complexes the Schiff base behaves as a nitrogen-sulfur (NS) bidentate chelating ligand, bonding through the azomethine nitrogen and thiolate sulfur. The Schiff base and the metal complexes were evaluated with respect to antimicrobial activity, which was performed in relation to two selected pathogenic microbials (Bacillus subtilis and Pseudomonas aeruginosa). It was observed that only the zinc Schiff base complex exhibited strong activity against the Bacillus subtilis bacteria with an inhibition zone of 25 mm. 

Synthesis, Characterization and Biological Activity of NitrogenOxygen-Sulfur (NOS) Transition Metal Complexes Derived from Novel S-2,4-dichlorobenzyldithiocarbazate with 5-fluoroisatin

2010 ◽  
Vol 7 (2) ◽  
pp. 67
Author(s):  
Mohd Abdul Fatah Abdul Manan ◽  
Hadariah Bahron ◽  
Karimah Kassim ◽  
Mohd Asrul Hafiz Muhamad ◽  
Syed Nazmi Sayed Mohamad
Keyword(s):  
Bacillus Subtilis ◽  
Schiff Base ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Condensation Reaction ◽  
Inhibition Zone ◽  
Azomethine Nitrogen ◽  
Strong Activity ◽  
Chelating Ligand ◽  
Physico Chemical

A novel Schiff base containing nitrogen-oxygen-sulfur (NOS) donor atoms formed from the condensation reaction of S-2,4- dichlorobenzyldithiocarbazate (S-2.4BDTC) with 5-fluroisatin has been synthesized. Complexes of cobalt(ll), nickel(ll), copper(ll), zinc(ll) and cadmium(ll) with this Schiff base have been prepared and characterized using elemental analysis and various physico-chemical techniques. In the cobalt(ll) and nickel(II) complexes the SchifJbase behaves as a uninegatively charged tridentate nitrogen-oxygen-sulfur (NOS) chelating ligand, bonding through the azomethine nitrogen, thiolate sulfur and carbonylic oxygen of the isatin moiety. However. in the copper(ll), zinc(II) and cadmium(II) complexes the Schiff base behaves as a nitrogen-sulfur (NS) bidentate chelating ligand, bonding through the azomethine nitrogen and thiolate sulfur. The Schiff base and the metal complexes were evaluated with respect to antimicrobial activity, which was performed in reallion to two selected pathogenic microbials (Bacillus subtilis and Pseudomonas aeruginosa). It was observed that only the zinc Schiffbase complex exhibited strong activity against the Bacillus subtilis bacteria with an inhibition zone of25 mm.

Nickel(II)-Methyl Complexes Adopting Idealized Seesaw Geometries

2019 ◽  
Author(s):  
Ethan A. Hill ◽  
Norman Zhao ◽  
Alexander S. Filatov ◽  
John Anderson
Keyword(s):  
Singlet State ◽  
Strong Field ◽  
Structural Distortion ◽  
Computational Results ◽  
Threefold Symmetry ◽  
Chelating Ligand ◽  
Electronic Stabilization

We report four-coordinate nickel(II)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.

Instantaneous Fabrication of Thin MEMS Features by Copper Electrodeposition Using Modified Inkjet Printer

2020 ◽  
Vol 12 (2) ◽  
pp. 02044-1-02044-4
Author(s):  
Vimal Kumar Deshmukh ◽  
◽  
Ankit Namdev ◽  
H. K. Narang ◽  
M. S. Rajput ◽  
...  
Keyword(s):  
Copper Electrodeposition ◽  
Inkjet Printer

scholarly journals Electrolyte for Improved Durability of Dynamic Windows Based on Reversible Metal Electrodeposition

Joule ◽  
2020 ◽  
Vol 4 (7) ◽  
pp. 1501-1513
Author(s):  
Tyler S. Hernandez ◽  
Majed Alshurafa ◽  
Michael T. Strand ◽  
Andrew L. Yeang ◽  
Michael G. Danner ◽  
...  
Keyword(s):  
Metal Electrodeposition
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