Stimuli-responsive phenothiazine-based donor–acceptor isomers: AIE, mechanochromism and polymorphism

2020 ◽  
Vol 8 (10) ◽  
pp. 3589-3602 ◽  
Author(s):  
Anupama Ekbote ◽  
Shaikh M. Mobin ◽  
Rajneesh Misra

Stimuli responsive phenothiazine-based donor–acceptor (D–A) molecules were designed and synthesized as positional isomers p-PTZ, m-PTZ and o-PTZ. A comprehensive comparative study of the electronic and photophysical properties has been performed to study the effect of positional change.

2018 ◽  
Vol 6 (40) ◽  
pp. 10888-10901 ◽  
Author(s):  
Anupama Ekbote ◽  
Shaikh M. Mobin ◽  
Rajneesh Misra

Multichromophoric stimuli responsive D–A–A′ molecules were designed and synthesized as positional isomers p-BT, m-BT and o-BT. A comparative study of the photophysical and electronic properties has been carried out to study the effect of position.


2021 ◽  
Author(s):  
Ramya NK ◽  
Femina C ◽  
Suganya Suresh ◽  
Divya S Mohanakumari ◽  
Retheesh Krishnan ◽  
...  

This study reports a detailed analysis of fluorescence switching in a series of octyloxy substituted α-dicyanodistyrylbenzene positional isomers in combination with structures derived from single crystal X-ray diffraction. All the...


2020 ◽  
Vol 2020 ◽  
pp. 1-24 ◽  
Author(s):  
Carmen Cretu ◽  
Loredana Maiuolo ◽  
Domenico Lombardo ◽  
Elisabeta I. Szerb ◽  
Pietro Calandra

The involvement of metal ions within the self-assembly spontaneously occurring in surfactant-based systems gives additional and interesting features. The electronic states of the metal, together with the bonds that can be established with the organic amphiphilic counterpart, are the factors triggering new photophysical properties. Moreover, the availability of stimuli-responsive supramolecular amphiphile assemblies, able to disassemble in a back-process, provides reversible switching particularly useful in novel approaches and applications giving rise to truly smart materials. In particular, small amphiphiles with an inner distribution, within their molecular architecture, of various polar and apolar functional groups, can give a wide variety of interactions and therefore enriched self-assemblies. If it is joined with the opportune presence and localization of noble metals, whose chemical and photophysical properties are undiscussed, then very interesting materials can be obtained. In this minireview, the basic concepts on self-assembly of small amphiphilic molecules with noble metals are shown with particular reference to the photophysical properties aiming at furnishing to the reader a panoramic view of these exciting problematics. In this respect, the following will be shown: (i) the principles of self-assembly of amphiphiles that involve noble metals, (ii) examples of amphiphiles and amphiphile-noble metal systems as representatives of systems with enhanced photophysical properties, and (iii) final comments and perspectives with some examples of modern applications.


2021 ◽  
Vol 28 (7) ◽  
Author(s):  
Ashraf A. El-Shehawy ◽  
Morad M. El-Hendawy ◽  
Adel M. Attia ◽  
Abdul-Rahman I. A. Abdallah ◽  
Nabiha I. Abdo

Author(s):  
Kim Phan ◽  
Steven De Meester ◽  
Katleen Raes ◽  
Karen De Clerck ◽  
Veronique Van Speybroeck

2013 ◽  
Vol 51 (16) ◽  
pp. 3333-3338 ◽  
Author(s):  
Pepa Cotanda ◽  
Daniel B. Wright ◽  
Martin Tyler ◽  
Rachel K. O'Reilly

2018 ◽  
Vol 26 (8) ◽  
pp. 1848-1858 ◽  
Author(s):  
Arif Fadlan ◽  
Hiroki Tanimoto ◽  
Tatsuya Ito ◽  
Yusuke Aritomi ◽  
Maho Ueno ◽  
...  

ARKIVOC ◽  
2003 ◽  
Vol 2003 (11) ◽  
pp. 100-111 ◽  
Author(s):  
Efrén V. García-Báez ◽  
Francisco J. Martínez-Martínez ◽  
Herbert Höpfl ◽  
Itzia I. Padilla-Martínez

2015 ◽  
Vol 6 (12) ◽  
pp. 2312-2318 ◽  
Author(s):  
Zeyun Xiao ◽  
Kuan Sun ◽  
Jegadesan Subbiah ◽  
Tianshi Qin ◽  
Shirong Lu ◽  
...  

The effect of molecular weight of a conjugated polymer on its photophysical properties and solar cell device performance was investigated.


2018 ◽  
Vol 24 (61) ◽  
pp. 16379-16387 ◽  
Author(s):  
Saptarshi Chakraborty ◽  
Debes Ray ◽  
Vinod K. Aswal ◽  
Suhrit Ghosh

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