scholarly journals Vapochromic luminescent proton conductors: switchable vapochromism and proton conduction of luminescent Pt(ii) complexes with proton-exchangeable sites

2019 ◽  
Vol 7 (47) ◽  
pp. 14923-14931 ◽  
Author(s):  
Atsushi Kobayashi ◽  
Shin-ichiro Imada ◽  
Yasuhiro Shigeta ◽  
Yuki Nagao ◽  
Masaki Yoshida ◽  
...  

New switchable vapochromic luminescent and highly-proton-conducting Pt(ii) complexes [PtCl(tpypy)]Cl and [PtCl(tpypyH)]Cl2 are reported.

2019 ◽  
Vol 7 (29) ◽  
pp. 17626-17636 ◽  
Author(s):  
A. Perrichon ◽  
M. Jiménez-Ruiz ◽  
L. Mazzei ◽  
S. M. H. Rahman ◽  
M. Karlsson

Studies of partially and fully hydrated Ba2In2O5(H2O)xproton conductors point toward segregation into pseudo-cubic and brownmillerite-type phases and a highly anisotropic proton conduction mechanism.


RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.


2020 ◽  
Vol 49 (47) ◽  
pp. 17130-17139
Author(s):  
Lu Feng ◽  
Hao-Bo Hou ◽  
Hong Zhou

As newly emerging proton-conducting materials, metal–organic frameworks (MOFs) have been attracting wide attention in the field of proton exchange membrane fuel cells.


RSC Advances ◽  
2015 ◽  
Vol 5 (78) ◽  
pp. 63732-63737 ◽  
Author(s):  
Xinpei Gao ◽  
Fei Lu ◽  
Bin Dong ◽  
Tao Zhou ◽  
Yizhi Liu ◽  
...  

Nanostructured proton conductors having hexagonal and cubic structures were constructed by the self-assembly of zwitterionic ionic liquids. These nanostructured proton conductors all exhibited an assembled-structure dependent proton conduction behavior.


2016 ◽  
Vol 40 (9) ◽  
pp. 7580-7586 ◽  
Author(s):  
Fei Lu ◽  
Xinpei Gao ◽  
Panpan Sun ◽  
Liqiang Zheng

Polymerizable zwitterionic ionic liquid microemulsions were fabricated for the first time to prepare ionic liquid based proton-conductors.


1992 ◽  
Vol 293 ◽  
Author(s):  
Martha Greenblatt ◽  
Shouhua Feng

AbstractThe properties of various proton conducting solid electrolytes were investigated by electrochemical galvanic cell and ac impedance type measurements for applications as high temperature (T>200°C) humidity sensors. The basic characteristics of proton conductors required for humidity sensing are reviewed. Results of ionic conductivity and EMF measurements and their implications for the mechanism of ion transport are discussed for two prototype ceramic humidity sensors: β-Ca(PO3)2 and a NASICON-type ceramic composite, HZr2P3O12/ZrP2O7.


1979 ◽  
Vol 4 (4) ◽  
pp. 327-338 ◽  
Author(s):  
T TAKAHASHI ◽  
S TANASE ◽  
O YAMAMOTO ◽  
S YAMAUCHI ◽  
H KABEYA

2020 ◽  
Vol 19 (4) ◽  
pp. 131-132
Author(s):  
Yuta HORI ◽  
Toshiya SUETAKE ◽  
Tomonori IDA ◽  
Motohiro MIZUNO ◽  
Yasuteru SHIGETA

Author(s):  
Takaya Ogawa ◽  
Hidenori Ohashi ◽  
Anilkumar M. Gopinathan ◽  
Takanori Tamaki ◽  
Takeo Yamaguchi

Proton conducting materials suffer from low proton conductivity under low-relative humidity (RH) conditions. Previously, it was reported that acid-acid interactions, where acids interact with each other at close distances, can...


2013 ◽  
Vol 773 ◽  
pp. 660-663
Author(s):  
Li Qiang Guo ◽  
Zhao Jun Guo ◽  
Yuan Yuan Yang ◽  
Ju Mei Zhou

P-doped SiO2 were prepared by PECVD and one metal shadow mask self-assembled method was used for fabricating oxide thin film transistors gated by such proton conductors. Proton conduction of these films was demonstrated and electrical characteristics of oxide thin film transistors gated by such proton conductors were discussed. Due to excellent proton conduction and big capacitance density, oxide thin film transistors gated by such proton conductors have obtained excellent performances with mobility of 48.39 cm2/Vs, threshold voltage of-0.36 V, subthreshold swing of 0.13 V/decade, Ion/off ratio of 3.2×106 with the relative humidity of 30% at the room temperature.


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