The fabrication of IMo6@iPAF-1 as an enzyme mimic in heterogeneous catalysis for oxidative desulfurization under O2 or air

2020 ◽  
Vol 8 (19) ◽  
pp. 9813-9824 ◽  
Author(s):  
Yue Li ◽  
Jian Song ◽  
Mengting Jiang ◽  
Mbage Bawa ◽  
Xiaohong Wang ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Building Material ◽  
Oxidative Desulfurization ◽  
Enzyme Mimic ◽  
Highly Efficient ◽  
Porous Aromatic Framework

Na5[IMo6O24]·3H2O and a porous aromatic framework (iPAF-1) were used to build an off-the-shelf building material (IMo6@iPAF-1) to realize the highly efficient oxidation of organic sulfurs like oxygenase.

Rational design of ionic V-MOF with confined Mo species for highly efficient oxidative desulfurization

2021 ◽  
pp. 120594
Author(s):  
Shuo Wang ◽  
Xu Zhang ◽  
Xue Chang ◽  
Meng-Ya Zong ◽  
Cun-Zheng Fan ◽  
...  
Keyword(s):  
Rational Design ◽  
Oxidative Desulfurization ◽  
Highly Efficient

Facile Synthesis of Porphyrin Based Covalent Organic Frameworks via an A2B2 Monomer for Highly Efficient Heterogeneous Catalysis

2019 ◽  
Vol 31 (19) ◽  
pp. 8100-8105 ◽  
Author(s):  
Wenjing Hao ◽  
Dan Chen ◽  
Yusen Li ◽  
Zongfan Yang ◽  
Guolong Xing ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Covalent Organic Frameworks ◽  
Facile Synthesis ◽  
Highly Efficient

Functionalized microporous organic nanotube networks as a new platform for highly efficient heterogeneous catalysis

2016 ◽  
Vol 7 (30) ◽  
pp. 4975-4982 ◽  
Author(s):  
Hui Zhang ◽  
Linfeng Xiong ◽  
Zidong He ◽  
Aiqing Zhong ◽  
Tianqi Wang ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Cross Linking ◽  
Base Catalyst ◽  
Highly Efficient ◽  
Heterogeneous Base Catalyst ◽  
Heterogeneous Base

A novel amino-functionalized microporous organic nanotube networks (NH2-MONNs) as heterogeneous base catalyst was successfully synthesized by combination of hyper-cross-linking and molecular templating of multicomponent bottlebrush copolymers.

Highly efficient mesoporous WO x /KIT-6 catalysts for oxidative desulfurization of dibenzothiophene with hydrogen peroxide

2018 ◽  
Vol 44 (6) ◽  
pp. 3687-3695 ◽  
Author(s):  
Zhenghua Li ◽  
Chengbin Li ◽  
Su Bin Park ◽  
Gyoung Hee Hong ◽  
Jin Seo Park ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidative Desulfurization ◽  
Highly Efficient

Design of highly efficient Mo and W-promoted SnO2solid acids for heterogeneous catalysis: acetalization of bio-glycerol

2013 ◽  
Vol 15 (2) ◽  
pp. 478-489 ◽  
Author(s):  
Baithy Mallesham ◽  
Putla Sudarsanam ◽  
Gangadhara Raju ◽  
Benjaram M. Reddy
Keyword(s):  
Heterogeneous Catalysis ◽  
Highly Efficient

scholarly journals Heterogeneous catalysis with encapsulated haem and other synthetic porphyrins: Harnessing the power of porphyrins for oxidation reactions

2018 ◽  
Vol 16 (1) ◽  
pp. 763-789 ◽  
Author(s):  
Nicola A. Dare ◽  
Timothy J. Egan
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Organic Substrates ◽  
Oxidation Reactions ◽  
Highly Efficient ◽  
Protein Environment

AbstractEncapsulated metalloporphyrins have been widely studied for their use as efficient heterogeneous catalysts, inspired by the known catalytic activity of porphyrins in haemoproteins. The oxidation of organic substrates by haemoproteins is one of the well-known roles of these proteins, in which the haem (ferriprotoporphyrin IX = FePPIX) cofactor is the centre of reactivity. While these porphyrins are highly efficient catalysts in the protein environment, once removed, they quickly lose their reactivity. It is for this reason that they have garnered much interest in the field of heterogeneous catalysis of oxidation reactions. This review details current research in the field, focusing on the application of encapsulated haem, and other synthetic metalloporphyrins, applied to oxidation reactions.

All-around coating of CoNi nanoalloy using a hierarchically porous carbon derived from bimetallic MOFs for highly efficient hydrolytic dehydrogenation of ammonia-borane

2020 ◽  
Vol 44 (7) ◽  
pp. 3021-3027 ◽  
Author(s):  
Min-Jie Chen ◽  
Dai-Xue Zhang ◽  
Dan Li ◽  
Shan-Chao Ke ◽  
Xiao-Chen Ma ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Porous Carbon ◽  
Ammonia Borane ◽  
Core Shell ◽  
Hierarchically Porous ◽  
Highly Efficient

In situ synthesis of core–shell carbon enclosed CoNi alloys achieves efficient heterogeneous catalysis.

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