Free-standing 3D nitrogen–carbon anchored Cu nanorod arrays: in situ derivation from a metal–organic framework and strategy to stabilize lithium metal anodes

2020 ◽  
Vol 8 (3) ◽  
pp. 1425-1431 ◽  
Author(s):  
Dongming Yin ◽  
Gang Huang ◽  
Shaohua Wang ◽  
Dongxia Yuan ◽  
Xuxu Wang ◽  
...  
Keyword(s):  
Lithium Batteries ◽  
Metal Organic Framework ◽  
Current Collector ◽  
Nanorod Arrays ◽  
Lithium Metal ◽  
Free Standing ◽  
Metal Organic ◽  
Lithium Metal Anodes ◽  
Organic Framework

A free-standing and integrated 3D nitrogen–carbon co-doped Cu nanorod arrays (3D NC/Cu) as a completely new current collector is in situ derived from the metal–organic framework (MOF) and can effectively address dendrite issues for lithium batteries.

Stabilization of lithium metal anodes by conductive metal–organic framework architectures

2021 ◽  
Author(s):  
Jing Zhao ◽  
Hongye Yuan ◽  
Guiling Wang ◽  
Xiao Feng Lim ◽  
Hualin Ye ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Current Collector ◽  
Li Ion Batteries ◽  
Lithium Metal ◽  
Seeding Layer ◽  
Current Collectors ◽  
Metal Organic ◽  
Lithium Metal Anodes ◽  
Li Ion ◽  
Cu Foil

The Cu-foil current collectors with Ni3(HITP)2 films were prepared to reduce the energy barrier of the current collector surface and thus provide a uniform seeding layer for the subsequent deposition of Li in Li-ion batteries.

A Li+ conductive metal organic framework electrolyte boosts the high-temperature performance of dendrite-free lithium batteries

2019 ◽  
Vol 7 (16) ◽  
pp. 9530-9536 ◽  
Author(s):  
Nan Chen ◽  
Yuejiao Li ◽  
Yujuan Dai ◽  
Wenjie Qu ◽  
Yi Xing ◽  
...  
Keyword(s):  
High Temperature ◽  
High Temperatures ◽  
Lithium Batteries ◽  
Metal Organic Framework ◽  
Lithium Metal ◽  
Temperature Performance ◽  
Metal Organic ◽  
Organic Framework

Conventional electrolytes of Li metal batteries are highly flammable and volatile, which accelerates the consumption of lithium metal at high temperatures, resulting in catastrophic fires or explosions.

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti)

2021 ◽  
Vol 316 ◽  
pp. 110957
Author(s):  
Mian Zahid Hussain ◽  
Mounib Bahri ◽  
Werner R. Heinz ◽  
Quanli Jia ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Metal Organic Framework ◽  
In Situ Investigation ◽  
Metal Organic ◽  
Organic Framework

In Situ Growth of Metal–Organic Framework Thin Films with Gas Sensing and Molecule Storage Properties

Langmuir ◽  
2013 ◽  
Vol 29 (27) ◽  
pp. 8657-8664 ◽  
Author(s):  
Wei-Jin Li ◽  
Shui-Ying Gao ◽  
Tian-Fu Liu ◽  
Li-Wei Han ◽  
Zu-Jin Lin ◽  
...  
Keyword(s):  
Thin Films ◽  
Gas Sensing ◽  
Metal Organic Framework ◽  
In Situ Growth ◽  
Metal Organic ◽  
Storage Properties ◽  
Organic Framework
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