Aerobic selective oxidation of methylaromatics to benzoic acids over Co@N/Co-CNTs with high loading CoN4 species

2019 ◽  
Vol 7 (48) ◽  
pp. 27212-27216 ◽  
Author(s):  
Bingfeng Chen ◽  
Shaopeng Li ◽  
Shoujie Liu ◽  
Minghua Dong ◽  
Buxing Han ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
High Density ◽  
High Loading ◽  
Benzoic Acids ◽  
Selective Aerobic Oxidation

A high density of CoN4 species embedded in N-doped CNTs achieved outstanding performance for selective aerobic oxidation of methylaromatics to benzoic acids.

scholarly journals NHC-catalysed highly selective aerobic oxidation of nonactivated aldehydes

2013 ◽  
Vol 9 ◽  
pp. 602-607 ◽  
Author(s):  
Lennart Möhlmann ◽  
Stefan Ludwig ◽  
Siegfried Blechert
Keyword(s):  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Environmentally Friendly ◽  
Heterocyclic Carbenes ◽  
Metal Free ◽  
Reaction Proceeds ◽  
Selective Aerobic Oxidation ◽  
Terminal Oxidation ◽  
Oxidation Agent

This publication describes a highly selective oxidation of aldehydes to the corresponding acids or esters. The reaction proceeds under metal-free conditions by using N-heterocyclic carbenes as organocatalysts in combination with environmentally friendly oxygen as the terminal oxidation agent.

Selective Aerobic Oxidation of Primary Alcohols to Aldehydes

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1554-1557 ◽  
Author(s):  
Masatoshi Shibuya ◽  
Keisuke Furukawa ◽  
Yoshihiko Yamamoto
Keyword(s):  
Carboxylic Acid ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Co Catalyst ◽  
Tert Butyl ◽  
Selective Aerobic Oxidation

The 2-azaadamantane-N-oxyl (AZADO)- and 9-azanoradamantane-N-oxyl (nor-AZADO)-catalyzed selective oxidation of primary alcohols to the corresponding aldehydes is described. The use of tert-butyl nitrite as the co-catalyst enables efficient aerobic oxidation in MeCN instead of previously reported AcOH; this is important for the selectivity of the reaction. The addition of a solution of saturated aqueous NaHCO3 after the completion of the reaction was effective to suppress the overoxidation of the product to the corresponding carboxylic acid during the workup.

Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water

2018 ◽  
Vol 20 (17) ◽  
pp. 3921-3926 ◽  
Author(s):  
Maria Ventura ◽  
Francesco Nocito ◽  
Elvira de Giglio ◽  
Stefania Cometa ◽  
Angela Altomare ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Mixed Oxides ◽  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation

The selective oxidation of 5-HMF towards 2,5-furandicarboxylic acid (FDCA) has been achieved with 99% yield in water, using oxygen as the oxidant over CuO·MnO2·CeO2 mixed oxides.

Synthesis and characterization of Co3O4 immobilized on dipeptide-functionalized silica-coated magnetite nanoparticles as a catalyst for the selective aerobic oxidation of alcohols

2018 ◽  
Vol 42 (14) ◽  
pp. 11381-11389 ◽  
Author(s):  
Mohammad Mehdi Khodaei ◽  
Mahsa Dehghan
Keyword(s):  
Selective Oxidation ◽  
Magnetite Nanoparticles ◽  
Aerobic Oxidation ◽  
Recyclable Catalyst ◽  
Synthesis And Characterization ◽  
Core Shell ◽  
Functionalized Silica ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation

A supermagnetic core–shell nanocatalyst functionalized with a dipeptide ligand as a recyclable catalyst for the selective oxidation of alcohols.

Highly selective aerobic oxidation of biomass alcohol to benzaldehyde by an in situ doped Au/TiO2 nanotube photonic crystal photoanode for simultaneous hydrogen production promotion

2017 ◽  
Vol 5 (24) ◽  
pp. 12407-12415 ◽  
Author(s):  
Zhongyi Wu ◽  
Jie Wang ◽  
Zhaoyu Zhou ◽  
Guohua Zhao
Keyword(s):  
Photonic Crystal ◽  
Hydrogen Production ◽  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Tio2 Nanotube ◽  
Photoelectrochemical Cell ◽  
Oxidation Of Benzyl Alcohol ◽  
Selective Aerobic Oxidation

Highly selective oxidation of benzyl alcohol for simultaneous hydrogen production promotion with solar-driven dual photoelectrode photoelectrochemical cell.

Selective aerobic oxidation of cyclic ethers to lactones over Au/CeO2 without any additives

2020 ◽  
Vol 56 (17) ◽  
pp. 2638-2641 ◽  
Author(s):  
Shulin Liu ◽  
Shaopeng Li ◽  
Xiaojun Shen ◽  
Yanyan Wang ◽  
Juan Du ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Cyclic Ethers ◽  
Selective Aerobic Oxidation

Selective oxidation of ethers to lactones with O2 as a benign oxidant using Au/CeO2 as the catalyst has been developed.

Selective aerobic oxidation of alkyl aromatics on Bi2MoO6 nanoplates decorated with Pt nanoparticles under visible light irradiation

2018 ◽  
Vol 54 (86) ◽  
pp. 12194-12197 ◽  
Author(s):  
Bao Zhang ◽  
Xiaojing Yang ◽  
Jun Li ◽  
Gang Cheng
Keyword(s):  
Visible Light ◽  
Selective Oxidation ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Pt Nanoparticles ◽  
Light Irradiation ◽  
Light Illumination ◽  
Visible Light Illumination ◽  
Selective Aerobic Oxidation

Pt/Bi2MoO6 nanoplates are efficient photocatalysts for the selective oxidation of saturated C–H bonds in alkyl aromatics under visible light illumination using O2 as an oxidant.

Efficient and selective aerobic oxidation of alcohols catalysed by MOF-derived Co catalysts

2016 ◽  
Vol 18 (4) ◽  
pp. 1061-1069 ◽  
Author(s):  
Cuihua Bai ◽  
Aiqin Li ◽  
Xianfang Yao ◽  
Hongli Liu ◽  
Yingwei Li
Keyword(s):  
Heterogeneous Catalyst ◽  
Selective Oxidation ◽  
Atmospheric Pressure ◽  
Aerobic Oxidation ◽  
Co Catalysts ◽  
Highly Efficient ◽  
Neat Water ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation

A magnetic Co-based heterogeneous catalyst derived from MOFs is highly efficient in selective oxidation of alcohols in neat water under an atmospheric pressure of air and base-free conditions.

Merging the catechol–TiO2 complex photocatalyst with TEMPO for selective aerobic oxidation of amines into imines

2018 ◽  
Vol 8 (15) ◽  
pp. 3910-3917 ◽  
Author(s):  
Ji-Long Shi ◽  
Huimin Hao ◽  
Xia Li ◽  
Xianjun Lang
Keyword(s):  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Blue Led ◽  
Selective Aerobic Oxidation ◽  
Led Irradiation

Merging of catechol–TiO2 complex photocatalysis with TEMPO catalysis can successfully facilitate the selective oxidation of amines into imines with air under blue LED irradiation.

The selective oxidation of glycerol over metal-free photocatalysts: insights into the solvent effect on catalytic efficiency and product distribution

2021 ◽  
Author(s):  
Pingbo Zhang ◽  
Chengguang Yue ◽  
Mingming Fan ◽  
Agus Haryonob ◽  
Yan Leng ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Catalytic Efficiency ◽  
Product Distribution ◽  
Dft Theory ◽  
Oxidative Esterification ◽  
Metal Free ◽  
Selective Aerobic Oxidation ◽  
Theory Calculation

Solvent effect in selective aerobic oxidation of glycerol over O-doped g-C3N4 was studied combining with control experiments and DFT theory calculation. Notably, a novel oxidative esterification of glycerol to yield esters was discovered in CH3CN.

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