Sandwich structured WO3 nanoplatelets for highly efficient photoelectrochemical water splitting

2019 ◽  
Vol 7 (45) ◽  
pp. 26077-26088 ◽  
Author(s):  
Guangwei Zheng ◽  
Jinshu Wang ◽  
Guannan Zu ◽  
Haibing Che ◽  
Chen Lai ◽  
...  

Promising PEC water splitting activity with a photocurrent density of 3.16 mA cm−2 at 1.23 V vs. RHE was demonstrated in sandwich structured WO3 with exposed highly reactive (002) facet and superior crystallinity of 2-D nanoplatelets.

2017 ◽  
Vol 1 (2) ◽  
pp. 338-342 ◽  
Author(s):  
Haibo Li ◽  
Fengyi Zhao ◽  
Jincheng Zhang ◽  
Lei Luo ◽  
Xujing Xiao ◽  
...  

g-C3N4/WO3 heterojunctions with exceptional ability and stability for photoelectrochemical (PEC) water splitting which achieved a high photocurrent density.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Beibei Zhang ◽  
Shiqiang Yu ◽  
Ying Dai ◽  
Xiaojuan Huang ◽  
Lingjun Chou ◽  
...  

AbstractDeveloping low-cost and highly efficient catalysts toward the efficient oxygen evolution reaction (OER) is highly desirable for photoelectrochemical (PEC) water splitting. Herein, we demonstrated that N-incorporation could efficiently activate NiFeOx catalysts for significantly enhancing the oxygen evolution activity and stability of BiVO4 photoanodes, and the photocurrent density has been achieved up to 6.4 mA cm−2 at 1.23 V (vs. reversible hydrogen electrode (RHE), AM 1.5 G). Systematic studies indicate that the partial substitution of O sites in NiFeOx catalysts by low electronegative N atoms enriched the electron densities in both Fe and Ni sites. The electron-enriched Ni sites conversely donated electrons to V sites of BiVO4 for restraining V5+ dissolution and improving the PEC stability, while the enhanced hole-attracting ability of Fe sites significantly promotes the oxygen-evolution activity. This work provides a promising strategy for optimizing OER catalysts to construct highly efficient and stable PEC water splitting devices.


Nanoscale ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 4302-4308 ◽  
Author(s):  
Yajun Pang ◽  
Wenjie Zang ◽  
Zongkui Kou ◽  
Lei Zhang ◽  
Guangqing Xu ◽  
...  

Atom-dispersed Bi metal along the TiO2 nanorods is properly designed as an efficiency co-catalyst to boost the photoelectrochemical (PEC) water splitting with a three-fold enhancement on photocurrent density.


2020 ◽  
Vol 8 (41) ◽  
pp. 21474-21502
Author(s):  
Xingyue Zou ◽  
Zhuxing Sun ◽  
Yun Hang Hu

Recent progress in and future perspectives on strategies for improving the intrinsic properties of g-C3N4 and the quality of g-C3N4-based film electrodes for highly efficient and stable PEC water splitting.


2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>


2019 ◽  
Vol 7 (14) ◽  
pp. 8061-8072 ◽  
Author(s):  
Erhuan Zhang ◽  
Jia Liu ◽  
Muwei Ji ◽  
Hongzhi Wang ◽  
Xiaodong Wan ◽  
...  

Construction of hollow anisotropic semiconductor nanostructures that possess excellent crystallinity, flexibly tunable structure/morphology and aqueous dispersity is of special interest for photoelectrochemical (PEC) water splitting


2019 ◽  
Vol 48 (31) ◽  
pp. 11934-11940 ◽  
Author(s):  
Jianmin Wang ◽  
Yunan Wang ◽  
Xinchao Xv ◽  
Yan Chen ◽  
Xi Yang ◽  
...  

Defective Fe3+ self-doped spinel ZnFe2O4 with abundant oxygen vacancies exhibits largely enhanced photoelectrochemical performance.


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