Thiocarboxylate-modified Ni(OH)2 nanosheets for high-performance alkaline batteries

2019 ◽  
Vol 7 (35) ◽  
pp. 20176-20181 ◽  
Author(s):  
Hongyang Zhao ◽  
Dandan Yin ◽  
Jianwei Wang ◽  
Yuansuo Zheng ◽  
Yaping Du
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Rechargeable Battery ◽  
Alkaline Batteries

Thiocarboxylate-modified Ni(OH)2 nanosheets present a superior electrochemical performance as an alkaline rechargeable battery cathode due to their highly conductive metal–sulfur bonds.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

scholarly journals Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries

2017 ◽  
Vol 8 (1) ◽  
pp. 160-164 ◽  
Author(s):  
Qidong Li ◽  
Qiulong Wei ◽  
Wenbin Zuo ◽  
Lei Huang ◽  
Wen Luo ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Anode Material ◽  
High Performance ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Sodium Storage

A new anode material, Fe3S4, shows superior electrochemical performance and a novel mechanism for sodium storage.

scholarly journals Sb nanosheet modified separator for Li–S batteries with excellent electrochemical performance

RSC Advances ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 6798-6803
Author(s):  
Linchao Zeng ◽  
Jianhui Zhu ◽  
Minsu Liu ◽  
Peixin Zhang
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Excellent Electrochemical Performance ◽  
First Time ◽  
Modified Separator

Antimony nanosheet modified separator is prepared for high performance Li–S batteries for the first time.

Self-assembled ZnO-carbon dots anode materials for high performance nickel-zinc alkaline batteries

2021 ◽  
pp. 130660
Author(s):  
Ji-Shi Wei ◽  
Ze-Yang Zhu ◽  
Xiao Zhao ◽  
Tian-Bing Song ◽  
Jian-Hang Huang ◽  
...  
Keyword(s):  
Carbon Dots ◽  
Anode Materials ◽  
High Performance ◽  
Alkaline Batteries ◽  
Nickel Zinc ◽  
Self Assembled

Self-assembly synthesis of nitrogen-doped mesoporous carbons used as high-performance electrode materials in lithium-ion batteries and supercapacitors

2017 ◽  
Vol 41 (21) ◽  
pp. 12901-12909 ◽  
Author(s):  
Chunfeng Shao ◽  
Ziqiang Wang ◽  
Errui Wang ◽  
Shujun Qiu ◽  
Hailiang Chu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Self Assembly ◽  
High Performance ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Mesoporous Carbons ◽  
Nitrogen Doped ◽  
First Time ◽  
Enhanced Electrochemical Performance

Guanine was, for the first time, used as a nitrogen source during the synthesis of nitrogen-doped porous carbons (NMCs) with enhanced electrochemical performance.

Unusual morphologies of reduced graphene oxide and polyaniline nanofibers-reduced graphene oxide composites for high performance supercapacitor applications

RSC Advances ◽  
2014 ◽  
Vol 4 (43) ◽  
pp. 22551-22560 ◽  
Author(s):  
Rahul S. Diggikar ◽  
Dattatray J. Late ◽  
Bharat B. Kale
Keyword(s):  
Graphene Oxide ◽  
Electrochemical Performance ◽  
Reduced Graphene Oxide ◽  
High Performance ◽  
Polyaniline Nanofibers ◽  
Pani Nanofibers ◽  
Reduced Graphene ◽  
Oxide Composites ◽  
Enhanced Electrochemical Performance ◽  
Supercapacitor Applications

The unique morphologies of reduced graphene oxide (RGO) and RGO–PANI nanofibers (NF) composites have been demonstrated. The enhanced electrochemical performance was observed for honeycomb like RGO–PANI NFs composites.

Highly ordered nanoscale phosphomolybdate-grafted polyaniline/metal hybrid layered structures prepared via secondary sputtering phenomenon as high-performance pseudocapacitor electrodes

2021 ◽  
Author(s):  
Eun Seop Yoon ◽  
Bong Gill Choi ◽  
Hwan-Jin Jeon
Keyword(s):  
Electron Transfer ◽  
Aspect Ratio ◽  
Electrochemical Performance ◽  
High Aspect Ratio ◽  
High Performance ◽  
Electrode Materials ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
High Rate ◽  
Large Area

Abstract The development of energy storage electrode materials is important for enhancing the electrochemical performance of supercapacitors. Despite extensive research on improving electrochemical performance with polymer-based materials, electrode materials with micro/nanostructures are needed for fast and efficient ion and electron transfer. In this work, highly ordered phosphomolybdate (PMoO)-grafted polyaniline (PMoO-PAI) deposited onto Au hole-cylinder nanopillar arrays is developed for high-performance pseudocapacitors. The three-dimensional nanostructured arrays are easily fabricated by secondary sputtering lithography, which has recently gained attention and features a high resolution of 10 nm, a high aspect ratio greater than 20, excellent uniformity/accuracy/precision, and compatibility with large area substrates. These 10nm scale Au nanostructures with a high aspect ratio of ~30 on Au substrates facilitate efficient ion and electron transfer. The resultant PMoO-PAI electrode exhibits outstanding electrochemical performance, including a high specific capacitance of 114 mF/cm2, a high-rate capability of 88%, and excellent long-term stability.

Morphology and Structure Induced Co3O4 Nanowires High-Performance Supercapacitor Electrode Material

2021 ◽  
Vol 16 (6) ◽  
pp. 1005-1010
Author(s):  
Jian Wang ◽  
Yan Zhao ◽  
Yucai Li ◽  
Shiwei Song
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Structural Characteristics ◽  
High Porosity ◽  
Ni Foam ◽  
Supercapacitor Electrode ◽  
Morphology And Structure ◽  
Hydrothermal Approach ◽  
Large Capacitance ◽  
Superior Cycling Stability

The electrochemical performance of the material depends heavily on the morphologies and structural characteristics of the material. Co3O4 samples show the remarkable electrochemical performance owing to the high porosity, appropriate pore size distribution and novel architecture and the effect of NH4F for morphology. Co3O4 nanowires grown on Ni foam have been synthesized through a facile hydrothermal approach, revealing large capacitance of 2178.4 mF cm−2 at the current density of 2 mA cm−2 and superior cycling stability.

Hierarchical coral-like MnCo2O4.5@Co-Ni LDH composites on Ni foam as promising electrodes for high-performance supercapacitor

2021 ◽  
Author(s):  
yajun JI ◽  
Fei Chen ◽  
Shufen Tan ◽  
Fuyong Ren
Keyword(s):  
Electrochemical Performance ◽  
Metal Oxides ◽  
High Performance ◽  
High Capacity ◽  
Rate Capability ◽  
Negative Electrode ◽  
High Energy ◽  
Hybrid Nanostructures ◽  
High Energy Density ◽  
Ni Foam

Abstract Transition metal oxides are generally designed as hybrid nanostructures with high performance for supercapacitors by enjoying the advantages of various electroactive materials. In this paper, a convenient and efficient route had been proposed to prepare hierarchical coral-like MnCo2O4.5@Co-Ni LDH composites on Ni foam, in which MnCo2O4.5 nanowires were enlaced with ultrathin Co-Ni layered double hydroxides nanosheets to achieve high capacity electrodes for supercapacitors. Due to the synergistic effect of shell Co-Ni LDH and core MnCo2O4.5, the outstanding electrochemical performance in three-electrode configuration was triggered (high area capacitance of 5.08 F/cm2 at 3 mA/cm2 and excellent rate capability of maintaining 61.69 % at 20 mA/cm2), which is superior to those of MnCo2O4.5, Co-Ni LDH and other metal oxides based composites reported. Meanwhile, the as-prepared hierarchical MnCo2O4.5@Co-Ni LDH electrode delivered improved electrical conductivity than that of pristine MnCo2O4.5. Furthermore, the as-constructed asymmetric supercapacitor using MnCo2O4.5@Co-Ni LDH as positive and activated carbon as negative electrode presented a rather high energy density of 220 μWh/cm2 at 2400 μW/cm2 and extraordinary cycling durability with the 100.0 % capacitance retention over 8000 cycles at 20 mA/cm2, demonstrating the best electrochemical performance compared to other asymmetric supercapacitors using metal oxides based composites as positive electrode material. It can be expected that the obtained MnCo2O4.5@Co-Ni LDH could be used as the high performance and cost-effective electrode in supercapacitors.

Phytic Acid Induced Nitrogen Configuration Adjustment of Active Nitrogen-Rich Carbon Nanosheets for High-Performance Potassium-Ion Storage

2021 ◽  
Author(s):  
Ma Liang ◽  
Zhibin Li ◽  
Jinliang Li ◽  
Yao Dai ◽  
Chen Qian ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Phytic Acid ◽  
High Performance ◽  
Nitrogen Doping ◽  
Potassium Ion ◽  
Active Nitrogen ◽  
Carbon Nanosheets ◽  
Ion Storage

As a conventional modification approach, nitrogen doping in carbon can greatly improve the electrochemical performance for potassium (K)-ion storage. However, we realized that the improvement of electrochemical performance by simple...

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