ZnO nanoconfined 3D porous carbon composite microspheres to stabilize lithium nucleation/growth for high-performance lithium metal anodes

2019 ◽  
Vol 7 (33) ◽  
pp. 19442-19452 ◽  
Author(s):  
Linsheng Tang ◽  
Rui Zhang ◽  
Xinyue Zhang ◽  
Naiqin Zhao ◽  
Chunsheng Shi ◽  
...  
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Cycling Performance ◽  
Carbon Composite ◽  
Carbon Layer ◽  
Lithium Metal ◽  
Metal Anode ◽  
Composite Microspheres ◽  
Lithium Metal Anode ◽  
Lithium Metal Anodes

The lithiophilic nucleation seed is confined by the carbon layer to improve the cycling performance of the lithium metal anode.

scholarly journals Bio-inspired low-tortuosity carbon host for high-performance lithium-metal anode

2018 ◽  
Vol 6 (2) ◽  
pp. 247-256 ◽  
Author(s):  
Yi-Chen Yin ◽  
Zhi-Long Yu ◽  
Zhi-Yuan Ma ◽  
Tian-Wen Zhang ◽  
Yu-Yang Lu ◽  
...  
Keyword(s):  
Volume Change ◽  
High Performance ◽  
Rate Capability ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Nucleation Sites ◽  
Micro Channels

Abstract Lithium metal is one of the most promising anode materials for high-energy-density Li batteries. However, low stability caused by dendrite growth and volume change during cycling hinders its practical application. Herein, we report an ingenious design of bio-inspired low-tortuosity carbon with tunable vertical micro-channels to be used as a host to incorporate nanosized Sn/Ni alloy nucleation sites, which can guide Li metal's plating/stripping and meanwhile accommodate the volume change. The pore sizes of the vertical channels of the carbon host can be regulated to investigate the structure–performance correlation. After compositing Li, the bio-inspired carbon host with the smallest pore size (∼14 μm) of vertical channels exhibits the lowest overpotential (∼18 mV at 1 mA cm−2), most stable tripping/plating voltage profiles, and best cycling stability (up to 500 cycles) in symmetrical cells. Notably, the carbon/Li composite anode is more rewarding than Li foil when coupled with LiFePO4 in full cells, exhibiting a much lower polarization effect, better rate capability and higher capacity retention (90.6% after 120 cycles). This novel bio-inspired design of a low-tortuosity carbon host with nanoalloy coatings may open a new avenue for fabricating advanced Li-metal batteries with high performance.

High performance lithium metal anode enabled by CF4 plasma treated carbon paper

Nanoscale ◽  
2021 ◽  
Author(s):  
Fei Shen ◽  
Fan Zhang ◽  
Yuting Yin ◽  
Sile Chen ◽  
Jie Gao ◽  
...  
Keyword(s):  
Energy Density ◽  
Dendritic Growth ◽  
High Performance ◽  
Carbon Paper ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Treated Carbon ◽  
Metal Anodes

To substantially boost the energy density of secondary batteries, researches on Li metal anodes are booming to develop technologies on Li metal batteries. However, suffered from Li dendritic growth and...

High performance lithium metal anode: Progress and prospects

2017 ◽  
Vol 7 ◽  
pp. 115-129 ◽  
Author(s):  
Jialiang Lang ◽  
Longhao Qi ◽  
Yuzi Luo ◽  
Hui Wu
Keyword(s):  
High Performance ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Lithium Metal Anodes: Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition (Adv. Mater. 25/2018)

2018 ◽  
Vol 30 (25) ◽  
pp. 1870181 ◽  
Author(s):  
Chong Yan ◽  
Xin‐Bing Cheng ◽  
Yang Tian ◽  
Xiang Chen ◽  
Xue‐Qiang Zhang ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Deposition ◽  
Lithium Metal Anodes ◽  
Metal Anodes

Oxygen and nitrogen co-doped porous carbon granules enabling dendrite-free lithium metal anode

2019 ◽  
Vol 18 ◽  
pp. 320-327 ◽  
Author(s):  
Yuanming Liu ◽  
Xianying Qin ◽  
Shaoqiong Zhang ◽  
Yulan Huang ◽  
Feiyu Kang ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Co Doped

Sulfur–nitrogen co-doped porous carbon nanosheets to control lithium growth for a stable lithium metal anode

2019 ◽  
Vol 7 (31) ◽  
pp. 18267-18274 ◽  
Author(s):  
Mei Chen ◽  
Jianhui Zheng ◽  
Ouwei Sheng ◽  
Chengbin Jin ◽  
Huadong Yuan ◽  
...  
Keyword(s):  
Porous Carbon ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Metal ◽  
Capacity Retention ◽  
Carbon Nanosheets ◽  
Metal Anode ◽  
Co Doping ◽  
Lithium Metal Anode ◽  
Co Doped

Based on S, N co-doping, a full cell exhibits high capacity retention and excellent rate capability.

Dual‐Scale Al 2 O 3 Particles Coating for High‐Performance Separator and Lithium Metal Anode

2020 ◽  
Vol 8 (5) ◽  
pp. 1901429
Author(s):  
Qingtong Wang ◽  
Jian Yang ◽  
Zhuyi Wang ◽  
Liyi Shi ◽  
Yin Zhao ◽  
...  
Keyword(s):  
High Performance ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Dual Scale
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