P-Doped NiMoO4 parallel arrays anchored on cobalt carbonate hydroxide with oxygen vacancies and mass transfer channels for supercapacitors and oxygen evolution

2019 ◽  
Vol 7 (33) ◽  
pp. 19589-19596 ◽  
Author(s):  
Feifei Wang ◽  
Kui Ma ◽  
Wen Tian ◽  
Juncai Dong ◽  
Han Han ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Oxygen Vacancy ◽  
Oxygen Evolution ◽  
Oxygen Vacancies ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Parallel Arrays ◽  
Transfer Channels

Phosphate-doped and oxygen vacancy-rich NiMoO4 parallel nanosheets anchored on Co(CO3)0.5(OH)·0.11H2O were synthesized for supercapacitors and oxygen evolution.

scholarly journals Facile Synthesis of Carbon Cloth Supported Cobalt Carbonate Hydroxide Hydrate Nanoarrays for Highly Efficient Oxygen Evolution Reaction

2021 ◽  
Vol 9 ◽  
Author(s):  
Yubing Yan
Keyword(s):  
Electron Microscopy ◽  
Oxygen Evolution ◽  
Current Density ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Carbon Cloth ◽  
High Porosity ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Developing efficient and low-cost replacements for noble metals as electrocatalysts for the oxygen evolution reaction (OER) remain a great challenge. Herein, we report a needle-like cobalt carbonate hydroxide hydrate (Co(CO3)0.5OH·0.11H2O) nanoarrays, which in situ grown on the surface of carbon cloth through a facile one-step hydrothermal method. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations demonstrate that the Co(CO3)0.5OH nanoarrays with high porosity is composed of numerous one-dimensional (1D) nanoneedles. Owing to unique needle-like array structure and abundant exposed active sites, the Co(CO3)0.5OH@CC only requires 317 mV of overpotential to reach a current density of 10 mA cm−2, which is much lower than those of Co(OH)2@CC (378 mV), CoCO3@CC (465 mV) and RuO2@CC (380 mV). For the stability, there is no significant attenuation of current density after continuous operation 27 h. This work paves a facile way to the design and construction of electrocatalysts for the OER.

Oxygen vacancy-confined CoMoO4@CoNiO2 nanorod arrays for oxygen evolution with improved performance

2019 ◽  
Vol 48 (27) ◽  
pp. 10116-10121 ◽  
Author(s):  
Xiaoqiang Du ◽  
Guangyu Ma ◽  
Xiaoshuang Zhang
Keyword(s):  
Oxygen Vacancy ◽  
Oxygen Evolution ◽  
Adsorption Energy ◽  
Active Sites ◽  
Oxygen Vacancies ◽  
Dft Calculation ◽  
Catalytic Properties ◽  
Nanorod Arrays ◽  
Calculation Results ◽  
Improved Performance

Experimental and DFT calculation results show that the presence of oxygen vacancies can decrease the adsorption energy of intermediates at active sites and facilitate the adsorption of intermediates, thus improving the catalytic properties.

Ag nanoparticles decorated urchin-like cobalt carbonate hydroxide composites for highly efficient oxygen evolution reaction

2020 ◽  
Vol 31 (47) ◽  
pp. 475402
Author(s):  
Wei Wang ◽  
Sainan Zhu ◽  
Xingliang Chen ◽  
Xinyu Zhang ◽  
Yourong Tao ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Ag Nanoparticles ◽  
Cobalt Carbonate ◽  
Highly Efficient ◽  
Carbonate Hydroxide

Boosted Oxygen Evolution Reactivity via Atomic Iron Doping in Cobalt Carbonate Hydroxide Hydrate

2020 ◽  
Vol 12 (36) ◽  
pp. 40220-40228
Author(s):  
Shan Zhang ◽  
Bolong Huang ◽  
Liguang Wang ◽  
Xiaoyan Zhang ◽  
Haishuang Zhu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Iron Doping ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Cobalt carbonate hydroxide superstructures for oxygen evolution reactions

2017 ◽  
Vol 53 (57) ◽  
pp. 8010-8013 ◽  
Author(s):  
Simin Zhang ◽  
Bing Ni ◽  
Haoyi Li ◽  
Haifeng Lin ◽  
Huihui Zhu ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Cobalt Hydroxide ◽  
Facile Hydrothermal Method ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Reaction Performance

A novel 3D superstructure of cobalt hydroxide carbonate with excellent electrocatalytic oxygen evolution reaction performance has been synthesized via a facile hydrothermal method.

Cubic Nanostructures of Nickel–Cobalt Carbonate Hydroxide Hydrate as a High-Performance Oxygen Evolution Reaction Electrocatalyst in Alkaline and Near-Neutral Media

2020 ◽  
Vol 59 (22) ◽  
pp. 16690-16702 ◽  
Author(s):  
Kannimuthu Karthick ◽  
Sugumar Subhashini ◽  
Rishabh Kumar ◽  
Sridhar Sethuram Markandaraj ◽  
Muthukumar Muthu Teepikha ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Cobalt Carbonate ◽  
Nickel Cobalt ◽  
Carbonate Hydroxide ◽  
Neutral Media ◽  
Hydroxide Hydrate

Porous cobalt carbonate hydroxide nanospheres towards oxygen evolution reaction

2020 ◽  
pp. 128066
Author(s):  
Yi Jia ◽  
Ya-Nan Li ◽  
Zheng-Min Wang ◽  
Fu-Min Li ◽  
Pu-Jun Jin ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide

Oxygen vacancy engineered unsaturated coordination in cobalt carbonate hydroxide nanowires enables highly selective photocatalytic CO2 reduction

2021 ◽  
Vol 14 (10) ◽  
pp. 5339-5346
Author(s):  
Huanhuan Liu ◽  
Fu Zhang ◽  
Haifei Wang ◽  
Jierui Xue ◽  
Yiming Guo ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Hydrogen Evolution ◽  
Active Sites ◽  
Co2 Reduction ◽  
The Self ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide

The unsaturated coordinated cobalt centers of Vo-CCO NWs as active sites were manufactured by the self-photoetching approach, which can preferably adsorb and activate CO2 molecules, effectively inhibiting hydrogen evolution.

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