In situ formed ultrafine NbTi nanocrystals from a NbTiC solid-solution MXene for hydrogen storage in MgH2

2019 ◽  
Vol 7 (23) ◽  
pp. 14244-14252 ◽  
Author(s):  
Zeyi Wang ◽  
Xuelian Zhang ◽  
Zhuanghe Ren ◽  
Yong Liu ◽  
Jianjiang Hu ◽  
...  

In situ formed NbTi nanocrystals from a NbTiC solid-solution MXene offer highly stable catalytic activity for hydrogen storage in MgH2.

RSC Advances ◽  
2021 ◽  
Vol 11 (60) ◽  
pp. 37677-37683
Author(s):  
Ying Cheng ◽  
Shuhua Zhou ◽  
Biqing Shi ◽  
Bing Dong ◽  
Xianbin Ji ◽  
...  

The MgH2–Ce0.8Fe0.1Zr0.1O2 onset dissociation temperature was 82 K lower than that of MgH2.


2016 ◽  
Vol 111 ◽  
pp. 248-252 ◽  
Author(s):  
Yongqing Wang ◽  
Zhiyan Zhou ◽  
Wenzheng Zhou ◽  
Liqin Xu ◽  
Jin Guo ◽  
...  

Materialia ◽  
2018 ◽  
Vol 1 ◽  
pp. 114-120 ◽  
Author(s):  
Zhengyang Shen ◽  
Zeyi Wang ◽  
Min Zhang ◽  
Mingxia Gao ◽  
Jianjiang Hu ◽  
...  

2018 ◽  
Vol 97 ◽  
pp. 544-552 ◽  
Author(s):  
Yu Zhang ◽  
Yongfeng Liu ◽  
Yaxiong Yang ◽  
You Li ◽  
Jianjiang Hu ◽  
...  

1980 ◽  
Vol 45 (8) ◽  
pp. 2219-2223 ◽  
Author(s):  
Marie Jakoubková ◽  
Martin Čapka

Kinetics of homogenous hydrogenation of 1-heptene catalysed by rhodium(I) complexes prepared in situ from μ,μ'-dichloro-bis(cyclooctenerhodium) and phosphines of the type RP(C6H5)2 (R = -CH3, -(CH2)nSi(CH3)3; n = 1-4) have been studied. The substitution of the ligands by the trimethylsilyl group was found to increase significantly the catalytic activity of the complexes. The results are discussed in relation to the electron density on the phosphorus atom determined by 31P NMR spectroscopy and to its proton acceptor ability determined by IR spectroscopy.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Mikkel Herzberg ◽  
Anders Støttrup Larsen ◽  
Tue Hassenkam ◽  
Anders Østergaard Madsen ◽  
Jukka Rantanen

Solvents can dramatically affect molecular crystals. Obtaining favorable properties for these crystals requires rational design based on molecular level understanding of the solid-solution interface. Here we show how atomic force...


2021 ◽  
Author(s):  
Wenbo Gao ◽  
Sheng Feng ◽  
Hanxue Yan ◽  
Qianru Wang ◽  
Hua Xie ◽  
...  

A cobalt magnesium oxide solid solution (Co-Mg-O) supported LiH catalyst has been synthesized, in which LiH functions both as a strong reductant for in-situ formation of Co metal nanoparticles and...


2021 ◽  
Vol 9 (13) ◽  
pp. 8341-8349
Author(s):  
Jiahe Zang ◽  
Shaofei Wang ◽  
Rongrun Hu ◽  
Han Man ◽  
Jichao Zhang ◽  
...  

A bimetallic oxide Ni3(VO4)2 has been synthesized to catalyze the hydrogen storage reaction of MgH2. The formation of the Mg2Ni alloy and the kinetic modulation of V results in a dehydrogenation temperature of 210 °C. The NiV2O4 intermediate active species is also detected.


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