Artificial electrode interfaces enable stable operation of freestanding anodes for high-performance flexible lithium ion batteries

2019 ◽  
Vol 7 (23) ◽  
pp. 14097-14107 ◽  
Author(s):  
Lixiang Liu ◽  
Minshen Zhu ◽  
Shaozhuan Huang ◽  
Xueyi Lu ◽  
Long Zhang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion ◽  
High Energy ◽  
Energy Output ◽  
Stable Operation

Artificial electrode interfaces enable stable operation of freestanding electrodes with high energy output and mechanical robustness.

Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries

2013 ◽  
Vol 5 (12) ◽  
pp. 1042-1048 ◽  
Author(s):  
Chao Wang ◽  
Hui Wu ◽  
Zheng Chen ◽  
Matthew T. McDowell ◽  
Yi Cui ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
High Energy ◽  
Stable Operation ◽  
Self Healing

scholarly journals Enhanced Roles of Carbon Architectures in High-Performance Lithium-Ion Batteries

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Lu Wang ◽  
Junwei Han ◽  
Debin Kong ◽  
Ying Tao ◽  
Quan-Hong Yang
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
High Mass

Abstract Lithium-ion batteries (LIBs), which are high-energy-density and low-safety-risk secondary batteries, are underpinned to the rise in electrochemical energy storage devices that satisfy the urgent demands of the global energy storage market. With the aim of achieving high energy density and fast-charging performance, the exploitation of simple and low-cost approaches for the production of high capacity, high density, high mass loading, and kinetically ion-accessible electrodes that maximize charge storage and transport in LIBs, is a critical need. Toward the construction of high-performance electrodes, carbons are promisingly used in the enhanced roles of active materials, electrochemical reaction frameworks for high-capacity noncarbons, and lightweight current collectors. Here, we review recent advances in the carbon engineering of electrodes for excellent electrochemical performance and structural stability, which is enabled by assembled carbon architectures that guarantee sufficient charge delivery and volume fluctuation buffering inside the electrode during cycling. Some specific feasible assembly methods, synergism between structural design components of carbon assemblies, and electrochemical performance enhancement are highlighted. The precise design of carbon cages by the assembly of graphene units is potentially useful for the controlled preparation of high-capacity carbon-caged noncarbon anodes with volumetric capacities over 2100 mAh cm−3. Finally, insights are given on the prospects and challenges for designing carbon architectures for practical LIBs that simultaneously provide high energy densities (both gravimetric and volumetric) and high rate performance.

SnSb/TiO2/C nanocomposite fabricated by high energy ball milling for high-performance lithium-ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (39) ◽  
pp. 32462-32466 ◽  
Author(s):  
Haihua Zhao ◽  
Wen Qi ◽  
Xuan Li ◽  
Hong Zeng ◽  
Ying Wu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Ball Milling ◽  
High Performance ◽  
High Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Li Ion Batteries ◽  
Energy Ball ◽  
Li Ion

Alloy anodes for Li-ion batteries (LIBs) have attracted great interest due to their high capacity.

PROPORTIONAL EFFECT IN SbSi/N-DOPED GRAPHENE NANOCOMPOSITE PREPARATION FOR HIGH-PERFORMANCE LITHIUM-ION BATTERIES

2021 ◽  
pp. 2150105
Author(s):  
NARUEPHON MAHAMAI ◽  
THANAPHAT AUTTHAWONG ◽  
AISHUI YU ◽  
THAPANEE SARAKONSRI
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Morphological Identification ◽  
Synthesis Methods ◽  
Doped Graphene

Lithium-ion batteries (LIBs) have become commercialized technologies for the modern and future world, but commercial batteries using graphite still have a low specific capacity and are concerned with safety issues. Silicon (Si) and antimony (Sb) nanocomposites have the tendency to be synthesized as high-energy-density anode materials which can be a solution for the above-mentioned problems. This work reported the synthesis methods and characterization of Sb and Si composited with nitrogen-doped graphene (SbSi/NrGO) by facile chemical method and thermal treatment. Si was obtained by magnesiothermic reduction of SiO2 derived from rice husk, waste from the agricultural process. To study the phases, particle distributions, and morphologies, all prepared composites were characterized. In this experiment, the phase compositions were confirmed as [Formula: see text]-Si, [Formula: see text]-Si, SiC, Sb, and shifted peaks of expanded C which were caused by NrGO synthesis. Interestingly, a good distribution of Si and Sb particles on the NrGO surface was obtained in 15Sb15Si/NrGO composition. It could be due to appropriate Sb and Si contents on the NrGO surface area in composite materials. Morphological identification of synthesized products represented the Sb and Si particles in nanoscale dispersed on thin wrinkled-paper NrGO. These results suggested that the synthesis method in this paper is appropriate to prepare SbSi/NrGO nanocomposites to be used as high-performance anode materials in high-performance LIBs for advanced applications.

scholarly journals Facile Synthesis of FeS@C Particles Toward High-Performance Anodes for Lithium-Ion Batteries

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1467
Author(s):  
Xuanni Lin ◽  
Zhuoyi Yang ◽  
Anru Guo ◽  
Dong Liu
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Current Density ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Hierarchical Porous

High energy density batteries with high performance are significantly important for intelligent electrical vehicular systems. Iron sulfurs are recognized as one of the most promising anodes for high energy density lithium-ion batteries because of their high theoretical specific capacity and relatively stable electrochemical performance. However, their large-scale commercialized application for lithium-ion batteries are plagued by high-cost and complicated preparation methods. Here, we report a simple and cost-effective method for the scalable synthesis of nanoconfined FeS in porous carbon (defined as FeS@C) as anodes by direct pyrolysis of an iron(III) p-toluenesulfonate precursor. The carbon architecture embedded with FeS nanoparticles provides a rapid electron transport property, and its hierarchical porous structure effectively enhances the ion transport rate, thereby leading to a good electrochemical performance. The resultant FeS@C anodes exhibit high reversible capacity and long cycle life up to 500 cycles at high current density. This work provides a simple strategy for the mass production of FeS@C particles, which represents a critical step forward toward practical applications of iron sulfurs anodes.

Low-Flammble Electrolytes for Stable Operation of High Energy-Density Lithium-Ion Batteries

2021 ◽  
Vol MA2021-02 (3) ◽  
pp. 262-262
Author(s):  
Hao Jia ◽  
Yaobin Xu ◽  
Xianhui Zhang ◽  
Lirong Zhong ◽  
Chongmin Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Stable Operation

SnO2 Nanoparticles for Lithium-Ion Batteries Prepared by Sol-Gel Method

2017 ◽  
Vol 727 ◽  
pp. 718-725 ◽  
Author(s):  
Xu Yan Liu ◽  
Yan Lin Han ◽  
Qiang Li ◽  
Deng Pan
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Discharge Rate ◽  
Sol Gel ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Storage ◽  
Gel Method ◽  
Sol Gel Method

Nanostructured SnO2 is an attractive anode material for high-energy-density lithium-ion batteries because of the fourfold higher theoretical charge capacity than commercially used graphite. However, the poor capacity retention at high rates and long-term cycling have intrinsically limited applications of nanostructured SnO2 anodes due to large polarization and ~300% volume change upon lithium insertion/extraction. Here we report the design of SnO2 nanoparticles, which are synthesized by sol-gel method, with an aim at overcome the above problems for the high-performance reversible lithium storage. The results showed that the mean sizes of SnO2 particles treated with 6 wt.% ammonia were less than 30 nm, which can store charge with a capacity density as high as ~1888 mAh/g. Even when the discharge rate was increased to 0.5 C, it still retained ~1017 mAh/g.

scholarly journals Self-reductive synthesis of MXene/Na0.55Mn1.4Ti0.6O4hybrids for high-performance symmetric lithium ion batteries

2019 ◽  
Vol 7 (13) ◽  
pp. 7516-7525 ◽  
Author(s):  
Guodong Zou ◽  
Bingcheng Ge ◽  
Hao Zhang ◽  
Qingrui Zhang ◽  
Carlos Fernandez ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Reduction Method ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Bifunctional Properties

A new MXene/Na0.55Mn1.4Ti0.6O4hybrid with bifunctional properties is synthesized by a self-reduction method, providing a high energy density for symmetric LIBs.

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