β-Functionalized push–pull opp-dibenzoporphyrins as sensitizers for dye-sensitized solar cells: the role of the phenylethynyl bridge

2019 ◽  
Vol 7 (17) ◽  
pp. 10712-10722 ◽  
Author(s):  
Yi Hu ◽  
Whitney A. Webre ◽  
Michael B. Thomas ◽  
Austen Moss ◽  
Sarah N. Hancock ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Push–pull opp-dibenzoporphyrins with a phenylethynyl bridge were newly synthesized as sensitizers for dye-sensitized solar cells, giving power conversion efficiencies up to 6.7%, close to that of the N719 dye under similar conditions.

Carboxy-1,4-phenylenevinylene- and carboxy-2, 6-naphthylene-vinylene unsymmetrical substituted zinc phthalocyanines for dye-sensitized solar cells

2009 ◽  
Vol 13 (03) ◽  
pp. 369-375 ◽  
Author(s):  
Fabio Silvestri ◽  
Miguel García-Iglesias ◽  
Jun-Ho Yum ◽  
Purificación Vázquez ◽  
M. Victoria Martínez-Díaz ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized ◽  
Zinc Phthalocyanines ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells ◽  
Phthalocyanine Ring

Two unsymmetrical Zn (II) phthalocyanines 1 and 2 bearing an anchoring carboxylic function linked to the phthalocyanine ring through different rigid arylenevinylene bridges have been designed for dye-sensitized solar cell (DSSC) applications. The phthalocyanines 1 and 2, when anchored onto nanocrystalline TiO 2 films, yielded 30% incident monochromatic photon-to-current conversion efficiency (IPCE) and 2% power conversion efficiencies under AM1.5 sun.

Effect of functional groups on sensitization of dye-sensitized solar cells (DSSCs) using free base porphyrins

2017 ◽  
Vol 21 (03) ◽  
pp. 222-230 ◽  
Author(s):  
Nivedita Chaudhri ◽  
Nipun Sawhney ◽  
Bijjam Madhusudhan ◽  
Anubhav Raghav ◽  
Muniappan Sankar ◽  
...  
Keyword(s):  
Solar Cells ◽  
Functional Groups ◽  
Functional Group ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Amino Group ◽  
Free Base ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Dye-sensitized solar cells (DSSCs) were fabricated with six meso-substituted A[Formula: see text]B and A[Formula: see text] free base porphyrin dyes having different functional groups, as sensitizers. The two step synthesis and the effect of different functional groups and their positions on the photosensitization properties of these porphyrin dyes are reported. The highest power conversion efficiencies ([Formula: see text] of 3.26%, 2.94% and 2.84% were achieved for the DSSC fabricated using 5,10,15-tris(4[Formula: see text]-pyridyl)-20-(4[Formula: see text]-carboxyphenyl)porphyrin (H[Formula: see text]TriPyMCPP), 5,10,15,20-tetrakis(4[Formula: see text]-aminophenyl)porphyrin (H[Formula: see text]TAPP) and 5-(4[Formula: see text]-pyridyl)-10,15,20-tris(4[Formula: see text]-carboxyphenyl)porphyrin (H[Formula: see text]MPyTriCPP) dyes, respectively. The electron donating amino group is shown to enhance the power conversion efficiency while pyridyl appended porphyrin sensitizers are shown to be superior sensitizers as compared to carboxyphenylporphyrins. The investigation of effect of functional group and position of functional group of porphyrin dye on DSSC can serve as an important tool to guide further selection and synthesis of potential candidates as sensitizers.

Graphene oxide/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate layers on silver nanowire working electrodes enhance the power conversion efficiencies of dye-sensitized solar cells in a low temperature process

RSC Advances ◽  
2016 ◽  
Vol 6 (53) ◽  
pp. 47185-47191 ◽  
Author(s):  
Bo-Tau Liu ◽  
Zheng-Tang Wang
Keyword(s):  
Graphene Oxide ◽  
Solar Cells ◽  
Silver Nanowires ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Silver Nanowire ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells ◽  
Low Temperature Process

Graphene oxide/PEDOT:PSS hybrid isolates silver nanowires to makes the silver nanowire working electrodes feasible for dye-sensitized solar cells.

Porphyrins as excellent dyes for dye-sensitized solar cells: recent developments and insights

2015 ◽  
Vol 44 (2) ◽  
pp. 448-463 ◽  
Author(s):  
Tomohiro Higashino ◽  
Hiroshi Imahori
Keyword(s):  
Solar Cells ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Ruthenium Complexes ◽  
Dye Sensitized ◽  
Highly Efficient ◽  
Recent Developments ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.

Synthesis and characterization of simple cost-effective trans-A2BC porphyrins with various donor groups for dye-sensitized solar cells

2016 ◽  
Vol 40 (7) ◽  
pp. 5704-5713 ◽  
Author(s):  
Ravi Kumar ◽  
Muniappan Sankar ◽  
Vediappan Sudhakar ◽  
Kothandam Krishnamoorthy
Keyword(s):  
Solar Cells ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Cost Effective ◽  
Synthesis And Characterization ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Zn(ii) porphyrin dyes have been synthesized in three steps and exhibited power conversion efficiencies of 2.1 to 4.2% which depend on the electron donating ability of the R group.

scholarly journals Dye-Sensitized Solar Cells Employing a Single Film of Mesoporous TiO2 Beads Achieve Power Conversion Efficiencies Over 10%

ACS Nano ◽  
2010 ◽  
Vol 4 (8) ◽  
pp. 4420-4425 ◽  
Author(s):  
Frédéric Sauvage ◽  
Dehong Chen ◽  
Pascal Comte ◽  
Fuzhi Huang ◽  
Leo-Philipp Heiniger ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Mesoporous Tio2 ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

4H-pyranylidene organic dyes for dye-sensitized solar cells: Twisted structures towards enhanced power conversion efficiencies

Solar Energy ◽  
2019 ◽  
Vol 193 ◽  
pp. 74-84 ◽  
Author(s):  
José María Andrés-Castán ◽  
Raquel Andreu ◽  
Belén Villacampa ◽  
Jesús Orduna ◽  
Santiago Franco
Keyword(s):  
Solar Cells ◽  
Organic Dyes ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells
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