Fe–N-doped hierarchical mesoporous carbon nanomaterials as efficient catalysts for oxygen reduction in both acidic and alkaline media

2019 ◽  
Vol 7 (20) ◽  
pp. 12518-12525 ◽  
Author(s):  
Rongmin Dun ◽  
Menggeng Hao ◽  
Yumiao Su ◽  
Wenmu Li
Keyword(s):  
Oxygen Reduction ◽  
Mesoporous Carbon ◽  
Carbon Nanomaterials ◽  
Catalytic Performance ◽  
Hollow Microspheres ◽  
Alkaline Media ◽  
Acidic And Alkaline Media

Hierarchical mesoporous carbon nanomaterials synthesized using Fe2O3 hollow microspheres as a multifunctional template exhibit efficient catalytic performance for oxygen reduction in both acidic and alkaline media.

Air plasma etching towards rich active sites in Fe/N-porous carbon for the oxygen reduction reaction with superior catalytic performance

2017 ◽  
Vol 5 (32) ◽  
pp. 16605-16610 ◽  
Author(s):  
Wenhua Zhong ◽  
Jiaxiang Chen ◽  
Peixin Zhang ◽  
Libo Deng ◽  
Lei Yao ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Plasma Etching ◽  
Porous Carbon ◽  
Active Sites ◽  
Catalytic Performance ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Air Plasma ◽  
Acidic And Alkaline Media

Plasma etching removed less stable carbons and exposed the active sites in Fe–N/C catalysts which resulted in excellent performances towards the oxygen reduction reaction in both acidic and alkaline media.

Ordered mesoporous carbon assisted Fe–N–C for efficient oxygen reduction catalysis in both acidic and alkaline media

2020 ◽  
Vol 31 (16) ◽  
pp. 165708 ◽  
Author(s):  
Shuqin Liang ◽  
Haichuan Guo ◽  
Hangjia Shen ◽  
Hanzhang Gong ◽  
Fenghui Fan ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Mesoporous Carbon ◽  
Ordered Mesoporous Carbon ◽  
Alkaline Media ◽  
Ordered Mesoporous ◽  
Acidic And Alkaline Media

scholarly journals Superior FexN electrocatalyst derived from 1,1′-diacetylferrocene for oxygen reduction reaction in alkaline and acidic media

2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Current Density ◽  
Active Sites ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Acidic Media ◽  
Onset Potential ◽  
Acidic And Alkaline Media ◽  
The Stability

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.

Highly active Fe–N-doped porous hollow carbon nanospheres as oxygen reduction electrocatalysts in both acidic and alkaline media

Nanoscale ◽  
2020 ◽  
Vol 12 (28) ◽  
pp. 15115-15127 ◽  
Author(s):  
Meng-geng Hao ◽  
Rong-min Dun ◽  
Yu-miao Su ◽  
Wen-mu Li
Keyword(s):  
Oxygen Reduction ◽  
Nitrogen Sources ◽  
Alkaline Media ◽  
Carbon Nanospheres ◽  
Highly Active ◽  
Acidic And Alkaline Media ◽  
Hollow Carbon ◽  
Soft Templates

MF nanospheres decomposed into NH3 and CO2 as soft templates, nitrogen sources and pore-forming agents.

2D Layered non-precious metal mesoporous electrocatalysts for enhanced oxygen reduction reaction

2017 ◽  
Vol 5 (10) ◽  
pp. 4868-4878 ◽  
Author(s):  
Lili Huo ◽  
Baocang Liu ◽  
Geng Zhang ◽  
Rui Si ◽  
Jian Liu ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Specific Surface ◽  
Oxygen Reduction ◽  
Electrocatalytic Activity ◽  
Precious Metal ◽  
Reduction Reaction ◽  
High Specific Surface Area ◽  
Alkaline Media ◽  
Homogeneous Distribution ◽  
Acidic And Alkaline Media

2D Layered meso-M/N-C/N-G nanocomposites with high specific surface area, homogeneous distribution of ultra-small M-N-C nanoparticles less than 5 nm, and mesopores with a size of ∼3.6 nm exhibit excellent electrocatalytic activity toward oxygen reduction reaction (ORR) in acidic and alkaline media.

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