Deep insight into ionic transport in polyampholyte gel electrolytes towards high performance solid supercapacitors

2019 ◽  
Vol 7 (27) ◽  
pp. 16414-16424
Author(s):  
Dong Li ◽  
Zhen Xu ◽  
Xingxiang Ji ◽  
Libin Liu ◽  
Guangjie Gai ◽  
...  

A novel polyampholyte gel electrolyte with high ionic conductivity and high mechanical strength was developed and was suitable for supercapacitors.

RSC Advances ◽  
2020 ◽  
Vol 10 (29) ◽  
pp. 17070-17078
Author(s):  
Ana Šantić ◽  
Marc Brinkkötter ◽  
Tomislav Portada ◽  
Leo Frkanec ◽  
Cornelia Cremer ◽  
...  

Novel supramolecular ionogels with high ionic conductivity and variable mechanical strength prepared by gelation of ionic liquid [C4mim][N(Tf)2] with (S,S)-bis(phenylalaninol)oxamide.


2020 ◽  
Vol 56 (57) ◽  
pp. 7929-7932
Author(s):  
Meng Zhang ◽  
Quan Zuo ◽  
Lei Wang ◽  
Songrui Yu ◽  
Yiyong Mai ◽  
...  

Solid-state polymer electrolytes with remarkably high ionic conductivity and high mechanical strength are achieved via nanophase separation.


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 874
Author(s):  
Soyoung Bae ◽  
Youngno Kim ◽  
Jeong Min Kim ◽  
Jung Hyun Kim

MXene, a 2D material, is used as a filler to manufacture polymer electrolytes with high ionic conductivity because of its unique sheet shape, large specific surface area and high aspect ratio. Because MXene has numerous -OH groups on its surface, it can cause dehydration and condensation reactions with poly(4-styrenesulfonic acid) (PSSA) and consequently create pathways for the conduction of cations. The movement of Grotthuss-type hydrogen ions along the cation-conduction pathway is promoted and a high ionic conductivity can be obtained. In addition, when electrolytes composed of a conventional acid or metal salt alone is applied to an electrochromic device (ECD), it does not bring out fast response time, high coloration efficiency and transmittance contrast simultaneously. Therefore, dual-cation electrolytes are designed for high-performance ECDs. Bis(trifluoromethylsulfonyl)amine lithium salt (LiTFSI) was used as a source of lithium ions and PSSA crosslinked with MXene was used as a source of protons. Dual-Cation electrolytes crosslinked with MXene was applied to an indium tin oxide-free, all-solution-processable ECD. The effect of applying the electrolyte to the device was verified in terms of response time, coloration efficiency and transmittance contrast. The ECD with a size of 5 × 5 cm2 showed a high transmittance contrast of 66.7%, fast response time (8 s/15 s) and high coloration efficiency of 340.6 cm2/C.


Nanoscale ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 3079-3091
Author(s):  
Libo Chang ◽  
Zhiyuan Peng ◽  
Tong Zhang ◽  
Chuying Yu ◽  
Wenbin Zhong

Wood-inspired HCNF@Lig introduced into MXenes constructing a nacre-like material with high mechanical strength and excellent flexibility used as a flexible supercapacitor.


Soft Matter ◽  
2021 ◽  
Author(s):  
Fengjin Xie ◽  
Xinpei Gao ◽  
Yang Yu ◽  
Fei Lu ◽  
Liqiang Zheng

Gel electrolytes have aroused extensive interest for diverse flexible electronics due to their high ionic conductivity and inherent stretchability. However, gel electrolytes still face challenges in terms of mechanical properties,...


2020 ◽  
Vol 8 (44) ◽  
pp. 23344-23353
Author(s):  
Pengfei Zhai ◽  
Na Peng ◽  
Zeyu Sun ◽  
Wenjia Wu ◽  
Weijie Kou ◽  
...  

Thin laminar composite solid electrolyte with high mechanical strength and ionic conductivity imparts the Li–S battery an excellent electrochemical performance.


2012 ◽  
Vol 182-183 ◽  
pp. 278-282
Author(s):  
Yan Mu ◽  
Ying Li Fu ◽  
Feng Qing Zhao

A high performance water resistance agent KD-3 prepared from OPC cement, fly ash, slag and additives was used for the modification of hemi-hydrate desulphurization gypsum. Various factors on gypsum block were investigated. The prepared gypsum block possesses excellent water-resistance, good operating property and high mechanical strength. The optimized results was obtained: calcined gypsum 74.9%, KD-3 25%, retarder 0.1%, curing temperature 60°C and curing time 16h.


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