A self-templating method for metal–organic frameworks to construct multi-shelled bimetallic phosphide hollow microspheres as highly efficient electrocatalysts for hydrogen evolution reaction

2019 ◽  
Vol 7 (14) ◽  
pp. 8602-8608 ◽  
Author(s):  
Yunmei Du ◽  
Mingjuan Zhang ◽  
Zuochao Wang ◽  
Yanru Liu ◽  
Yongjun Liu ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Environmentally Friendly ◽  
Hollow Microspheres ◽  
Great Promise ◽  
Templating Method ◽  
Energy Technologies ◽  
Metal Organic ◽  
Cost Efficient

Hydrogen evolution reaction (HER) via electrocatalysis using cost-efficient bimetallic phosphide as electrocatalyst holds a great promise for environmentally friendly energy technologies.

Surface anion-rich NiS2 hollow microspheres derived from metal–organic frameworks as a robust electrocatalyst for the hydrogen evolution reaction

2017 ◽  
Vol 5 (39) ◽  
pp. 20985-20992 ◽  
Author(s):  
Tian Tian ◽  
Lan Huang ◽  
Lunhong Ai ◽  
Jing Jiang
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Hollow Microspheres ◽  
Excellent Performance ◽  
Metal Organic

Surface anion-rich NiS2 hollow microspheres derived from metal–organic frameworks exhibit excellent performance for electrocatalyzing the hydrogen evolution reaction with expected activity and durability.

Recent progress in pristine MOF-based catalysts for electrochemical hydrogen evolution, oxygen evolution and oxygen reduction

2021 ◽  
Author(s):  
Lili Fan ◽  
Zixi Kang ◽  
Mengfei Li ◽  
Daofeng Sun
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Hydrogen Evolution ◽  
Oxygen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Reduction Reaction ◽  
Metal Organic

Among various kinds of materials that have been investigated as electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR), metal-organic frameworks (MOFs) emerge as...

scholarly journals Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yamei Sun ◽  
Ziqian Xue ◽  
Qinglin Liu ◽  
Yaling Jia ◽  
Yinle Li ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Catalyst Design ◽  
Single Atom ◽  
Hydrogen Energy ◽  
Structure Of Metal ◽  
Metal Organic

AbstractDeveloping high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu0.13-BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36 mV at a current density of 10 mA cm−2 in 1 M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.

scholarly journals Cobalt-Based Metal-Organic Frameworks and Their Derivatives for Hydrogen Evolution Reaction

2020 ◽  
Vol 8 ◽  
Author(s):  
Wenjuan Han ◽  
Minhan Li ◽  
Yuanyuan Ma ◽  
Jianping Yang
Keyword(s):  
Hydrogen Production ◽  
Hydrogen Evolution ◽  
Water Splitting ◽  
Hydrogen Evolution Reaction ◽  
Alternative Energy ◽  
Metal Organic Frameworks ◽  
Electrochemical Performances ◽  
Promising Alternative ◽  
Metal Organic ◽  
Electrochemical Water Splitting

Hydrogen has been considered as a promising alternative energy to replace fossil fuels. Electrochemical water splitting, as a green and renewable method for hydrogen production, has been drawing more and more attention. In order to improve hydrogen production efficiency and lower energy consumption, efficient catalysts are required to drive the hydrogen evolution reaction (HER). Cobalt (Co)-based metal-organic frameworks (MOFs) are porous materials with tunable structure, adjustable pores and large specific surface areas, which has attracted great attention in the field of electrocatalysis. In this review, we focus on the recent progress of Co-based metal-organic frameworks and their derivatives, including their compositions, morphologies, architectures and electrochemical performances. The challenges and development prospects related to Co-based metal-organic frameworks as HER electrocatalysts are also discussed, which might provide some insight in electrochemical water splitting for future development.

Metal–organic frameworks based on tetraphenylpyrazine-derived tetracarboxylic acid for electrocatalytic hydrogen evolution reaction and NAC sensing

CrystEngComm ◽  
2019 ◽  
Vol 21 (3) ◽  
pp. 494-501 ◽  
Author(s):  
Tao Wang ◽  
Kun Huang ◽  
Mengni Peng ◽  
Xianglin Li ◽  
Defang Han ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Tetracarboxylic Acid ◽  
Metal Organic

Tetraphenylpyrazine-derived tetracarboxylic acid-based new MOFs and their promising applications in the electrocatalytic hydrogen evolution reaction.

Copper‐Metal Organic Frameworks Electrodeposited on Carbon Paper as an Enhanced Cathode for the Hydrogen Evolution Reaction

2019 ◽  
Vol 6 (17) ◽  
pp. 4507-4510 ◽  
Author(s):  
Xiao‐Feng Li ◽  
Miao‐Yu Lu ◽  
Hai‐Yang Yu ◽  
Tian‐Heng Zhang ◽  
Jiao Liu ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Carbon Paper ◽  
Copper Metal ◽  
Metal Organic

Modulating Electronic Structure of Metal-Organic Frameworks by Introducing Atomically Dispersed Ru for Efficient Hydrogen Evolution

2020 ◽  
Author(s):  
Yamei Sun ◽  
Ziqian Xue ◽  
Qinglin Liu ◽  
Yaling Jia ◽  
Yinle Li ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Catalyst Design ◽  
Single Atom ◽  
Hydrogen Energy ◽  
Structure Of Metal ◽  
Metal Organic

Abstract Developing high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction (HER) electrocatalyst (NiRu0.13-BDC, BDC: terephthalic acid) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding HER activity in all pH, especially with a low overpotential of only 36 mV at a current density of 10 mA cm-2 in 1 M phosphate buffered saline (PBS) solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.

Co-Fe-P nanotubes electrocatalysts derived from metal-organic frameworks for efficient hydrogen evolution reaction under wide pH range

Nano Energy ◽  
2019 ◽  
Vol 56 ◽  
pp. 225-233 ◽  
Author(s):  
Jiahui Chen ◽  
Jianwen Liu ◽  
Jin-Qi Xie ◽  
Huangqing Ye ◽  
Xian-Zhu Fu ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Wide Ph Range ◽  
Metal Organic ◽  
Ph Range

ZnxCo1–xMoS3 Microboxes from Metal–Organic Frameworks as Efficient Electrocatalysts for Hydrogen Evolution Reaction

2019 ◽  
Vol 7 (11) ◽  
pp. 9800-9807 ◽  
Author(s):  
Li Zhang ◽  
Lifan Yang ◽  
Guancheng Xu ◽  
Weiwei Wang ◽  
Huijun Song ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Metal Organic Frameworks ◽  
Metal Organic
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