Frustration between two- and three-dimensional smectic ordering leads to a biaxial nematic phase
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T-shaped bolaamphiphiles develop 2D smectic ordering which is incompatible with the initial lamellar structure, with both structures becoming short-ranged and resulting in a 3D biaxial nematic phase with macroscopic orthorhombic symmetry.
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2011 ◽
Vol 540
(1)
◽
pp. 42-49
◽
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