Formation of highly porous CuCo2O4 nanosheet assemblies for high-rate and long-term lithium storage

2019 ◽  
Vol 3 (12) ◽  
pp. 3370-3374 ◽  
Author(s):  
Jia Li ◽  
Yongxing Zhang ◽  
Li Li ◽  
Lixun Cheng ◽  
Song Dai ◽  
...  

Mixed transition metal oxides with high theoretical capacity show great potential to replace carbonaceous anode materials in lithium-ion batteries.

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Peng Zhang ◽  
Danjun Wang ◽  
Qizhen Zhu ◽  
Ning Sun ◽  
Feng Fu ◽  
...  

Abstract Bi2MoO6 is a potentially promising anode material for lithium-ion batteries (LIBs) on account of its high theoretical capacity coupled with low desertion potential. Due to low conductivity and large volume expansion/contraction during charge/discharge cycling of Bi2MoO6, effective modification is indispensable to address these issues. In this study, a plate-to-layer Bi2MoO6/Ti3C2Tx (MXene) heterostructure is proposed by electrostatic assembling positive-charged Bi2MoO6 nanoplates on negative-charged MXene nanosheets. MXene nanosheets in the heterostructure act as a highly conductive substrate to load and anchor the Bi2MoO6 nanoplates, so as to improve electronic conductivity and structural stability. When the mass ratio of MXene is optimized to 30%, the Bi2MoO6/MXene heterostructure exhibits high specific capacities of 692 mAh g−1 at 100 mA g−1 after 200 cycles and 545.1 mAh g−1 with 99.6% coulombic efficiency at 1 A g−1 after 1000 cycles. The results provide not only a high-performance lithium storage material, but also an effective strategy that could address the intrinsic issues of various transition metal oxides by anchoring them on MXene nanosheets to form heterostructures and use as anode materials for LIBs.


2018 ◽  
Vol 6 (16) ◽  
pp. 7070-7079 ◽  
Author(s):  
Long Pan ◽  
Zheng-Wei Zhou ◽  
Yi-Tao Liu ◽  
Xu-Ming Xie

A universal strategy is proposed for thein situsynthesis of TiO2(B) nanosheets on pristine carbon nanomaterials. Benefiting from a remarkable synergistic effect, the resulting nanohybrids exhibit superior high-rate lithium storage performance. In this sense, our strategy may open the door to next-generation, high-power and high-energy anode materials for lithium-ion batteries.


2021 ◽  
Author(s):  
Ni Wen ◽  
Siyuan Chen ◽  
xiaolong Li ◽  
Ke Zhang ◽  
Jingjie Feng ◽  
...  

Transition metal oxides (TMOs) are prospective anode materials for lithium-ion batteries (LIBs) owing to their high theoretical specific capacity. Whereas, the inherent low conductivity of TMOs restricts its application. Given...


2019 ◽  
Vol 48 (5) ◽  
pp. 1906-1914 ◽  
Author(s):  
Wenwen Chai ◽  
Fan Yang ◽  
Weihao Yin ◽  
Shunzhang You ◽  
Ke Wang ◽  
...  

Bi2S3 is a promising negative electrode material for lithium storage owing to its high theoretical capacity. During the Bi2S3/C synthesis process, the carbonization of H3BTC prevents aggregation of Bi2S3 particles, with an average diameter of 60 nm.


2021 ◽  
Author(s):  
Yaqin Zhu ◽  
Jiachang Zhao ◽  
Lanjie Li ◽  
Jingli Xu ◽  
Xinxin Zhao ◽  
...  

The emerging Bi2Se3-based anode materials arouse great interest for lithium storage because of its high theoretical capacity. Although quite attractive, Bi2Se3 still faces with the problem of large volume expansion...


2019 ◽  
Vol 14 (1) ◽  
Author(s):  
Zongyang Li ◽  
Lian Ying Zhang ◽  
Lei Zhang ◽  
Jiamu Huang ◽  
Hongdong Liu

AbstractAs a typical metal selenide, CoSe is a kind of foreground anode material for lithium-ion batteries (LIBs) because of its two-dimensional layer structure, good electrical conductivity, and high theoretical capacity. In this work, the original CoSe/N-doped carbon (CoSe/NC) composites were synthesized using ZIF-67 as a precursor, in which the CoSe nanoparticles are encapsulated in NC nanolayers and they are connected through C–Se bonds. The coating structure and strong chemical coupling make the NC nanolayers could better effectively enhance the lithium storage properties of CoSe/NC composites. As a consequence, the CoSe/NC composites deliver a reversible capacity of 310.11 mAh g−1 after 500 cycles at 1.0 A g−1. Besides, the CoSe/NC composites show a distinct incremental behavior of capacity.


Nanoscale ◽  
2022 ◽  
Author(s):  
zhiwen Long ◽  
Chu Shi ◽  
Caiqin Wu ◽  
Luhan Yuan ◽  
Hui Qiao ◽  
...  

Fe2O3 as anode for lithium-ion batteries has attracted intense attention because of its high theoretical capacity, natural abundance and good safety. However, the inferior cycling stability, low-rate performance and limited...


2018 ◽  
Vol 6 (16) ◽  
pp. 7005-7013 ◽  
Author(s):  
Shiyao Lu ◽  
Tianxiang Zhu ◽  
Zhaoyang Li ◽  
Yuanchao Pang ◽  
Lei Shi ◽  
...  

Ultrafine Ni3V2O8@CMK-3 nanocomposites with long-term and high-rate lithium storage capability have been developed.


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