Catalytic conversion of ferrous carbonate to higher hydrocarbons under mild conditions and its application in transformation of CO2 to liquid fuels

2020 ◽  
Vol 4 (1) ◽  
pp. 96-100 ◽  
Author(s):  
Yulv Yu ◽  
Jin Huang ◽  
Yuan Wang
Keyword(s):  
Catalytic Conversion ◽  
Liquid Fuels ◽  
Mild Conditions ◽  
Higher Hydrocarbons ◽  
Ferrous Carbonate ◽  
Long Chain

Coupling conversion of CO32− to hydrocarbons with carbonation of ferrous species by CO2 leads to the generation of long-chain hydrocarbons.

ChemInform Abstract: Heterogeneous Catalytic Conversion of Biobased Chemicals into Liquid Fuels in the Aqueous Phase

ChemInform ◽  
2016 ◽  
Vol 47 (35) ◽  
Author(s):  
Kejing Wu ◽  
Yulong Wu ◽  
Yu Chen ◽  
Hao Chen ◽  
Jianlong Wang ◽  
...  
Keyword(s):  
Aqueous Phase ◽  
Catalytic Conversion ◽  
Liquid Fuels ◽  
Heterogeneous Catalytic ◽  
Biobased Chemicals

DIRECT CATALYTIC CONVERSION OF METHANE TO HIGHER HYDROCARBONS

1987 ◽  
Vol 5 (2) ◽  
pp. 169-183 ◽  
Author(s):  
Prasad S. Yarlagadda ◽  
Lawrence A. Morton ◽  
Norman R. Hunter ◽  
Hyman D. Gesser
Keyword(s):  
Catalytic Conversion ◽  
Conversion Of Methane ◽  
Higher Hydrocarbons

Novel process and catalytic materials for converting CO2 and H2 containing mixtures to liquid fuels and chemicals

2015 ◽  
Vol 183 ◽  
pp. 197-215 ◽  
Author(s):  
Nora Meiri ◽  
Yakov Dinburg ◽  
Meital Amoyal ◽  
Viatcheslav Koukouliev ◽  
Roxana Vidruk Nehemya ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Performance ◽  
Reaction Rates ◽  
Operating Conditions ◽  
Reactor System ◽  
Liquid Fuels ◽  
High Productivity ◽  
Carbide Phases ◽  
Production Of Hydrogen ◽  
Higher Hydrocarbons

Carbon dioxide and water are renewable and the most abundant feedstocks for the production of chemicals and fungible fuels. However, the current technologies for production of hydrogen from water are not competitive. Therefore, reacting carbon dioxide with hydrogen is not economically viable in the near future. Other alternatives include natural gas, biogas or biomass for the production of carbon dioxide, hydrogen and carbon monoxide mixtures that react to yield chemicals and fungible fuels. The latter process requires a high performance catalyst that enhances the reverse water-gas-shift (RWGS) reaction and Fischer–Tropsch synthesis (FTS) to higher hydrocarbons combined with an optimal reactor system. Important aspects of a novel catalyst, based on a Fe spinel and three-reactor system developed for this purpose published in our recent paper and patent, were investigated in this study. Potassium was found to be a key promoter that improves the reaction rates of the RWGS and FTS and increases the selectivity of higher hydrocarbons while producing mostly olefins. It changed the texture of the catalyst, stabilized the Fe–Al–O spinel, thus preventing decomposition into Fe3O4 and Al2O3. Potassium also increased the content of Fe5C2 while shifting Fe in the oxide and carbide phases to a more reduced state. In addition, it increased the relative exposure of carbide iron on the catalysts surface, the CO2 adsorption and the adsorption strength. A detailed kinetic model of the RWGS, FTS and methanation reactions was developed for the Fe spinel catalyst based on extensive experimental data measured over a range of operating conditions. Significant oligomerization activity of the catalyst was found. Testing the pelletized catalyst with CO2, CO and H2 mixtures over a range of operating conditions demonstrated its high productivity to higher hydrocarbons. The composition of the liquid (C5+) was found to be a function of the potassium content and the composition of the feedstock.

One-pot catalytic conversion of microalgae (Chlorococcum sp.) into 5-hydroxymethylfurfural over the commercial H-ZSM-5 zeolite

2016 ◽  
Vol 18 (2) ◽  
pp. 452-460 ◽  
Author(s):  
J. J. Wang ◽  
Z. C. Tan ◽  
C. C. Zhu ◽  
G. Miao ◽  
L. Z. Kong ◽  
...  
Keyword(s):  
Catalytic Conversion ◽  
Experimental Results ◽  
High Yield ◽  
One Pot ◽  
Mild Conditions ◽  
Zeolite P

A high yield of HMF is directly obtained from aquatic microalgae over a commercial acidic zeolite under mild conditions. Experimental results reveal that proteins and lipids in microalgal cells benefit the HMF stability in water.

scholarly journals Heterogeneous catalytic hydrogenation of CO2 to methanol: recent advances and prospects

2020 ◽  
Vol 61 (2) ◽  
pp. 57-67
Author(s):  
Shahla Firiddun Taghiyevа ◽  
Keyword(s):  
Climate Change ◽  
Carbon Dioxide ◽  
Carbon Dioxide Emissions ◽  
Power Plants ◽  
Catalytic Conversion ◽  
Raw Material ◽  
Liquid Fuels ◽  
Industrial Chemicals ◽  
Heterogeneous Catalytic ◽  
Reduce Carbon Dioxide

Carbon dioxide is the main source of the greenhouse effect, causing global warming and climate change. In this regard, in order to avoid more dangerous consequences, the United Nations Conference on Climate Change has emphasized the need to reduce carbon dioxide emissions by at least half their current value by 2050, aiming to limit the global increase in average temperature to a maximum of 2 °C. Carbon dioxide is emitted mainly from power plants (e.g., coal-based) and vehicles, and other industrial sources contribute to an increase in CO2 emissions. In recent years, the scientific community has begun to view CO2 not as a costly waste, but mainly as a potential carbon alternative to fossils. Therefore, future prospects for reducing carbon dioxide emissions will concern not only the development of more efficient carbon dioxide storage technologies, but also the development of new strategies for CO2 processing in the energetical direction and in chemical intermediate products. In this regard, the conversion of CO2 to methanol has received increased attention, since methanol (CH3OH) is a key raw material for industrial chemicals, which can later be converted to high molecular weight alternative liquid fuels. The review considers works published over the past 10 years on the heterogeneous catalytic conversion of CO2 to methanol. The characteristics of the used catalysts, reaction mechanisms, key technologies and problems of industrial use, prospects for the application of heterogeneous catalytic conversion of CO2 to hydrocarbons are discussed.

scholarly journals Production of alkanes from CO2 by engineered bacteria

2018 ◽  
Author(s):  
Tapio Lehtinen ◽  
Henri Virtanen ◽  
Suvi Santala ◽  
Ville Santala
Keyword(s):  
Production Systems ◽  
Liquid Fuels ◽  
Modular System ◽  
Fatty Aldehyde ◽  
Efficient Production ◽  
Acinetobacter Baylyi ◽  
Single Organism ◽  
Fuels And Chemicals ◽  
Microbial Biosynthesis ◽  
Long Chain

AbstractBackgroundMicrobial biosynthesis of alkanes is considered a promising method for the sustainable production of drop-in fuels and chemicals. Carbon dioxide would be an ideal carbon source for these production systems, but efficient production of long carbon chains from CO2is difficult to achieve in a single organism. A potential solution is to employ acetogenic bacteria for the reduction of CO2to acetate, and engineer a second organism to convert the acetate into long-chain hydrocarbons.ResultsIn this study, we demonstrate alkane production from CO2by a system combining the acetogenAcetobacterium woodiiand a non-native alkane producerAcinetobacter baylyiADP1 engineered for alkane production. Nine synthetic two-step alkane biosynthesis pathways consisting of different aldehyde- and alkane-producing enzymes were combinatorically constructed and expressed inA. baylyi.The aldehyde-producing enzymes studied were AAR fromSynechococcus elongatus,Acr1 fromA. baylyi,and Ramo, a putative dehydrogenase, fromNevskia ramosa.The alkane-producing enzymes were ADOs fromS. elongatusandNostoc punctiforme,and CER1 fromArabidopsis thaliana.The performance of the pathways was evaluated with a twin-layer biosensor, which allowed the monitoring of both the intermediate, fatty aldehyde, as well as the alkane production. The highest alkane production, as indicated by the biosensor, was achieved with a pathway consisting of AAR and ADO fromS. elongatus.The performance of this pathway was further improved by balancing the relative expression levels of the enzymes in order to limit the accumulation of the intermediate fatty aldehyde. Finally, the acetogenA. woodiiwas used to produce acetate from CO2and H2, and the acetate was used for alkane production by the engineeredA. baylyi,thereby leading to the net production of long-chain alkanes from CO2.ConclusionsA modular system for the production of drop-in liquid fuels from CO2was demonstrated. Among the studied synthetic pathways, the combination of ADO and AAR fromS. elongatuswas found to be the most efficient in heterologous alkane production inA. baylyi.Furthermore, limiting the accumulation of the fatty aldehyde intermediate was found to be beneficial for the alkane production.

scholarly journals Catalytic Conversion From Plastic Waste by Silica-Alumina-Ceramic Catalyst to Produce an Alternative Fuel Hydrocarbon Fraction

2019 ◽  
Vol 20 (2) ◽  
pp. 83
Author(s):  
Hendro Juwono ◽  
M. Arif Tri Sujadmiko ◽  
Laily Fauziah ◽  
Ismi Qurrota Ayyun
Keyword(s):  
Catalytic Cracking ◽  
Catalytic Conversion ◽  
Plastic Waste ◽  
Liquid Fuels ◽  
Commercial Gasoline ◽  
Silica Alumina ◽  
Gas Chromatography Mass Spectroscopy ◽  
Adsorption Desorption ◽  
Ceramic Catalyst ◽  
Mcm 41

Liquid fuels from polypropylene plastic waste have been successfully performed by catalytic cracking method. The catalyst used is Al-MCM-41- Ceramics. The catalyst was characterized by XRD, SEM, Pyridine-FTIR, N2-Adsorption-Desorption, and the product of catalytic cracking were investigated by gas chromatography-mass spectroscopy (GC-MS). The catalyst was using three times at sample notify A,B and C. The results showed liquid fuels have the largest percentage of gasoline (C8-C12) are 92.76; 91.92 and 90.58 percent fraction produced. The performance of catalyst showed that reuseability number were decrease, but the charactersitic of liquid fuel produced were also be agreeable to commercial gasoline standard. Keywords: olypropylene waste plastics, liquid fuels, catalytic conversion, Al-MCM-41-Cer catalyst, reuseability number.

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