Facile room-temperature growth of nanostructured CuBi2O4 for selective electrochemical reforming and photoelectrochemical hydrogen evolution reactions

2020 ◽  
Vol 4 (2) ◽  
pp. 625-632 ◽  
Author(s):  
Chia-Yu Lin ◽  
Shao-Yu Lin ◽  
Ming-Chun Tsai ◽  
Cheng-Hsien Wu

Facile, room-temperature, and surfactant-free seed-mediated chemical bath deposition was developed to directly grow nanostructured CuBi2O4 with promising properties towards electro-reforming of glucose and PEC hydrogen generation.

2020 ◽  
Vol 59 (49) ◽  
pp. 22171-22178 ◽  
Author(s):  
Wei‐Hong Lai ◽  
Heng Wang ◽  
Lirong Zheng ◽  
Quan Jiang ◽  
Zi‐Chao Yan ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1014 ◽  
Author(s):  
Clay Huff ◽  
Julia M. Long ◽  
Tarek M. Abdel-Fattah

The unsustainable nature of carbon-based fuels has prompted scientists and engineers to investigate alternative sources of energy. Silver nanoparticle networks (AgNPNs) were synthesized using beta-cyclodextrin for applications in hydrogen evolution reactions from sodium borohydride (NaBH4). The identities of the AgNPNs were confirmed using ultraviolet–visible spectroscopy, X-ray diffraction, and Transmission electron microscopy (TEM). The catalytic activity of the hydrogen evolution reactions was measured using a gravimetric water displacement system. The data collected show an increase in the efficiency of the hydrogen generation reaction with the addition of AgNPN. The silver nanoparticle network catalyst performed best at 22 °C with an increased concentration of NaBH4 producing hydrogen at a rate of 0.961 mL∙min−1∙mLcat−1. The activation energy was calculated to be 50.3 kJ/mol.


2020 ◽  
Vol 8 (27) ◽  
pp. 13694-13701 ◽  
Author(s):  
Wei Wang ◽  
Xiaoling Hong ◽  
Qilu Yao ◽  
Zhang-Hui Lu

NiPt NPs immobilized on mesoporous N-doped carbon have been facilely synthesized for efficient and complete hydrogen generation from N2H4BH3 solution at room temperature.


2020 ◽  
Vol 132 (49) ◽  
pp. 22355-22362
Author(s):  
Wei‐Hong Lai ◽  
Heng Wang ◽  
Lirong Zheng ◽  
Quan Jiang ◽  
Zi‐Chao Yan ◽  
...  

MRS Advances ◽  
2020 ◽  
Vol 5 (63) ◽  
pp. 3353-3360
Author(s):  
Susana Helena Arellano Ramírez ◽  
Perla García Casillas ◽  
Christian Chapa González

AbstractA significant area of research is biomedical applications of nanoparticles which involves efforts to control the physicochemical properties through simple and scalable processes. Gold nanoparticles have received considerable attention due to their unique properties that they exhibit based on their morphology. Gold nanospheres (AuNSs) and nanorods (AuNRs) were prepared with a seed-mediated method followed of polyethylene glycol (PEG)-coating. The seeds were prepared with 0.1 M cetyltrimethyl-ammonium bromide (CTAB), 0.005 M chloroauric acid (HAuCl4), and 0.01 M sodium borohydride (NaBH4) solution. Gold nanoparticles with spherical morphology was achieved by growth by aggregation at room temperature, while to achieve the rod morphology 0.1 M silver nitrate (AgNO3) and 0.1 M ascorbic acid solution were added. The gold nanoparticles obtained by the seed-mediated synthesis have spherical or rod shapes, depending on the experimental conditions, and a uniform particle size. Surface functionalization was developed using polyethylene glycol. Morphology, and size distribution of AuNPs were evaluated by Field Emission Scanning Electron Microscopy. The average size of AuNSs, and AuNRs was 7.85nm and 7.96 x 31.47nm respectively. Fourier transform infrared spectrometry was performed to corroborate the presence of PEG in the AuNPs surface. Additionally, suspensions of AuNSs and AuNRs were evaluated by UV-Vis spectroscopy. Gold nanoparticles were stored for several days at room temperature and it was observed that the colloidal stability increased once gold nanoparticles were coated with PEG due to the shield formed in the surface of the NPs and the increase in size which were 9.65±1.90 nm of diameter for AuNSs and for AuNRs were 29.03±5.88 and 8.39±1.02 nm for length and transverse axis, respectively.


Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 10974-10981 ◽  
Author(s):  
Xiulin Yang ◽  
Ang-Yu Lu ◽  
Yihan Zhu ◽  
Shixiong Min ◽  
Mohamed Nejib Hedhili ◽  
...  

High surface area FeP nanosheets on a carbon cloth were prepared by gas phase phosphidation of electroplated FeOOH, which exhibit exceptionally high catalytic efficiency and stability for hydrogen generation.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Xiaoshuang Chen ◽  
Meina Ju ◽  
Kun Song ◽  
Guoli Chen ◽  
Rui Yang ◽  
...  

Hydrogen generation via water electroreduction is a pivotal portion of exploiting clean-energy skills. Nevertheless, developing a low price and high-performance catalytic activity substance to take the place of expensively precious...


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