scholarly journals Synthesis of a binary alloy nanoparticle catalyst with an immiscible combination of Rh and Cu assisted by hydrogen spillover on a TiO2 support

2020 ◽  
Vol 11 (16) ◽  
pp. 4194-4203 ◽  
Author(s):  
Shinya Masuda ◽  
Kazuki Shun ◽  
Kohsuke Mori ◽  
Yasutaka Kuwahara ◽  
Hiromi Yamashita
Keyword(s):  
Solid Solution ◽  
Binary Alloy ◽  
Hydrogen Spillover ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Binary Solid Solution ◽  
Tio2 Support ◽  
Nanoparticle Catalyst ◽  
Non Equilibrium

This work demonstrates the use of TiO2 as a promising platform for the synthesis of non-equilibrium binary solid solution alloy nanoparticles with a combination of immiscible Rh and Cu assisted by the hydrogen spillover.

scholarly journals Enhanced catalytic activity of inhomogeneous Rh-based solid-solution alloy nanoparticles

RSC Advances ◽  
2019 ◽  
Vol 9 (66) ◽  
pp. 38882-38890 ◽  
Author(s):  
Md Samiul Islam Sarker ◽  
Takahiro Nakamura ◽  
Satoshi Kameoka ◽  
Yuichiro Hayasaka ◽  
Shu Yin ◽  
...  
Keyword(s):  
Solid Solution ◽  
Catalytic Activity ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Solution Structures ◽  
Homogeneous Solid Solution

Catalytic Rh-based alloy nanoparticles (NPs) with inhomogeneous solid-solution structures were prepared from homogeneous solid-solution alloy NPs.

scholarly journals Formation of Au/Pd Alloy Nanoparticles on TMV

2010 ◽  
Vol 2010 ◽  
pp. 1-6 ◽  
Author(s):  
Jung-Sun Lim ◽  
Seung-Min Kim ◽  
Sang-Yup Lee ◽  
Eric A. Stach ◽  
James N. Culver ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Solid Solution ◽  
Genetically Engineered ◽  
Solid Solution Alloy ◽  
Alloy Formation ◽  
Alloy Nanoparticles ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
Pd Alloy ◽  
Electron Energy Loss

A gold-palladium (AuPd) solid solution alloy was successfully deposited on the genetically engineered tobacco mosaic virus (TMV1Cys) by the biosorption of Au(III) and Pd(II) precursors and the reduction of the Au(III) and Pd(II) to their respective metals or metal alloy. The resulting morphologies of alloy nanoparticles deposited on the TMV1Cys were observed with transmission electron microscopy (TEM), and the AuPd alloy formation was supported with surface plasmon resonance (SPR) and selected area electron diffraction (SAED). In addition, selected alloy nanoparticles on the TMV1Cys were analyzed further with electron energy loss spectroscopy (EELS) to confirm the presence of gold and palladium. Our result implies that biotemplated metal mineralization is a potentially useful methodology to prepare alloy nanoparticles.

Crystal Structure-dependent Thermal Stability and Catalytic Performance of AuRu3 Solid-solution Alloy Nanoparticles

2018 ◽  
Vol 47 (4) ◽  
pp. 559-561 ◽  
Author(s):  
Quan Zhang ◽  
Kohei Kusada ◽  
Dongshuang Wu ◽  
Shogo Kawaguchi ◽  
Yoshiki Kubota ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Stability ◽  
Solid Solution ◽  
Catalytic Performance ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles

scholarly journals Solid-Solution Alloy Nanoparticles of the Immiscible Iridium-Copper System with a Wide Composition Range for Enhanced Electrocatalytic Applications

2018 ◽  
Vol 130 (17) ◽  
pp. 4595-4599 ◽  
Author(s):  
Fenglong Wang ◽  
Kohei Kusada ◽  
Dongshuang Wu ◽  
Tomokazu Yamamoto ◽  
Takaaki Toriyama ◽  
...  
Keyword(s):  
Solid Solution ◽  
Composition Range ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Wide Composition Range

Crystalline to amorphous transformation in solid-solution alloy nanoparticles induced by boron doping

2020 ◽  
Vol 56 (85) ◽  
pp. 12941-12944
Author(s):  
Keigo Kobayashi ◽  
Kohei Kusada ◽  
Dongshuang Wu ◽  
Naoki Ogiwara ◽  
Hirokazu Kobayashi ◽  
...  
Keyword(s):  
Solid Solution ◽  
Long Range ◽  
Boron Doping ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Atomic Correlation

Synthesis of Pd–Ru–B solid-solution alloy is first reported. Alloying of B atoms into Pd–Ru alloy is accompanied by a characteristic crystalline–amorphous transformation to results in the disappearance of long-range atomic correlation.

Synthesis of Mo and Ru solid-solution alloy NPs and their hydrogen evolution reaction activity

2020 ◽  
Vol 56 (92) ◽  
pp. 14475-14478
Author(s):  
Shinya Okazoe ◽  
Kohei Kusada ◽  
Dongshuang Wu ◽  
Tomokazu Yamamoto ◽  
Takaaki Toriyama ◽  
...  
Keyword(s):  
Solid Solution ◽  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Carbonyl Complexes

We report the synthesis of MoRu solid-solution alloy nanoparticles using carbonyl complexes as a precursor through a thermal decomposition, and their catalytic activity for hydrogen evolution reaction.

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