Oxygen atom transfer with organofunctionalized polyoxovanadium clusters: O-atom vacancy formation with tertiary phosphanes and deoxygenation of styrene oxide

Brittney E. Petel; Rachel L. Meyer; William W. Brennessel; Ellen M. Matson

doi:10.1039/c9sc02882j

Oxygen atom transfer with organofunctionalized polyoxovanadium clusters: O-atom vacancy formation with tertiary phosphanes and deoxygenation of styrene oxide

Chemical Science ◽

10.1039/c9sc02882j ◽

2019 ◽

Vol 10 (34) ◽

pp. 8035-8045 ◽

Cited By ~ 6

Author(s):

Brittney E. Petel ◽

Rachel L. Meyer ◽

William W. Brennessel ◽

Ellen M. Matson

Keyword(s):

Oxygen Atom ◽

Styrene Oxide ◽

Vacancy Formation ◽

Atom Transfer ◽

Oxygen Atom Transfer

We report a rare example of oxygen atom transfer (OAT) from a polyoxometalate cluster to a series of tertiary phosphanes followed by OAT from styrene oxide to the reduced scaffold, resulting in the formation of styrene.

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Molybdenum-Oxo and Peroxo Complexes in Oxygen Atom Transfer Processes with O2as the Primary Oxidant

Current Inorganic Chemistry ◽

10.2174/1877944111101020140 ◽

2011 ◽

Vol 1 (2) ◽

pp. 140-145 ◽

Cited By ~ 6

Author(s):

Henri Arzoumanian

Keyword(s):

Oxygen Atom ◽

Atom Transfer ◽

Peroxo Complexes ◽

Oxygen Atom Transfer ◽

Transfer Processes

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Oxygen Atom Transfer as Key To Reverse Regioselectivity in the Gold(I)-Catalyzed Generation of Aminooxazoles from Ynamides

The Journal of Organic Chemistry ◽

10.1021/acs.joc.0c02584 ◽

2020 ◽

Author(s):

Dmitry P. Zimin ◽

Dmitry V. Dar’in ◽

Vadim Yu. Kukushkin ◽

Alexey Yu. Dubovtsev

Keyword(s):

Oxygen Atom ◽

Atom Transfer ◽

Oxygen Atom Transfer

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Oxygen Atom Transfer Catalysis by Dioxidomolybdenum(VI) Complexes of Pyridyl Aminophenolate Ligands

Polyhedron ◽

10.1016/j.poly.2021.115234 ◽

2021 ◽

pp. 115234

Author(s):

Md. Kamal Hossain ◽

Jörg A. Schachner ◽

Matti Haukka ◽

Michael G. Richmond ◽

Nadia C. Mösch-Zanetti ◽

...

Keyword(s):

Oxygen Atom ◽

Atom Transfer ◽

Oxygen Atom Transfer

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Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

Inorganic Chemistry Frontiers ◽

10.1039/d1qi00308a ◽

2021 ◽

Author(s):

Leila G. Ranis ◽

Jacqueline Gianino ◽

Justin M. Hoffman ◽

Seth N. Brown

Keyword(s):

Oxygen Atom ◽

Transfer Reaction ◽

Transfer Reactions ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Oxygen Atom Transfer Reactions ◽

Atom Transfer Reactions ◽

Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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Catalytic oxygen atom transfer reactions

Transition Metal Chemistry ◽

10.1007/bf01096756 ◽

1985 ◽

Vol 10 (11) ◽

pp. 439-440 ◽

Cited By ~ 3

Author(s):

B. F. G. Johnson ◽

M. V. Twigg

Keyword(s):

Oxygen Atom ◽

Transfer Reactions ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Oxygen Atom Transfer Reactions ◽

Atom Transfer Reactions

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ChemInform Abstract: Synthesis, Characterization, and Oxygen Atom Transfer Reactions of (HB(Me2C3N2H)3)MoO(S2P(OR)2) and (HB(Me2C3N2H)3)MoO2(η1-S2P(OEt)2).

ChemInform ◽

10.1002/chin.198851277 ◽

1988 ◽

Vol 19 (51) ◽

Author(s):

S. A. ROBERTS ◽

C. G. YOUNG ◽

W. E. JUN. CLELAND ◽

R. B. ORTEGA ◽

J. H. ENEMARK

Keyword(s):

Oxygen Atom ◽

Transfer Reactions ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Oxygen Atom Transfer Reactions ◽

Atom Transfer Reactions

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Influence of the Oxygen Atom Acceptor on the Reaction Coordinate and Mechanism of Oxygen Atom Transfer From the Dioxo-Mo(VI) Complex, TpiPrMoO2(OPh), to Tertiary Phosphines

Inorganic Chemistry ◽

10.1021/ic902500h ◽

2010 ◽

Vol 49 (11) ◽

pp. 4895-4900 ◽

Cited By ~ 25

Author(s):

Partha Basu ◽

Brian W. Kail ◽

Charles G. Young

Keyword(s):

Oxygen Atom ◽

Reaction Coordinate ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Tertiary Phosphines

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Activation of Nitroarenes in the Homogenous Catalytic Carbonylation of Nitroaromatics via an Oxygen-Atom-Transfer Mechanism Induced by Inner-Sphere Electron Transfer†

Journal of the American Chemical Society ◽

10.1021/ja971899w ◽

1997 ◽

Vol 119 (45) ◽

pp. 11049-11060 ◽

Cited By ~ 41

Author(s):

Steven J. Skoog ◽

Wayne L. Gladfelter

Keyword(s):

Electron Transfer ◽

Oxygen Atom ◽

Transfer Mechanism ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Inner Sphere ◽

Catalytic Carbonylation

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ChemInform Abstract: ROLE OF FERRYL (FEO2+) COMPLEXES IN OXYGEN ATOM TRANSFER REACTIONS. MECHANISM OF IRON(II) PORPHYRIN CATALYZED OXYGENATION OF TRIPHENYLPHOSPHINE

Chemischer Informationsdienst ◽

10.1002/chin.198047260 ◽

1980 ◽

Vol 11 (47) ◽

Author(s):

D.-H. CHIN ◽

G. N. LA MAR ◽

A. L. BALCH

Keyword(s):

Oxygen Atom ◽

Transfer Reactions ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Oxygen Atom Transfer Reactions ◽

Atom Transfer Reactions ◽

Reactions Mechanism

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Epoxidation of olefins by cytochrome P-450 model compounds: kinetics and stereochemistry of oxygen atom transfer and origin of shape selectivity

Journal of the American Chemical Society ◽

10.1021/ja00293a034 ◽

1985 ◽

Vol 107 (7) ◽

pp. 2000-2005 ◽

Cited By ~ 141

Author(s):

James P. Collman ◽

John I. Brauman ◽

Bernard Meunier ◽

Teruyuki Hayashi ◽

Thomas Kodadek ◽

...

Keyword(s):

Oxygen Atom ◽

Shape Selectivity ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Model Compounds ◽

Cytochrome P 450 ◽

Epoxidation Of Olefins

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