scholarly journals Near-infrared fluorescein dyes containing a tricoordinate boron atom

2019 ◽  
Vol 10 (33) ◽  
pp. 7816-7821 ◽  
Author(s):  
Naoki Ando ◽  
Hiroki Soutome ◽  
Shigehiro Yamaguchi
Keyword(s):  
Boron Atom ◽  
Infrared Absorption ◽  
Near Infrared ◽  
Photophysical Properties ◽  
Multi Stage ◽  
Fluorescein Dyes

Tricoordinate boron imparts near-infrared absorption/emission and unusual multi-stage changes in the photophysical properties to fluorescein dyes.

Photophysical Properties and Electronic Structure of Bacteriochlorin-Chalcones with Extended Near-Infrared Absorption

2013 ◽  
Vol 89 (3) ◽  
pp. 586-604 ◽  
Author(s):  
Eunkyung Yang ◽  
Christian Ruzié ◽  
Michael Krayer ◽  
James R. Diers ◽  
Dariusz M. Niedzwiedzki ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Infrared Absorption ◽  
Near Infrared ◽  
Photophysical Properties

Thieno[1,3,2]oxazaborinine-containing aza-BODIPYs with near infrared absorption bands: synthesis, photophysical properties, and device applications

2020 ◽  
Vol 44 (1) ◽  
pp. 29-37
Author(s):  
Yuji Kubo ◽  
Takuma Shimada ◽  
Kentaro Maeda ◽  
Yuta Hashimoto
Keyword(s):  
Infrared Absorption ◽  
Near Infrared ◽  
Photophysical Properties ◽  
Single Component ◽  
Absorption Bands ◽  
Device Applications ◽  
First Time ◽  
Infrared Absorption Bands

Structurally constrained NIR aza-BODIPYs with thieno[1,3,2]oxazaborinine were synthesized for the first time, enabling their evaluation as NIR photodetectors through fabrication of a single-component device.

Two-Dimensional Near-Infrared and Shortwave Infrared Molecular Aggregates: Taking Kasha’s Model to the Next Dimension

2019 ◽  
Author(s):  
Arundhati Deshmukh ◽  
Danielle Koppel ◽  
Chern Chuang ◽  
Danielle Cadena ◽  
Jianshu Cao ◽  
...  
Keyword(s):  
Near Infrared ◽  
Photophysical Properties ◽  
Satellite Telemetry ◽  
Transition Dipole Moment ◽  
Short Wave ◽  
Tissue Imaging ◽  
Transition Dipole ◽  
Deep Tissue Imaging ◽  
Excitonic States ◽  
Shortwave Infrared

Technologies which utilize near-infrared (700 – 1000 nm) and short-wave infrared (1000 – 2000 nm) electromagnetic radiation have applications in deep-tissue imaging, telecommunications and satellite telemetry due to low scattering and decreased background signal in this spectral region. However, there are few molecular species, which absorb efficiently beyond 1000 nm. Transition dipole moment coupling (e.g. J-aggregation) allows for redshifted excitonic states and provides a pathway to highly absorptive electronic states in the infrared. We present aggregates of two cyanine dyes whose absorption peaks redshift dramatically upon aggregation in water from ~ 800 nm to 1000 nm and 1050 nm with sheet-like morphologies and high molar absorptivities (e ~ 10<sup>5 </sup>M<sup>-1</sup>cm<sup>-1</sup>). To describe this phenomenology, we extend Kasha’s model for J- and H-aggregation to describe the excitonic states of <i> 2-dimensional aggregates</i> whose slip is controlled by steric hindrance in the assembled structure. A consequence of the increased dimensionality is the phenomenon of an <i>intermediate </i>“I-aggregate”, one which redshifts yet displays spectral signatures of band-edge dark states akin to an H-aggregate. We distinguish between H-, I- and J-aggregates by showing the relative position of the bright (absorptive) state within the density of states using temperature dependent spectroscopy. Our results can be used to better design chromophores with predictable and tunable aggregation with new photophysical properties.

Study on the Near-infrared Absorption Properties of ZnGeP2 Single Crystals

2010 ◽  
Vol 25 (10) ◽  
pp. 1029-1033
Author(s):  
Shi-Xing XIA ◽  
Chun-Hui YANG ◽  
Chong-Qiang ZHU ◽  
Tian-Hui MA ◽  
Meng WANG ◽  
...  
Keyword(s):  
Single Crystals ◽  
Infrared Absorption ◽  
Near Infrared ◽  
Absorption Properties

Pyrrole-bridged quinones: π-electronic systems that modulate electronic structures by tautomerism and deprotonation

2021 ◽  
Author(s):  
Shinya Sugiura ◽  
Hiromitsu Maeda
Keyword(s):  
Infrared Absorption ◽  
Electronic Structures ◽  
Near Infrared ◽  
Ion Pairing ◽  
Anion Binding ◽  
Electronic Systems

A new series of π-extended quinone derivatives containing a pyrrole bridge exhibited NH/OH-type tautomerization and anion binding along with deprotonation that induced near-infrared absorption and ion-pairing assemblies.

scholarly journals Characterization and mapping of hematite ore mineral classes using hyperspectral remote sensing technique: a case study from Bailadila iron ore mining region

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Ibrahim Shaik ◽  
S. K. Begum ◽  
P. V. Nagamani ◽  
Narayan Kayet
Keyword(s):  
Infrared Absorption ◽  
Near Infrared ◽  
Spectral Feature ◽  
Absorption Feature ◽  
X Ray ◽  
Remote Sensing Technique ◽  
Ore Minerals ◽  
Feature Fitting ◽  
Hematite Ore

AbstractThe study demonstrates a methodology for mapping various hematite ore classes based on their reflectance and absorption spectra, using Hyperion satellite imagery. Substantial validation is carried out, using the spectral feature fitting technique, with the field spectra measured over the Bailadila hill range in Chhattisgarh State in India. The results of the study showed a good correlation between the concentration of iron oxide with the depth of the near-infrared absorption feature (R2 = 0.843) and the width of the near-infrared absorption feature (R2 = 0.812) through different empirical models, with a root-mean-square error (RMSE) between < 0.317 and < 0.409. The overall accuracy of the study is 88.2% with a Kappa coefficient value of 0.81. Geochemical analysis and X-ray fluorescence (XRF) of field ore samples are performed to ensure different classes of hematite ore minerals. Results showed a high content of Fe > 60 wt% in most of the hematite ore samples, except banded hematite quartzite (BHQ) (< 47 wt%).

scholarly journals New Approach in the Application of Conjugated Polymers: The Light-Activated Source of Versatile Singlet Oxygen Molecule

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1098
Author(s):  
Agata Blacha-Grzechnik
Keyword(s):  
Conjugated Polymers ◽  
Singlet Oxygen ◽  
Near Infrared ◽  
Photophysical Properties ◽  
Short Review ◽  
The Novel ◽  
New Approach ◽  
Intermolecular Energy ◽  
Intermolecular Energy Transfer ◽  
High Absorption

For many years, the research on conjugated polymers (CPs) has been mainly focused on their application in organic electronics. Recent works, however, show that due to the unique optical and photophysical properties of CPs, such as high absorption in UV–Vis or even near-infrared (NIR) region and efficient intra-/intermolecular energy transfer, which can be relatively easily optimized, CPs can be considered as an effective light-activated source of versatile and highly reactive singlet oxygen for medical or catalytic use. The aim of this short review is to present the novel possibilities that lie dormant in those exceptional polymers with the extended system of π-conjugated bonds.

The Diradical‐Dication Strategy for BODIPY‐ and Porphyrin‐Based Dyes with Near‐Infrared Absorption Maxima from 1070 to 2040 nm

2018 ◽  
Vol 24 (72) ◽  
pp. 19341-19347 ◽  
Author(s):  
Houjia Wei ◽  
Rui Feng ◽  
Yong Fang ◽  
Lei Wang ◽  
Chao Chen ◽  
...  
Keyword(s):  
Infrared Absorption ◽  
Near Infrared
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