Enantioselective intramolecular C–H amination of aliphatic azides by dual ruthenium and phosphine catalysis
By combining a chiral-at-metal ruthenium catalyst with catalytic amounts of tris(p-fluorophenyl)phosphine (both 1 mol%), the challenging catalytic enantioselective ring-closing C(sp3)-H amination of unactivated aliphatic azides has been achieved with high enantioselectivities.
1985 ◽
Vol 24
(2)
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pp. 324-326
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2010 ◽
Vol 132
(50)
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pp. 17741-17750
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2011 ◽
Vol 102
(1-2)
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pp. 243-250
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