scholarly journals Reducing-agent-free facile preparation of Rh-nanoparticles uniformly anchored on onion-like fullerene for catalytic applications

RSC Advances ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 2545-2559 ◽  
Author(s):  
Mayakrishnan Gopiraman ◽  
Somasundaram Saravanamoorthy ◽  
Sana Ullah ◽  
Andivelu Ilangovan ◽  
Ick Soo Kim ◽  
...  
Keyword(s):  
Reducing Agent ◽  
Fullerene C60 ◽  
Facile Preparation ◽  
Catalytic Applications ◽  
First Time

Herein we report a very simple ‘mix and heat’ synthesis of a very fine Rh-nanoparticle loaded carbon fullerene-C60 nanocatalyst (Rh(0)NPs/Fullerene-C60) for the very first time.

Facile preparation of semimetallic WP2 as a novel photocatalyst with high photoactivity

RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15724-15730 ◽  
Author(s):  
Mingyu Pi ◽  
Tianli Wu ◽  
Dingke Zhang ◽  
Shijian Chen ◽  
Shuxia Wang
Keyword(s):  
Micro Particles ◽  
Considerable Research ◽  
Earth Abundant ◽  
Facile Preparation ◽  
First Time

Searching for inexpensive and earth-abundant photocatalysts with high activities has attracted considerable research in recent years. Semimetallic tungsten diphosphide (WP2) micro-particles are explored as a novel photocatalyst at the first time.

scholarly journals Photocontrolled organic field effect transistors based on the fullerene C60 and spiropyran hybrid molecule

RSC Advances ◽  
2019 ◽  
Vol 9 (13) ◽  
pp. 7505-7508 ◽  
Author(s):  
A. R. Tuktarov ◽  
R. B. Salikhov ◽  
A. A. Khuzin ◽  
N. R. Popod'ko ◽  
I. N. Safargalin ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Active Layer ◽  
Field Effect ◽  
Field Effect Transistors ◽  
Fullerene C60 ◽  
Organic Field Effect Transistors ◽  
Hybrid Molecule ◽  
Hybrid Compound ◽  
First Time

Photocontrolled organic field-effect transistors (OFETs) containing a hybrid compound of fullerene C60 (n-semiconductor) with spiropyran (electrical conductivity photocontroller) as the active layer were fabricated for the first time.

Robust onionlike structures with magnetic and photodynamic properties formed by a fullerene C60–POM hybrid

2016 ◽  
Vol 52 (82) ◽  
pp. 12171-12174 ◽  
Author(s):  
Shengju Zhou ◽  
Yongqiang Feng ◽  
Mengjun Chen ◽  
Qian Li ◽  
Baoyong Liu ◽  
...  
Keyword(s):  
Fullerene C60 ◽  
First Time

A fullerene C60–Dawson POM hybrid was prepared for the first time, which can aggregate into onionlike structures with magnetic and photodynamic properties.

scholarly journals A Facile Preparation and Energetic Characteristics of the Core/Shell CoFe2O4/Al Nanowires Thermite Film

Micromachines ◽  
2020 ◽  
Vol 11 (5) ◽  
pp. 516
Author(s):  
Chunpei Yu ◽  
Wei Ren ◽  
Ganggang Wu ◽  
Wenchao Zhang ◽  
Bin Hu ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Laser Ignition ◽  
Heat Output ◽  
Core Shell ◽  
Optimal Thickness ◽  
Maximum Heat ◽  
The Core ◽  
Potential Applications ◽  
Facile Preparation ◽  
First Time

In this study, CoFe2O4 is selected for the first time to synthesize CoFe2O4/Al nanothermite films via an integration of nano-Al with CoFe2O4 nanowires (NWs), which can be prepared through a facile hydrothermal-annealing route. The resulting nanothermite film demonstrates a homogeneous structure and an intense contact between the Al and CoFe2O4 NWs at the nanoscale. In addition, both thermal analysis and laser ignition test reveal the superb energetic performances of the prepared CoFe2O4/Al NWs nanothermite film. Within different thicknesses of nano-Al for the CoFe2O4/Al NWs nanothermite films investigated here, the maximum heat output has reached as great as 2100 J·g−1 at the optimal thickness of 400 nm for deposited Al. Moreover, the fabrication strategy for CoFe2O4/Al NWs is also easy and suitable for diverse thermite systems based upon other composite metal oxides, such as MnCo2O4 and NiCo2O4. Importantly, this method has the featured advantages of simple operation and compatibility with microsystems, both of which may further facilitate potential applications for functional energetic chips.

Facile preparation of ion-doped poly(p-phenylenediamine) nanoparticles for photothermal therapy

2018 ◽  
Vol 54 (38) ◽  
pp. 4862-4865 ◽  
Author(s):  
Chunling Hu ◽  
Yanshu Shi ◽  
Chunqiang Sun ◽  
Shuang Liang ◽  
Shouxin Bao ◽  
...  
Keyword(s):  
Photothermal Therapy ◽  
Facile Preparation ◽  
First Time

Ion-doped poly(p-phenylenediamine) nanoparticles were synthesized and used as a photothermal agent for photothermal therapy for the first time.

Nanoparticles of ZrPO4 for green catalytic applications

Nanoscale ◽  
2014 ◽  
Vol 6 (24) ◽  
pp. 14898-14902 ◽  
Author(s):  
Peta Sreenivasulu ◽  
Chandrasekhar Pendem ◽  
Nagabhatla Viswanadham
Keyword(s):  
Zirconium Phosphate ◽  
Room Temperature ◽  
Reaction Conditions ◽  
Temperature Synthesis ◽  
Block Polymer ◽  
Room Temperature Synthesis ◽  
Catalytic Applications ◽  
First Time

Here we report the successful room temperature synthesis of zirconium phosphate nanoparticles (ZPNP) using the P123 tri-co-block polymer for the first time and was employed for fixation of CO2 on aniline to produce pharmaceutically important acetanilide under mild reaction conditions (150 °C and 150 Psi CO2 pressure).

A facile way to fabricate double-shell pomegranate-like porous carbon microspheres for high-performance Li-ion batteries

2017 ◽  
Vol 5 (24) ◽  
pp. 12073-12079 ◽  
Author(s):  
Lei Zhang ◽  
Yuhai Dou ◽  
Haipeng Guo ◽  
Binwei Zhang ◽  
Xiaoxiao Liu ◽  
...  
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Li Ion Batteries ◽  
Carbon Microspheres ◽  
Li Ion ◽  
Facile Preparation ◽  
First Time ◽  
Templating Technique

We report for the first time a facile preparation of double-shell pomegranate-like porous carbon microspheres (PCMs) by a modified templating technique.

Zinc pyrovanadate nanosheets of atomic thickness: excellent Li-storage properties and investigation of their electrochemical mechanism

2016 ◽  
Vol 4 (28) ◽  
pp. 10974-10985 ◽  
Author(s):  
Gongzheng Yang ◽  
Shuoyu Li ◽  
Mingmei Wu ◽  
Chengxin Wang
Keyword(s):  
Lithium Storage ◽  
Storage Mechanism ◽  
Electrochemical Mechanism ◽  
Facile Preparation ◽  
First Time ◽  
Storage Properties ◽  
Li Storage

We report the facile preparation of ultrathin Zn3(OH)2V2O7·2H2O nanosheets and for the first time in detail investigate their lithium-storage mechanism.

A general protocol for the reductive N-methylation of amines using dimethyl carbonate and molecular hydrogen: mechanistic insights and kinetic studies

2016 ◽  
Vol 6 (22) ◽  
pp. 7956-7966 ◽  
Author(s):  
Jose R. Cabrero-Antonino ◽  
Rosa Adam ◽  
Kathrin Junge ◽  
Matthias Beller
Keyword(s):  
Molecular Hydrogen ◽  
Dimethyl Carbonate ◽  
Kinetic Studies ◽  
Reducing Agent ◽  
Aliphatic Amines ◽  
First Time ◽  
Aromatic And Aliphatic Amines

A general and selective ruthenium-catalyzed reductive N-methylation of primary and secondary aromatic and aliphatic amines using dimethyl carbonate as a C1 source and molecular hydrogen as a reducing agent is reported for the first time.

scholarly journals A Bifunctional Copper Catalyst Enables Ester Reduction with H2: Expanding the Reactivity Space of Nucleophilic Copper Hydrides

2021 ◽  
Author(s):  
Birte Zimmermann ◽  
Trung Tran Ngoc ◽  
Dimitrios-Ioannis Tzaras ◽  
Trinadh Kaicharla ◽  
Johannes F. Teichert
Keyword(s):  
Hydrogen Bonding ◽  
Copper Catalyst ◽  
Hydride Transfer ◽  
Bifunctional Catalyst ◽  
Reducing Agents ◽  
Reducing Agent ◽  
Reduction Step ◽  
First Time ◽  
The Way

Employing a bifunctional catalyst based on a copper(I)/NHC complex and a guanidine organocatalyst, catalytic ester reductions to alcohols with H<sub>2</sub> as terminal reducing agent are facilitated. The approach taken here enables the simul-taneous activation of esters through hydrogen bonding and formation of nucleophilic copper(I) hydrides from H<sub>2</sub>, resulting in a catalytic hydride transfer to esters. The reduction step is further facilitated by a proton shuttle mediated by the guani-dinium subunit. This bifunctional approach to ester reductions for the first time shifts the reactivity of generally considered “soft” copper(I) hydrides to previously unreactive “hard” ester electrophiles and paves the way for a replacement of stoichi-ometric reducing agents by a catalyst and H<sub>2</sub>.<br>

Sign in / Sign up

Export Citation Format

Share Document