scholarly journals Oxidative steam reforming of ethanol over MxLa2−xCe1.8Ru0.2O7−δ (M = Mg, Ca) catalysts: effect of alkaline earth metal substitution and support on stability and activity

RSC Advances ◽  
2019 ◽  
Vol 9 (68) ◽  
pp. 39932-39944 ◽  
Author(s):  
Ho-Chen Hsieh ◽  
Ping-Wen Tsai ◽  
Yuan-Chia Chang ◽  
Sheng-Feng Weng ◽  
Hwo-Shuenn Sheu ◽  
...  

Alkaline earth metal substitutions on the A-site of pyrochlore oxide MxLa2−xCe1.8Ru0.2O7−δ (M = Mg, Ca) were studied as catalyst materials for oxidative/autothermal steam reforming of ethanol (OSRE/ATR).

2019 ◽  
Vol 131 (49) ◽  
pp. 17839-17842 ◽  
Author(s):  
Jingyu Guo ◽  
Abudukadi Tudi ◽  
Shujuan Han ◽  
Zhihua Yang ◽  
Shilie Pan

2020 ◽  
Vol 22 (21) ◽  
pp. 11984-11995 ◽  
Author(s):  
Jia Song ◽  
De Ning ◽  
Henny J. M. Bouwmeester

Revisiting the electrical conduction and oxygen transport properties of alkaline-earth metal substituted La0.6A0.4FeO3−δ (A = Ca, Sr and Ba) perovskite oxides.


Author(s):  
Igor Oshchapovsky ◽  
Volodymyr Pavlyuk ◽  
Grygoriy Dmytriv ◽  
Alexandra Griffin

The structure of lanthanum tetrazinc, LaZn4, has been determined from single-crystal X-ray diffraction data for the first time, approximately 70 years after its discovery. The compound exhibits a new structure type in the space groupCmcm, with one La atom and two Zn atoms occupying sites withm2msymmetry, and one Zn atom occupying a site with 2.. symmetry. The structure is closely related to the BaAl4, La3Al11, BaNi2Si2and CaCu5structure types, which can be presented as close-packed arrangements of 18-vertex clusters, in this case LaZn18. The kindred structure types contain related 18-vertex clusters around atoms of the rare earth or alkaline earth metal.


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