scholarly journals Synthesis and characterization of cyclobutenedione–bithiophene π-conjugated polymers: acetal-protecting strategy for Kumada–Tamao–Corriu coupling polymerization between aryl bromide and Grignard reagents

RSC Advances ◽  
2019 ◽  
Vol 9 (70) ◽  
pp. 40863-40872
Author(s):  
Tomoyuki Ohishi ◽  
Takuma Sone ◽  
Kohei Oda ◽  
Akihiro Yokoyama

Donor–acceptor-type π-conjugated polymers consisting of cyclobutenedione as an acceptor and bithiophene as a donor were synthesized by Kumada–Tamao–Corriu coupling polymerization of an acetal-protected monomer.

2016 ◽  
Vol 134 ◽  
pp. 171-177 ◽  
Author(s):  
Amsalu Efrem ◽  
Marc Courté ◽  
Kai Wang ◽  
Denis Fichou ◽  
Mingfeng Wang

2016 ◽  
Vol 49 (6) ◽  
pp. 2135-2144 ◽  
Author(s):  
Yu Jiang ◽  
Yao Gao ◽  
Hongkun Tian ◽  
Junqiao Ding ◽  
Donghang Yan ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (38) ◽  
pp. 21252-21264 ◽  
Author(s):  
Yan Zhang ◽  
Lingqian Kong ◽  
Xiuping Ju ◽  
Hongmei Du ◽  
Jinsheng Zhao ◽  
...  

Two novel neutral green D–A type conjugated polymers were synthesized, illustrating satisfactory electrochromic properties, such as low band gaps, desirable color switches, excellent solubility and favorable thermal stability.


2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Eunhee Lim

We have synthesized a series of carbazole-benzothiadiazole-triazole based copolymers, poly[(N-9′-heptadecanyl-2,7-carbazole)-co-(5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole))-co-((4-(4-butylphenyl)-3,5-diphenyl-4H-1,2,4]triazole))] (PCz3TBTz) by Suzuki coupling polymerization. The optical and electrochemical properties of the copolymers could be tuned by changing the comonomer unit of triazole from 0% to 80%. Organic photovoltaic (OPV) cells were fabricated by blending the synthesized polymers as a donor and PCBM as an acceptor. The material solubility and film morphology were improved by introducing the triazole unit in the main chain. Improved OPV device performance of 1.74% was achieved in the presence of an optimal amount of triazole moieties.


RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12995-13003
Author(s):  
Jialin Yang ◽  
Li Yang ◽  
Qianqian Chen ◽  
Keke Guo ◽  
Ji-Min Han

We report a pyridine-flanked diketopyrrolopyrrole monomer and all-acceptor conjugated polymers synthesized therefrom. Photophysical, thermal and electrochemical properties of the polymers have been determined.


2011 ◽  
Author(s):  
M. G. Murali ◽  
D. Udayakumar ◽  
P. Predeep ◽  
Mrinal Thakur ◽  
M. K. Ravi Varma

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