scholarly journals Unusual adsorption behaviours and responsive structural dynamics via selective gate effects of an hourglass porous metal–organic framework

RSC Advances ◽  
2019 ◽  
Vol 9 (64) ◽  
pp. 37222-37231
Author(s):  
Ying Xiong ◽  
Yan-Zhong Fan ◽  
Zhang-Wen Wei ◽  
Cheng-Xia Chen ◽  
Sha Chen ◽  
...  
Keyword(s):  
Structural Dynamics ◽  
Dynamic Behaviour ◽  
Metal Organic Framework ◽  
Sorption Isotherms ◽  
Porous Metal ◽  
Sorption Behavior ◽  
Release Process ◽  
Metal Organic ◽  
Organic Framework

A Cu2+ based metal–organic framework exhibits dynamic behaviour upon guest inclusion/release process, and performing stepwise sorption isotherms for various gas. We elucidate detailed mechanisms under its exceptional sorption behavior.

A Twofold Interpenetrating Porous Metal−Organic Framework with High Hydrothermal Stability: Structure and Gas Sorption Behavior

2009 ◽  
Vol 48 (24) ◽  
pp. 11507-11509 ◽  
Author(s):  
Xinfang Liu ◽  
Mira Park ◽  
Seunghee Hong ◽  
Minhak Oh ◽  
Ji Woong Yoon ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Hydrothermal Stability ◽  
Sorption Behavior ◽  
Gas Sorption ◽  
Stability Structure ◽  
Metal Organic ◽  
Organic Framework

Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework

2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization

2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

A Solar Assistant Dehumidifier Based on Porous Metal-Organic Framework

2021 ◽  
Vol 896 ◽  
pp. 13-20
Author(s):  
Xiao Yu Wen
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Modern Architecture ◽  
Activated Alumina ◽  
Additional Energy ◽  
Humidity Control ◽  
Energy Inputs ◽  
Metal Organic ◽  
High Regeneration ◽  
Organic Framework

As an important factor to measure environmental comfort, humidity control is very important. However, previous dehumidification methods have many defects, such as condensation and adsorbents, which often require a lot of energy. The growing requirements of an indoor environment can stem from the development of living levels and technology. Humidity, as an important factor to measure environmental comfort, affects living and production, and indoor humidity control is an indispensable part of modern architecture. However, there are many defects in the previous dehumidification methods, such as condensation dehumidification, which often requires a lot of energy. Traditional adsorbents (such as zeolite silica and activated alumina) have problems with fragile structures or high regeneration temperatures. In this paper, an indoor dehumidification device based on the porous metal-organic framework {MOF-801, Zr6O4(OH)4(Fumarate)6}, can realize the indoor dehumidification process only by using a small amount of solar energy (1 kilowatt per square meter). The device is expected to remove 0.2113 kg/h of moisture per square meter MOF-801, only needs a few additional energy inputs.

An eight-connected porous metal–organic framework based on hetero pentanuclear clusters

CrystEngComm ◽  
2014 ◽  
Vol 16 (1) ◽  
pp. 47-50 ◽  
Author(s):  
Yu-Hui Luo ◽  
Xiao-Yang Yu ◽  
Jia-Jun Yang ◽  
Hong Zhang
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Quantum Rotations and Chiral Polarization of Qubit Prototype Molecules in a Highly Porous Metal–Organic Framework: 1H NMR T1 Study

2011 ◽  
Vol 115 (42) ◽  
pp. 20460-20465 ◽  
Author(s):  
Svyatoslav P. Gabuda ◽  
Svetlana G. Kozlova ◽  
Denis G. Samsonenko ◽  
Danil N. Dybtsev ◽  
Vladimir P. Fedin
Keyword(s):  
1H Nmr ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
1H Nmr T1 ◽  
Highly Porous ◽  
Organic Framework
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