scholarly journals Mesoporous cerium oxide for fast degradation of aryl organophosphate flame retardant triphenyl phosphate

RSC Advances ◽  
2019 ◽  
Vol 9 (55) ◽  
pp. 32058-32065 ◽  
Author(s):  
Jakub Ederer ◽  
Martin Šťastný ◽  
Marek Došek ◽  
Jiří Henych ◽  
Pavel Janoš
Keyword(s):  
Aqueous Solution ◽  
Catalytic Activity ◽  
Flame Retardant ◽  
Cerium Oxide ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Triphenyl Phosphate ◽  
Organophosphate Flame Retardant

Cerium oxide nanoparticles were prepared by calcination of basic cerous carbonate (as a precursor) obtained by precipitation from an aqueous solution and subsequent tested for catalytic activity.

scholarly journals The enzyme-like catalytic activity of cerium oxide nanoparticles and its dependency on Ce3+ surface area concentration

Nanoscale ◽  
2018 ◽  
Vol 10 (15) ◽  
pp. 6971-6980 ◽  
Author(s):  
V. Baldim ◽  
F. Bedioui ◽  
N. Mignet ◽  
I. Margaill ◽  
J.-F. Berret
Keyword(s):  
Reactive Oxygen Species ◽  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Surface Area ◽  
Cerium Oxide ◽  
Superoxide Radical ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Oxygen Species ◽  
Surface Area Concentration

Cerium oxide nanoparticles are known to catalyze the decomposition of reactive oxygen species such as the superoxide radical and hydrogen peroxide.

Dual role of hydrogen peroxide on the oxidase-like activity of nanoceria and its application for colorimetric hydrogen peroxide and glucose sensing

RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 59939-59945 ◽  
Author(s):  
Ruochen Guo ◽  
Yanru Wang ◽  
Shaoxuan Yu ◽  
Wenxin Zhu ◽  
Fangqing Zheng ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Cerium Oxide ◽  
Glucose Sensing ◽  
Dual Role ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Chromogenic Substrate

Nanoceria (cerium oxide nanoparticles) exhibits excellent catalytic activity towards chromogenic substrate 3,3,5,5-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide (H2O2), which has been reported.

scholarly journals Colloidal stability and catalytic activity of cerium oxide nanoparticles in cell culture media

RSC Advances ◽  
2020 ◽  
Vol 10 (65) ◽  
pp. 39373-39384 ◽  
Author(s):  
Xiaohui Ju ◽  
Anna Fučíková ◽  
Břetislav Šmíd ◽  
Jaroslava Nováková ◽  
Iva Matolínová ◽  
...  
Keyword(s):  
Cell Culture ◽  
Catalytic Activity ◽  
Acrylic Acid ◽  
Cerium Oxide ◽  
Colloidal Stability ◽  
Culture Media ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Cell Culture Media ◽  
Poly Acrylic Acid

Cerium oxide nanoparticles coated with poly(acrylic acid) exhibited high colloidal stability and preserved catalytic activity in cell culture media.

Synergistic effect of gold supported on redox active cerium oxide nanoparticles for the catalytic hydrogenation of 4-nitrophenol

2017 ◽  
Vol 41 (14) ◽  
pp. 6720-6729 ◽  
Author(s):  
M. Anandkumar ◽  
G. Vinothkumar ◽  
K. Suresh Babu
Keyword(s):  
Catalytic Activity ◽  
Synergistic Effect ◽  
Cerium Oxide ◽  
Catalytic Hydrogenation ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Redox Active ◽  
Nitrophenol Degradation

Gold-coated cerium oxide nanoparticles enhance the catalytic activity towards nitrophenol degradation.

scholarly journals Modulating the Catalytic Activity of Cerium Oxide Nanoparticles with the Anion of the Precursor Salt

2017 ◽  
Vol 121 (36) ◽  
pp. 20039-20050 ◽  
Author(s):  
Swetha Barkam ◽  
Julian Ortiz ◽  
Shashank Saraf ◽  
Nicholas Eliason ◽  
Rameech Mccormack ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cerium Oxide ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles

scholarly journals CATALYTIC ACTIVITY OF CERIUM OXIDE NANOPARTICLES

2020 ◽  
Author(s):  
Irina BAZHUKOVA ◽  
Inna ZVONAREVA ◽  
Alexandra MYSHKINA ◽  
Sergei BAZHUKOV ◽  
Ilya GAVRILOV ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cerium Oxide ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles

Polyacrylic Acid Modified Cerium Oxide Nanoparticles: Synthesis and Characterization as a Peroxidase Mimic for Non-Enzymatic H2O2 Sensor

2020 ◽  
Vol 16 (5) ◽  
pp. 816-828
Author(s):  
Gurdeep Rattu ◽  
Nishtha Khansili ◽  
Prayaga M. Krishna
Keyword(s):  
Hydrogen Peroxide ◽  
Cerium Oxide ◽  
Polyacrylic Acid ◽  
Spectroscopic Analysis ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Peroxidase Mimic ◽  
Ft Ir ◽  
H2o2 Sensing ◽  
Fluorescence Spectrometer

Background: Cerium oxide nanoparticles (nanoceria) are efficient free-radical scavengers due to their dual valence state and thus exhibit optical and catalytic properties. Therefore, the main purpose of this work was to understand the peroxidase mimic activity of polymer-stabilized nanoceria for enzyme-less H2O2 sensing by fluorescence spectrometer. Objective: This research revealed the development of fluorescence hydrogen peroxide nanosensor based on the peroxidase-like activity of polyacrylic acid stabilized nanoceria (PAA-CeO2 Nps). Methods: PAA-CeO2 Nps were synthesized by simple cross-linking reaction at a low temperature and characterized by XRD, SEM, Zeta potential, TGA, FT-IR and UV-VIS spectroscopic analysis. H2O2 sensing was performed by a fluorescence spectrometer. Results:: The synthesized polymer nanocomposite was characterized by XRD, SEM, TGA, FT-IR and UV-VIS spectroscopic analysis. The XRD diffraction patterns confirmed the polycrystalline nature and SEM micrograph showed nanoparticles having hexagonal symmetry and crystallite size of 32 nm. The broad peak of Ce–O bond appeared at 508 cm-1. UV-VIS measurements revealed a welldefined absorbance peak around 315 nm and an optical band-gap of 3.17 eV. As synthesized PAACeO2 Nps effectively catalysed the decomposition of hydrogen peroxide (H2O2) into hydroxyl radicals. Then terephthalic acid was oxidized by hydroxyl radical to form a highly fluorescent product. Under optimized conditions, the linear range for determination of hydrogen peroxide was 0.01 - 0.2 mM with a limit of detection (LOD) of 1.2 μM. Conclusion: The proposed method is ideally suited for the sensing of H2O2 at a low cost and this detection system enabled the sensing of analytes (sugars), which can enzymatically generate hydrogen peroxide.

Sign in / Sign up

Export Citation Format

Share Document