scholarly journals Rational design of MgF2 catalysts with long-term stability for the dehydrofluorination of 1,1-difluoroethane (HFC-152a)

RSC Advances ◽  
2019 ◽  
Vol 9 (41) ◽  
pp. 23744-23751 ◽  
Author(s):  
Haodong Tang ◽  
Mingming Dang ◽  
Yuzhen Li ◽  
Lichun Li ◽  
Wenfeng Han ◽  
...  

In this study, sol–gel, precipitation and hard-template methods were applied to synthesize MgF2 catalysts with improved stability towards dehydrofluorination of hydrofluorocarbons and MgF2-T catalysts demonstrated superior long-term stability.

1995 ◽  
Vol 377 ◽  
Author(s):  
Mohan K. Bhan

ABSTRACTWe have systematically investigated the effects of addition of sub-ppm levels of boron on the stability of a-Si:H films and p-i-n devices, deposited by PE-CVD technique. The films thus produced with appropriate amounts of boron, show a significant improvement in stability, when soaked under both AM 1.5 (short-term) as well as 10×sun (long-term) illumination conditions. The opto-electronic properties of the films are quite respectable It is concluded that boron compensates the native impurities by forming donor-acceptor pairs, which reduces the “fast” defects and hence the initial degradation of the films. It is also speculated that boron may also be improving the short-term stability, by reducing the recombination of light generated electrons and holes, by converting D° into D+ states. The long-term stability appears to get affected by hydrogen dilution which seems to reduce the amount of “slow” defects. As a result of B doping of i-layer, the initial conversion efficiency of the devices decreases. It is presumed that our devices may contain an enhanced level of boron impurity, than expected, making them as worse material and to degrade less.


RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24126-24131 ◽  
Author(s):  
Kamaraj Mahendraprabhu ◽  
Perumal Elumalai

An YSZ-based electrochemical sensor was fabricated using sol–gel derived NiO nanospheres. The sensor exhibited high sensitivity and selectivity to C3H6 (propene) with excellent long-term stability.


Author(s):  
Kevin Ploner ◽  
Parastoo Delir Kheyrollahi Nezhad ◽  
Albert Gili ◽  
Franz Kamutzki ◽  
Aleksander Gurlo ◽  
...  

The adaption of the sol-gel autocombustion method to the Cu/ZrO2 system opens new pathways for the specific optimisation of the activity, long-term stability and CO2 selectivity of methanol steam reforming...


2020 ◽  
Vol 22 (26) ◽  
pp. 14838-14845 ◽  
Author(s):  
Wenbo Liu ◽  
Fei Yu ◽  
Weijun Fan ◽  
Qichun Zhang

Well-performing SSCs with SnO2 as the ETL and P3HT as the HTL, showing a long-term stability (more than 1500 h) were fabricated. Moreover, the aging process of the SSCs was analyzed in detail to explore the factors that affect the device behaviors.


2003 ◽  
Vol 75 (10) ◽  
pp. 2407-2413 ◽  
Author(s):  
Ying Tang ◽  
Elizabeth C. Tehan ◽  
Zunyu Tao ◽  
Frank V. Bright

Author(s):  
Abolfazl Ghaderian ◽  
Meenakshi Pegu ◽  
Naveen Harindu Hemasiri ◽  
Peng Huang ◽  
Shahzada Ahmad ◽  
...  

For industrial endeavors, perovskite solar cells (PSCs) demand long-term stability and a cost-effective hole-transporting layer (HTL). The PSC stability can be substantially improved by the rational design of dopant-free HTL...


Nanoscale ◽  
2018 ◽  
Vol 10 (27) ◽  
pp. 12963-12969 ◽  
Author(s):  
Chunhua Han ◽  
Xiao Zhang ◽  
Xiaoming Xu ◽  
Qi Li ◽  
Qiu He ◽  
...  

The porous CaFe2O4 was synthesized by a facile sol–gel method and shows a distinct trade-off in terms of high capacity and long-term stability compared to pristine iron oxides.


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