scholarly journals Effect of nitrogen co-doping with ruthenium on the catalytic performance of Ba/Ru–N-MC catalysts for ammonia synthesis

RSC Advances ◽  
2019 ◽  
Vol 9 (38) ◽  
pp. 22045-22052 ◽  
Author(s):  
Yongcheng Ma ◽  
Guojun Lan ◽  
Xiaolong Wang ◽  
Geshan Zhang ◽  
Wenfeng Han ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Catalytic Performance ◽  
Co Doping ◽  
Highly Active

A highly active and stable mesoporous Ba/Ru–N-MC catalyst for ammonia synthesis was prepared by an in situ thermal carbonization method with nitrogen co-doping with ruthenium NPs.

In situ formation of highly active Ni–Fe based oxygen-evolving electrocatalysts via simple reactive dip-coating

2017 ◽  
Vol 5 (22) ◽  
pp. 11009-11015 ◽  
Author(s):  
Guofa Dong ◽  
Ming Fang ◽  
Jianshuo Zhang ◽  
Renjie Wei ◽  
Lei Shu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
State Of The Art ◽  
Catalytic Performance ◽  
Dip Coating ◽  
Highly Active ◽  
Coating Method ◽  
In Situ Formation ◽  
Dip Coating Method ◽  
Oxygen Evolving

An extremely simple in situ reactive dip-coating method is developed to prepare Ni–Fe based electrocatalysts with good catalytic performance on oxygen evolution comparable to those of state-of-the art precious catalysts.

In situ assembly of monodispersed Ag nanoparticles in the channels of ordered mesopolymers as a highly active and reusable hydrogenation catalyst

2015 ◽  
Vol 3 (8) ◽  
pp. 4307-4313 ◽  
Author(s):  
Xianchun Liu ◽  
Renxi Jin ◽  
Dashu Chen ◽  
Lin Chen ◽  
Shuangxi Xing ◽  
...  
Keyword(s):  
Ag Nanoparticles ◽  
Reduction Method ◽  
Catalytic Performance ◽  
Hydrogenation Catalyst ◽  
Highly Active

Monodispersed Ag nanoparticles were assembled in the channels of FDU-15 ordered mesopolymers by a simple in situ auto-reduction method and exhibited high catalytic performance in the reduction of 4-nitrophenol.

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Promoting Hydrogen Evolution of g-C3N4 Based Photocatalyst by Indium and Phosphorus Co-doping

2021 ◽  
Author(s):  
Xiao-Hang Yang ◽  
Chi Cao ◽  
Zilong Guo ◽  
Xiaoyu Zhang ◽  
Yaxin Wang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Post Treatment ◽  
Experimental Results ◽  
Indium Chloride ◽  
Co Doping ◽  
In Situ Copolymerization ◽  
Co Doped

Indium and phosphorus co-doped g-C3N4 photocatalyst (In,P-g-C3N4) was prepared by K2HPO4 post-treatment of indium doped g-C3N4 photocatalyst (In-g-C3N4) derived from in-situ copolymerization of dicyandiamide and indium chloride. The experimental results...

In Situ Activated Co3–xNixO4 as a Highly Active and Ultrastable Electrocatalyst for Hydrogen Generation

ACS Catalysis ◽  
2021 ◽  
pp. 8174-8182
Author(s):  
Kailu Guo ◽  
Yantao Wang ◽  
Junfeng Huang ◽  
Min Lu ◽  
Hua Li ◽  
...  
Keyword(s):  
Hydrogen Generation ◽  
Highly Active

In-situ formed Co from Co-Mg-O solid solution synergizing with LiH for efficient ammonia synthesis

2021 ◽  
Author(s):  
Wenbo Gao ◽  
Sheng Feng ◽  
Hanxue Yan ◽  
Qianru Wang ◽  
Hua Xie ◽  
...  
Keyword(s):  
Solid Solution ◽  
Metal Nanoparticles ◽  
Magnesium Oxide ◽  
Ammonia Synthesis ◽  
Oxide Solid Solution ◽  
In Situ Formation

A cobalt magnesium oxide solid solution (Co-Mg-O) supported LiH catalyst has been synthesized, in which LiH functions both as a strong reductant for in-situ formation of Co metal nanoparticles and...

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